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1.
Sci Rep ; 12(1): 9642, 2022 06 10.
Artigo em Inglês | MEDLINE | ID: mdl-35688925

RESUMO

Broadband mid-infrared (MIR) spectroscopy is a well-established and valuable diagnostic technique for reactive plasmas. Plasmas are complex systems and consist of numerous (reactive) types of molecules; it is challenging to measure and control reaction specificity with a good sensitivity. Here, we demonstrate the first use of a novel MIR supercontinuum (SC) source for quantitative plasma spectroscopy. The SC source has a wide spectral coverage of 1300-2700 cm-1 (wavelength range 3.7-7.7 µm), thus enabling broadband multispecies detection. The high spatial coherence of the MIR SC source provides long interaction path lengths, thereby increasing the sensitivity for molecular species. The combination of such a SC source with a custom-built FTIR spectrometer (0.1 cm-1 spectral resolution) allows detection of various gases with high spectral resolution. We demonstrate its potential in plasma applications by accurate identification and quantification of a variety of reaction products (e.g. nitrogen oxides and carbon oxides) under low-pressure conditions, including the molecular species with overlapping absorbance features (e.g. acetone, acetaldehyde, formaldehyde, etc.).


Assuntos
Gases , Óxidos de Nitrogênio , Acetona , Análise de Fourier , Espectrofotometria Infravermelho/métodos
2.
Opt Express ; 29(14): 22315-22330, 2021 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-34265999

RESUMO

We present a fast-scanning Fourier transform spectrometer (FTS) in combination with high-repetition-rate mid-infrared supercontinuum sources, covering a wavelength range of 2-10.5 µm. We demonstrate the performance of the spectrometer for trace gas detection and compare various detection methods: baseband detection with a single photodetector, baseband balanced detection, and synchronous demodulation at the repetition rate of the supercontinuum source. The FTS uses off-the-shelf optical components and provides a minimum spectral resolution of 750 MHz. It achieves a noise equivalent absorption sensitivity of ∼10-6 cm-1 Hz-1/2 per spectral element, by using a 31.2 m multipass absorption cell.

3.
Opt Express ; 26(2): 2013-2022, 2018 Jan 22.
Artigo em Inglês | MEDLINE | ID: mdl-29401922

RESUMO

This paper presents fiber Bragg grating (FBG) inscription with a pulsed 248 nm UV KrF laser in polymer optical fibers (POFs) made of different polymers, namely polymethyl methacrylate (PMMA), cyclic-olefin polymer and co-polymer, and Polycarbonate. The inscribed gratings and the corresponding inscription parameters are compared with grating inscribed in POFs made of the aforementioned materials but with the hitherto most used laser for inscription, which is a continuous wave 325 nm UV HeCd laser. Results show a reduction of the inscription time of at least 16 times. The maximum time reduction is more than 130 times. In addition, a reflectivity and a bandwidth close to or higher than the ones with the 325 nm laser were obtained. The polymer optical fiber Bragg gratings (POFBGs) inscribed with the 248 nm laser setup present high stability with small variations in their central wavelength, bandwidth, and reflectivity after 40 days.

4.
Appl Opt ; 54(18): 5657-61, 2015 Jun 20.
Artigo em Inglês | MEDLINE | ID: mdl-26193010

RESUMO

We propose a novel dynamic gate algorithm (DGA) for precise and accurate peak detection. The algorithm uses a threshold-determined detection window and center of gravity algorithm with bias compensation. We analyze the wavelength fit resolution of the DGA for different values of the signal-to-noise ratio and different peak shapes. Our simulations and experiments demonstrate that the DGA method is fast and robust with better stability and accuracy than conventional algorithms. This makes it very attractive for future implementation in sensing systems, especially based on multimode fiber Bragg gratings.

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