Bio-engineered sensing of Atrazine by green CdS quantum dots: Evidence from electrochemical studies and DFT simulations.

The present investigation reports a comprehensible and responsive strategy for identifying atrazine in several conditions using an extensive electrochemical method. CdS Quantum dots were synthesized via a greener approach, and their formation was endorsed by numerous characterization techniques such as FTIR, SEM, Raman, UV-Vis, and XRD. Owing to the splendid electrocatalytic behavior, Green CdS quantum dots (QDs) of crystallite size ∼2 nm was opted as the sensor material and were, therefore, incorporated on the bare carbon paste electrode's surface. The developed sensor demonstrated an impressive outcome for atrazine sensing accompanied by superior selectivity and sensitivity. The lower detection limit (LLOD) of 0.53 µM was attained using the developed sensor in a linear concentration range of 10-100 µM. Furthermore, the practical pertinence of the developed sensor was examined on distilled water, wastewater, and fresh liquid milk, resulting in a tremendous retrieval of atrazine (91.33-99.8%).

Novel and sustainable green sulfur-doped carbon nanospheres via hydrothermal process for Cd (II) ion removal.

Herein, the synthesis, characterization, and adsorption performance of a novel green sulfur-doped carbon nanosphere (S-CNs) is studied to eliminate Cd (II) ions from water effectively. S-CNs were characterized using different techniques including Raman spectroscopy, powder X-ray diffraction (PXRD), scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX), , Brunauer-Emmett-Teller (BET) specific surface area analysis and Fourier transform infrared spectrophotometry (FT-IR), were performed. The efficient adsorption of the Cd (II) ions onto S-CNs strongly depended on pH, initial concentration of Cd (II) ions, S-CNs dosage, and temperature. Four isotherm models (Langmuir, Freundlich, Temkin & Redlich Peterson) were tested for modeling. Out of four, Langmuir showed more applicability than the other three models, with a Qmax value of 242.72 mg/g. Kinetic modeling studies suggest a superior fit of the obtained experimental data with the Elovich equation (linear) and pseudo-second-order (non-linear) rather than other linear and non-linear models. Data obtained from thermodynamic modeling indicates that using S-CNs for Cd (II) ions adsorption is a spontaneous and endothermic . The current work recommends using better and recyclable S-CNs to uptake excess Cd (II) ions.

Advanced experimental techniques for the sensitive detection of a toxic bisphenol A using UiO-66-NDC/GO-based electrochemical sensor.

In the present study, a simple and sensitive method for detecting bisphenol A (BPA) in various environments, including groundwater, was described using a widespread electrochemical method. BPA is well-known for its endocrine-disrupting properties, which may cause potential toxicological effects oon the nervous, reproductive, and immune systems. A novel metal-organic framework (UiO-66-NDC/GO) was synthesized, and its existence was confirmed by several characterization techniques like FTIR, UV-visible, XRD, SEM-EDX, Raman spectroscopy, and TGA. Due to the excellent electrocatalytic nature, UiO-66-NDC/GO was chosen as the sensor material and integrated on the surface of the bare carbon paste electrode (BCPE). The UiO-66-NDC/GO modified carbon paste electrode (MCPE) was engaged for the detection of BPA using techniques like cyclic Voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS). The applied sensor exhibited an astonishing outcome for BPA detection with high sensitivity and selectivity. The lower detection limit (LLOD) of 0.025 µM was achieved at the modified sensor with a linear concentration range of 10-70 µM. Moreover, the practical applicability of the sensor was tested on tap water, drinking water, and fresh liquid milk, giving an excellent recovery of BPA in the range of 94.8-99.3 (v.%). The proposed method could be employed for electrochemical device or a solid state device fabrication for the onsite monitoring of BPA.