1.
Org Biomol Chem
; 8(13): 3060-3, 2010 Jun 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20480094
RESUMO
Unprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagents.