Sorption of Total Petroleum Hydrocarbons in Microplastics.

As is the case for many others in the world, Mexican seas face complex pollution challenges; two of the contaminants that require special attention for their prevalence, possible chemical interactions, and relation to the country's economy are leaked petroleum and microplastics (MP). This research assessed the sorption of total petroleum hydrocarbons (TPH) as fuel oil on microplastics in laboratory and field scenarios. Preliminary tests allowed the development and validation of a methodology to measure the sorbed fuel oil by Soxhlet extraction, with a 99.65% recovery rate. The amount of TPH sorbed in the lab followed the order LDPE > PS > PP > PVC > PET > HDPE, with the highest concentration found on LDPE. The sorption of fuel oil on microplastics is correlated to the surface area of the plastic particles and could also be related to the crystallinity of plastics. Sorption, for all plastics, was consistent with a second-order kinetic model. The analysis of field samples collected on beaches of the Gulf of Mexico varied from 1660 to 35,258 mg/kg MP. It must be noticed that, unlike others, this research quantified a family of contaminants, which could explain the high concentrations observed on microplastics.

A mini review on the main challenges of implementing mechanical biological treatment plants for municipal solid waste in the Latin America region: Learning from the experiences of developed countries.

Most of the municipal solid waste (MSW) generated in the Latin America (LATAM) region is currently disposed of in landfills and dumpsites, which results in many negative environmental impacts. Mechanical biological treatment (MBT) is a strategy that combines the mechanical separation of recoverable materials with the biological stabilization of organic matter. MBT plants have proven to be a good alternative for the management of MSW and have been successfully implemented in developed countries for more than 30 years. However, the efficient introduction of these facilities in developing countries, such as those in the LATAM region, requires further feasibility studies. Therefore, this mini review seeks to offer significant insights into the main challenges that must be overcome to facilitate the implementation and operation of MBT plants, considering the unique technological, sociocultural, economic and political context of the LATAM region, through a comparison of the reported experiences of MBT plants in more developed countries with those in the LATAM region. The analysis herein indicates that key actions for the successful operation of MBT plants in the LATAM region include both the implementation of source separation as well as selective collection practices. Moreover, this work shows that other factors, like the establishment of valorization markets with safe working conditions for informal collectors, the development of intermunicipal cooperation schemes and the enforcement of strong regulatory frameworks for waste disposal specifications, are important contextual factors that have allowed the efficient operation of MBT plants in developed countries. Although the implementation of many of these practices will be challenging, such measures are necessary to increase the sustainability of MSW treatment practices in the LATAM region.

Corrigendum to "Recycling of nutrients from landfill leachate: A case study" [Heliyon 8 (5) (2022) e09540].

[This corrects the article DOI: 10.1016/j.heliyon.2022.e09540.].

Recycling of nutrients from landfill leachate: A case study.

The continuous increase in the consumption of natural resources requires different solutions directed to the recovery and recycling of different materials and products, including the nutrients used as fertilizers for food production. In this context, this research assessed the feasibility of using landfill leachate as a source of nutrients for the growth of maize. Leachate was treated to precipitate struvite, a rich magnesium, phosphate, and ammonium mineral that can be applied directly as fertilizer. It was used for the growth of maize, which was sowed in three different parcels. A commercial DAP + urea mixture was used to compare, and non-fertilized parcels were used as controls. Struvite was successfully obtained and applied in the fields. A marginal higher maize yield was achieved in two sites when using struvite (6.36% and 2.16%) compared to the commercial fertilizer, even if it was applied in a lower dose to weather conditions. An increase in N and Mg in soil could be observed, which allowed for the assimilation of nutrients in the plants. Concerning safety, the use of struvite did not produce the transfer of heavy metals or pathogens to the soil or plants. This research shows a promising way of dealing with leachate, which could be attractive in countries where organic waste is buried in landfills.

Waste management and environmental impact of absorbent hygiene products: A review.

Absorbent hygiene products (AHP) have received much interest due to the notion that their end-of-life (EoL) stage has high environmental impacts. Since the use of AHP will continue to rise in the foreseeable future, information that helps with a reduction in the environmental impacts of AHP through their life cycle is needed. This research presents an estimation of AHP in municipal waste, and it also reviews and discusses waste management options, available treatments at bench, pilot or full scale, and life cycle assessments (LCAs) available in the literature. Municipal waste of countries belonging to the Organization for Economic Co-operation and Development contains on average 2.7% of baby nappies, 4.8% of adult nappies and 0.5% of sanitary pads (in weight), whereas that of Latin-American countries have 7.3%, 3.3%, and 0.9%, respectively. Management options for AHP waste in developed countries are landfilling and incineration, while in developing countries AHP are disposed of in dumpsites and landfills. Most LCAs identify significant environmental impacts in the production of raw materials, while EoL scenarios involving incineration and landfill were found to have a significant contribution to global warming potential. Substitution with alternative products has been suggested as a way of decreasing environmental impacts; however, their use frequently causes a trade-off on different impact categories. Municipalities could use a wide range of policy tools, such as extended producer responsibility systems, bans, levies, ecolabelling, or a combination of these, to reduce the environmental and economic burden of AHP waste.

Dataset of quantification and classification of microplastics in Mexican sandy beaches.

The presence of microplastics in marine and coastal environments is an issue of concern for the preservation of these ecosystems. This dataset provides the results of the first national assessment of the presence of microplastics (<5 mm) in Mexican beaches. The research included 35 beaches along the five marine regions of the country. For each beach, ten samples (19 cm diameter, 5 cm depth) were taken along the high-tide line, and then microplastics were extracted by flotation and sieving. All the plastic particles were quantified and classified based on their colour, type of particle, and type of plastic used in their production, using visual inspection and FTIR spectroscopy. The use of the same methodology in all the beaches allowed us to compare and analyze the results, which are reported in the article Microplastics in Mexican beaches.

Degradation of Plastics under Anaerobic Conditions: A Short Review.

Plastic waste is an issue of global concern because of the environmental impact of its accumulation in waste management systems and ecosystems. Biodegradability was proposed as a solution to overcome this problem; however, most biodegradable plastics were designed to degrade under aerobic conditions, ideally fulfilled in a composting plant. These new plastics could arrive to anaerobic environments, purposely or frequently, because of their mismanagement at the end of their useful life. This review analyzes the behavior of biodegradable and conventional plastics under anaerobic conditions, specifically in anaerobic digestion systems and landfills. A review was performed in order to identify: (a) the environmental conditions found in anaerobic digestion processes and landfills, as well as the mechanisms for degradation in those environments; (b) the experimental methods used for the assessment of biodegradation in anaerobic conditions; and (c) the extent of the biodegradation process for different plastics. Results show a remarkable variability of the biodegradation rate depending on the type of plastic and experimental conditions, with clearly better performance in anaerobic digestion systems, where temperature, water content, and inoculum are strictly controlled. The majority of the studied plastics showed that thermophilic conditions increase degradation. It should not be assumed that plastics designed to be degraded aerobically will biodegrade under anaerobic conditions, and an exact match must be done between the specific plastics and the end of life options that they will face.

Biodegradation of compostable and oxodegradable plastic films by backyard composting and bioaugmentation.

Plastics are widely used in the production of short-life products, which are discarded producing an accumulation of these materials and problems due to their persistence in the environment and waste management systems. Degradable plastics (compostable, oxodegradable) have been presented as an alternative to decrease the negative effect of plastic waste. In this research, the feasibility of degrading a commercially available compostable film and oxodegradable polyethylene, with and without previous abiotic oxidation, is assessed in a home composting system. Reactors (200 L) were used to degrade the plastic films along with a mixture of organic food waste (50 %), mulch (25 %), and dry leaves (25 %), amended with yeast and a solution of brown sugar to increase the speed of the process. The presence of the plastic film did not affect the composting process, which showed an initial increase in temperature and typical profiles for moisture content, pH, with a final C/N of 17.4. After 57 days, the compostable plastic has decreased its mechanical properties in more than 90 %, while the oxodegradable film did not show significant degradation if it was not previously degraded by UV radiation. The use of these plastics should be assessed against the prevailing waste management system in each city or country. In the case of Mexico, which lacks the infrastructure for industrial composting, home composting could be an option to degrade compostable plastics along organic waste. However, more testing is needed in order to set the optimal parameters of the process.

Disposable diapers biodegradation by the fungus Pleurotus ostreatus.

This research assesses the feasibility of degrading used disposable diapers, an important component (5-15% in weight) of urban solid waste in Mexico, by the activity of the fungus Pleurotus ostreatus, also known as oyster mushroom. Disposable diapers contain polyethylene, polypropylene and a super absorbent polymer. Nevertheless, its main component is cellulose, which degrades slowly. P. ostreatus has been utilized extensively to degrade cellulosic materials of agroindustrial sources, using in situ techniques. The practice has been extended to the commercial farming of the mushroom. This degradation capacity was assayed to reduce mass and volume of used disposable diapers. Pilot laboratory assays were performed to estimate the usefulness of the following variables on conditioning of used diapers before they act as substrate for P. ostreatus: (1) permanence vs removal of plastic cover; (2) shredding vs grinding; (3) addition of grape wastes to improve structure, nitrogen and trace elements content. Wheat straw was used as a positive control. After 68 days, decrease of the mass of diapers and productivity of fungus was measured. Weight and volume of degradable materials was reduced up to 90%. Cellulose content was diminished in 50% and lignine content in 47%. The highest efficiency for degradation of cellulosic materials corresponded to the substrates that showed highest biological efficiency, which varied from 0% to 34%. Harvested mushrooms had good appearance and protein content and were free of human disease pathogens. This research indicates that growing P. ostreatus on disposable diapers could be a good alternative for two current problems: reduction of urban solid waste and availability of high protein food sources.