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1.
Appl Opt ; 63(8): 1962-1970, 2024 Mar 10.
Artigo em Inglês | MEDLINE | ID: mdl-38568636

RESUMO

In this paper, a dual-band terahertz metamaterial sensor based on aluminum and silicon is proposed and simulated. The aluminum surface, which is deposited on a silicon substrate, is made of a C-shaped frame resonator, a rectangular beam, and a cross. The device is insensitive to the change of incident angle in the range of 0°-30°, which shows the great transmission stability of the sensor. By examining the resonance frequency shift, it is shown that 98.3 and 237.5 GHz/RIU refractive index sensitivity can be obtained near 1.76 and 2.404 THz transmission dips of the proposed structure, respectively. The two dips can be used to sense analytes in different refractive index ranges, respectively. For Dip 1 at 1.76 THz, the range is 1.0-1.6. For Dip 2 at 2.404 THz, the range is 1.6-2.0. Different from traditional multi-band metamaterial sensors, two dips generated by the proposed device can measure continuous and non-multiplexed refractive index ranges, respectively. Because the resonance frequencies of matters are different, such a characteristic enables the device to measure different types of analyte using the appropriate resonant peak. A central-relief design is then proposed based on perturbation theory to further improve its sensing performance. The aluminum cross is covered by polyimide, which can interfere with the scattering field on the metal surface and affect the transmission results. For both transmission dips, the optimized structure realizes higher sensitivities of 111.7 GHz/RIU and 262.5 GHz/RIU, respectively. More significantly, the optimized structure also has the characteristic of a wide and non-multiplexed refractive index range. In addition, the effects of analyte thickness and polyimide layer thickness on sensor performance are also discussed. The proposed structure opens up new prospects in the design of multiple-band terahertz metamaterial sensors. It can also meet the sensing needs of biomedical, environmental monitoring, and industrial manufacturing.

2.
Phys Chem Chem Phys ; 26(11): 8993-9004, 2024 Mar 13.
Artigo em Inglês | MEDLINE | ID: mdl-38440799

RESUMO

This paper proposes a simulated design for a versatile terahertz absorber that can be actively tuned. The absorber utilizes the unique tuning capabilities of graphene and vanadium dioxide, enabling it to alternate between ultra-broadband absorption, broadband absorption, and almost complete reflection. In the metallic phase of vanadium dioxide, coupled with a graphene Fermi level at 0 eV, the absorber achieves ultra-broadband absorption. This spans an extensive frequency range from 3.85 THz to 9.73 THz, exhibiting an absorption rate surpassing 90%. As we shift to the insulating phase of vanadium dioxide and adjust the graphene Fermi level to 1 eV, the absorber operates in a broadband absorption mode. This mode spans 2.98 THz to 4.63 THz, demonstrating an absorption rate exceeding 90%. In the insulating state of vanadium dioxide with a graphene Fermi level at 0 eV, the absorber metamorphoses into a nearly total reflector. Its maximum absorption rate is a mere 0.52%. The unique adjustability of vanadium dioxide and graphene independently enables the fine-tuning of absorption rates for both ultra-broadband and broadband absorption without encountering interference. Additionally, thanks to the central symmetry inherent in the proposed structure, the absorber exhibits insensitivity to alterations in polarization angles and remains stable under a broad range of incident angles. With these benefits, the absorber shows promising potential for applications in electromagnetic stealth, wireless communication, and so on.

3.
Phys Chem Chem Phys ; 25(30): 20414-20421, 2023 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-37466116

RESUMO

A tunable dual broadband switchable terahertz absorber based on vanadium dioxide and graphene is proposed. The tunability of graphene and the phase transition properties of vanadium dioxide are used to switch broadband absorption between low-frequency and high-frequency, as well as the absorption rate tuning function. The simulation results indicate that when vanadium dioxide is in the insulating phase and the graphene Fermi energy is 0.7 eV, the absorber achieves low-frequency broadband absorption within the range of 2.6-4.2 THz with an absorptance greater than 90%; when vanadium dioxide is in the metallic phase and the graphene Fermi energy is 0 eV, the absorber achieves high-frequency broadband absorption within the range of 4.9-10 THz with an absorptance greater than 90%. Furthermore, the absorptance can be tuned by adjusting the conductivity of vanadium dioxide or the Fermi energy of graphene. Due to the central symmetry of the proposed structure, the absorber is completely insensitive to polarization. For TE and TM polarized waves, both low and high-frequency broadband absorption are maintained over a range of incident angles from 0° to 50°. The simple structure, tunable absorption rate, insensitivity to polarization angle and incident angle properties are advantages of our proposed absorber. It has broad application prospects in adjustable filters and electromagnetic shielding.

4.
Chem Commun (Camb) ; 57(15): 1939-1942, 2021 Feb 23.
Artigo em Inglês | MEDLINE | ID: mdl-33501475

RESUMO

Formamidine-based hybrid perovskite is an excellent optoelectronic material; however, its intrinsic non-layered crystalline structure makes it hard to isolate the corresponding 2D counterparts. In this work, a unique liquid-epitaxy technique was introduced to grow micro-sized two-dimensional FAPbX3 perovskite sheets. Such ultrathin sheets exhibited excellent photo-induced carrier properties with high crystalline quality, as well as provided new opportunities for next-generation optoelectronic devices.

5.
Nanoscale ; 12(2): 1100-1108, 2020 Jan 02.
Artigo em Inglês | MEDLINE | ID: mdl-31845949

RESUMO

The hybrid perovskite CH3NH3PbX3 (X = Cl, Br, I) is a promising material for developing novel optoelectronic devices. Due to its intrinsic non-layered crystal structure, it remains challenging to synthesize two-dimensional (2D) single-crystalline CH3NH3PbX3 with nanoscale thickness. Here, we report a bottom-up approach to fabricate large CH3NH3PbX3 2D crystals via liquid-phase growth on a mica substrate. The strong potassium-halogen interactions at the perovskite/mica interface decrease the interface energy, driving the striking in-plane growth of the perovskite. The grown 2D CH3NH3PbBr3 crystal was characterized as 8 nm in thickness and hundreds of micrometers in lateral size. Weak exciton binding energy was crucial for improving the photoelectric performance of 2D CH3NH3PbBr3. A visible-light photodetector with a metal/insulator/perovskite configuration was finally achieved with a photoresponsivity of 126 A W-1 and a bandwidth exceeding 80 kHz. Our work proves that the liquid-phase growth on mica is a controllable method to grow 2D hybrid CH3NH3PbX3 perovskites, which can facilitate both device applications and fundamental investigations.

6.
Int J Environ Res Public Health ; 13(4): 408, 2016 Apr 08.
Artigo em Inglês | MEDLINE | ID: mdl-27070631

RESUMO

In this study, the Mudan River, which is the most typical river in the northern cold region of China was selected as the research object; Environmental Fluid Dynamics Code (EFDC) was adopted to construct a new two-dimensional water quality model for the urban sections of the Mudan River, and concentrations of COD(Cr) and NH3N during ice-covered and open-water periods were simulated and analyzed. Results indicated that roughness coefficient and comprehensive pollutant decay rate were significantly different in those periods. To be specific, the roughness coefficient in the ice-covered period was larger than that of the open-water period, while the decay rate within the former period was smaller than that in the latter. In addition, according to the analysis of the simulated results, the main reasons for the decay rate reduction during the ice-covered period are temperature drop, upstream inflow decrease and ice layer cover; among them, ice sheet is the major contributor of roughness increase. These aspects were discussed in more detail in this work. The model could be generalized to hydrodynamic water quality process simulation researches on rivers in other cold regions as well.


Assuntos
Modelos Teóricos , Rios , Qualidade da Água , Amônia/análise , Análise da Demanda Biológica de Oxigênio , China , Temperatura Baixa , Monitoramento Ambiental , Hidrodinâmica , Rios/química , Movimentos da Água , Poluentes Químicos da Água/análise
7.
Zhonghua Wei Chang Wai Ke Za Zhi ; 16(6): 555-60, 2013 Jun.
Artigo em Chinês | MEDLINE | ID: mdl-23801210

RESUMO

OBJECTIVE: To investigate the value of incidental focal (18)F-FDG uptake in the colon and rectum and characteristics of functional anatomic form for differential diagnosis of colorectal benign or malignant diseases. METHODS: Clinical data and images of incidental focal hypermetabolism focus in colon and rectum of 37 individuals undergoing (18)F-FDG PET-CT were analyzed retrospectively. According to the eventual outcomes of pathological examination and clinical follow-up, these cases were divided into four subgroups: malignant disease, benign tumor (including precancerous change), inflammation and physiological uptake. Radioactive uptake level (SUVmax) and change of delayed imaging (RI) of focal hypermetabolism focus were compared between groups. The data analysis was performed using variance analysis. RESULTS: The average SUVmax was 6.3±3.7, 8.8±6.5, 5.2±1.4, and 3.8±0.9 in malignant disease (n=11), benign (precancerous) tumor (n=9), inflammation (n=9) and physiological uptaking (n=8) respectively. The average SUVmax was 7.6±5.6 in benign and malignant tumor, and 4.7±1.5 in inflammation and physiological uptake. The distinction of average SUVmax was not statistically significant between benign and malignant tumor or inflammation and physiological uptake. But it was higher in tumors as compared to inflammation or physiological uptake with a statistically difference (P<0.05). The RI was 0.3±0.2, 0.4±0.1, 0.3±0.2, 0.4±0.2 in above 4 groups respectively, and the differences were not statistically significant. CONCLUSIONS: The incidental focal hypermetabolism focus in the colon the rectum during (18)F-FDG PET-CT may indicate potential colorectal malignant diseases and precancerous lesions. SUVmax value in focal hypermetabolism focus in the colon and rectum can help to distinguish tumor from inflammation or physiological uptake. But there is no diagnostic value for distinguishing malignant disease from benign tumor.


Assuntos
Doenças do Colo/diagnóstico por imagem , Tomografia por Emissão de Pósitrons/métodos , Doenças Retais/diagnóstico por imagem , Adulto , Idoso , Idoso de 80 Anos ou mais , Diagnóstico Diferencial , Feminino , Fluordesoxiglucose F18 , Humanos , Masculino , Pessoa de Meia-Idade , Estudos Retrospectivos
8.
Huan Jing Ke Xue ; 33(7): 2438-43, 2012 Jul.
Artigo em Chinês | MEDLINE | ID: mdl-23002624

RESUMO

The transport processes of low-level radioactive liquid effluent of Xianning nuclear power station in the closed water body Fushui Reservoir are simulated using the EFDC model. Six nuclides concentration distribution with different half-lives in the reservoir are analyzed under the condition of 97% guarantee rate incoming water and four-running nuclear power units. The results show that the nuclides concentration distribution is mainly affected by the flow field of the reservoir and the concentration is decided by the half-lives of nuclide and the volume of incoming water. In addition, the influence region is enlarged as increasing of half-life and tends to be stable when the half-life is longer than 5 years. Moreover, the waste water discharged from the outlet of the nuclear power plant has no effect on the water-intake for the outlet located at the upstream of the water-intake and the flow field flows to the dam of the reservoir.


Assuntos
Modelos Teóricos , Centrais Nucleares , Poluentes Radioativos/análise , Eliminação de Resíduos Líquidos/métodos , China , Simulação por Computador , Monitoramento Ambiental , Meia-Vida , Hidrodinâmica , Análise Numérica Assistida por Computador , Águas Residuárias/química
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