Numerical Optimization on Char Conversion and NOx Emission under Various Operating Conditions in a Retrofit Biomass Boiler.

Retrofitting retirement or existing fossil boiler with biomass is an important method of curbing electricity shortage and lowering the cost of modern power plants. However, the use of biomass combustion is hampered by operational problems, such as the resulting high unburned carbon, amount of bottom ash, and nitrogen oxide (NOx) release. In this study, we investigated the burning of pulverized biomass in a retrofitting boiler power plant using computational fluid dynamics of commercial software fluent ANSYS to determine the optimal combustion conditions. The objective of this study was to investigate a 125 MWe pulverized biomass boiler that was retrofitted from an anthracite down-fired boiler. The air distribution, including the influence of the secondary air ratio and the location of the burner standby, was evaluated. Key factors such as biomass ash mass at the hopper, char conversion, and high zone temperature relating to NOx formation/reduction were calculated. The adjustment of the secondary air ratio from 30 to 50% of the total air and the mass ash at the hopper significantly decreased to a low value at 247 kg/h and a high value of char conversion at 97.33% in case R (SA40%). The standard deviation temperature was 240 K at the BNR B-A level for case R, which was significantly lower than in other cases. This implies that the best mixing of air and biomass occurs in case R at 40%. Comparative analysis of the burner standby conditions showed that the NOx emission was similar at the boiler outlet (approximately 94-116 ppm). Burner A on standby, with a secondary air ratio of 40%, was used as the optimal case with the highest value of char conversion at 98.43%, the lowest bottom ash release of 204 kg/h, and a low-NOx emission of 106 ppm.

Comparative Study of the Synergistic Effects of Blending Raw/Torrefied Biomass and Vietnamese Anthracite Using Co-pyrolysis.

Biomass can be upgraded via torrefaction, and torrefied kenaf (TK) is a fuel that allows blending with coal at high ratios. In the present study, raw kenaf (Hibiscus cannabinus L.) (RK) was torrefied at 523 K for 30 min and then mixed with Vietnamese anthracite (NinhBinh, NB) before co-pyrolysis. Thermogravimetric (TG) analysis was used to evaluate the behavior of RK, TK, and blended RK/TK during co-pyrolysis at biomass blending ratios (BBRs) of 0, 25, 50, 75, and 100 wt %. The TG and derivative thermogravimetry curves of a mixture of NB and RK (NBRK) were similar to those of RK. The decomposition curves of a mixture of NB and TK (NBTK) depended on the mass fraction of TK. Based on weight loss differences between the experimental and calculated data for the fuel blends, no interaction between the RK and anthracite was observed for all BBRs, whereas anthracite involving 50 and 75% TK exhibited synergistic effects. The temperature range for synergy and degree of synergy for NB and TK depended on the heating rate and mass ratio of TK. Kinetic parameters were calculated using the Friedman-non-isothermal free kinetic method at heating rates of 10, 20, and 40 K/min. The results showed that the activation energy (E) values of the NBRK at conversion ratios of 0.2-0.5 were equal to those of the RK, whereas they were superior at NB decomposition ratios of 0.6-0.8. NBTK1-1 (BBR of 50%) showed E values higher than those of NB at some conversion ratios, thus demonstrating a negative impact of blending. Further, NBTK1-3 (BBR of 75%) and NBTK3-1 (BBR of 25%) exhibited E values between those of NB and TK. The present study suggests that a high TK mass fraction (75%) in the blend for co-pyrolysis is optimal for the activation energy and volatile matter yield.

Effect of Torrefaction on Thermal and Kinetic Behavior of Kenaf during Its Pyrolysis and CO2 Gasification.

Torrefaction is an appealing pretreatment method for improving the fuel properties of kenaf biomass before its utilization in thermochemical processes. This study evaluated and compared the impact of torrefaction on thermal behavior and kinetics during pyrolysis and gasification. Thermogravimetric analysis experiments were conducted at temperatures of 300-1173 K at several heating rates under N2 and CO2 atmospheres. The raw and torrefied kenaf (RK and TK) during CO2 gasification in the low-temperature region (<900 K) was found to exhibit a tendency that was similar to that of N2. However, TK during CO2 gasification resulted in a lower maximum mass loss rate, delayed initiating temperature, and lower devolatilization index due to lower reactivity. In addition, the gasification reaction of CO2 and char was observed to occur in the high-temperature region (> 900 K), thus improving conversion efficiencies. The activation energy for TK in a CO2 atmosphere depending on the conversion was calculated using the distributed activation energy method. The activation of RK during CO2 gasification was higher than that of N2. However, TK during CO2 gasification exhibited a lower activation energy compared to that of N2, indicating its potential as a better feedstock during the CO2 gasification process and the ability to save energy.