Liquid Metal-Based Stable and Stretchable Zn-Ion Battery for Electronic Textiles.

Electronic textiles harmoniously interact with the human body and the surrounding environment, offering tremendous interest in smart wearable electronics. However, their wide application faces challenges due to the lack of stable and stretchable power electrodes/devices with multifunctional design. Herein, an intrinsically stretchable liquid metal-based fibrous anode for a stable Zn-ion battery (ZIB) is reported. Benefiting from the liquid feature and superior deformability of the liquid metal, optimized Zn ion concentration distribution and Zn (002) deposition behavior are observed, which result in dendrite-free performance even under stretching. With a strain of 50%, the ZIB maintains a high capacity of 139.8 mAh cm-3 (corresponding to 83.0% of the initial value) after 300 cycles, outperforming bare Zn fiber-based ZIB. The fibrous ZIB seamlessly integrates with the sensor, Joule heater, and wirelessly charging device, which provides a stable power supply for human signal monitoring and personal thermal management, holding promise for the application of wearable multifunctional electronic textiles.

Ultraviolet-Assisted Printing of Flexible Solid-State Zn-Ion Battery with a Heterostructure Electrolyte.

Flexible solid-state Zn-ion batteries (ZIBs) have garnered considerable attention for next-generation power sources, but the corrosion, dendrite growth, and interfacial problems severely hinder their practical applications. Herein, a high-performance flexible solid-state ZIB with a unique heterostructure electrolyte is facilely fabricated through ultraviolet-assisted printing strategy. The solid polymer/hydrogel heterostructure matrix not only isolates water molecules and optimizes electric field distribution for dendrite-free anode, but also facilitates fast and in-depth Zn2+ transport in the cathode. The in situ ultraviolet-assisted printing creates cross-linked and well-bonded interfaces between the electrodes and the electrolyte, enabling low ionic transfer resistance and high mechanical stability. As a result, the heterostructure electrolyte based ZIB outperforms single-electrolyte based cells. It not only delivers a high capacity of 442.2 mAh g-1 with long cycling life of 900 cycles at 2 A g-1 , but also maintains stable operation under mechanical bending and high-pressure compression in a wide temperature range (-20 °C to 100 °C).