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1.
ACS Nano ; 15(4): 6765-6773, 2021 Apr 27.
Artigo em Inglês | MEDLINE | ID: mdl-33848131

RESUMO

Expanding nanomagnetism and spintronics into three dimensions (3D) offers great opportunities for both fundamental and technological studies. However, probing the influence of complex 3D geometries on magnetoelectrical phenomena poses important experimental and theoretical challenges. In this work, we investigate the magnetoelectrical signals of a ferromagnetic 3D nanodevice integrated into a microelectronic circuit using direct-write nanofabrication. Due to the 3D vectorial nature of both electrical current and magnetization, a complex superposition of several magnetoelectrical effects takes place. By performing electrical measurements under the application of 3D magnetic fields, in combination with macrospin simulations and finite element modeling, we disentangle the superimposed effects, finding how a 3D geometry leads to unusual angular dependences of well-known magnetotransport effects such as the anomalous Hall effect. Crucially, our analysis also reveals a strong role of the noncollinear demagnetizing fields intrinsic to 3D nanostructures, which results in an angular dependent magnon magnetoresistance contributing strongly to the total magnetoelectrical signal. These findings are key to the understanding of 3D spintronic systems and underpin further fundamental and device-based studies.

2.
Phys Chem Chem Phys ; 23(2): 1727-1737, 2021 Jan 21.
Artigo em Inglês | MEDLINE | ID: mdl-33427842

RESUMO

Focusing on the potential applications of tailored graphene nanoribbons (t-GNRs), in this work, we systematically study size effects on the electronic transport in t-GNR-based molecular junctions. As a result of the manufacturing error generated during the processing or synthesis of t-GNRs using techniques such as ion beam lithography, the final dimensions of the as-fabricated devices often deviate from the design values, giving rise to a size distribution around the mean value which could considerably affect the device performance. To simulate the effects of the manufacturing error, a series of t-GNR-based junctions with various dimensions have been modelled and systematically investigated using density functional theory (DFT) coupled with the non-equilibrium Green's function (NEGF). For junctions that consist of an acene chain connected with two graphene nanosheets, it is found that the chain length has little influence on the electronic transport and that, on the other hand, the junction conductivity is significantly altered by its width due to the different number and nature of the electron transfer pathways. Furthermore, increasing the width of the junction leads to a clear odd-even variation of decreasing amplitude in its transport behavior. These findings underpin further fundamental and device-based studies of t-GNRs.

3.
Sci Rep ; 8(1): 13865, 2018 Sep 11.
Artigo em Inglês | MEDLINE | ID: mdl-30206372

RESUMO

A correction to this article has been published and is linked from the HTML and PDF versions of this paper. The error has been fixed in the paper.

4.
Sci Rep ; 8(1): 6607, 2018 Apr 26.
Artigo em Inglês | MEDLINE | ID: mdl-29700337

RESUMO

Existing techniques for patterning metallic structures on elastomers are limited in terms of resolution, yield and scalability. The primary constraint is the incompatibility of their physical properties with conventional cleanroom techniques. We demonstrate a reliable fabrication strategy to transfer high resolution metallic structures of <500 nm in dimension on elastomers. The proposed method consists of producing a metallic pattern using conventional lithographic techniques on silicon coated with a thin sacrificial aluminium layer. Subsequent wet etching of the sacrificial layer releases the elastomer with the embedded metallic pattern. Using this method, a nano-resistor with minimum feature size of 400 nm is fabricated on polydimethylsiloxane (PDMS) and applied in gas sensing. Adsorption of solvents in the PDMS causes swelling and increases the device resistance, which therefore enables the detection of volatile organic compounds (VOCs). Sensitivity to chloroform and toluene vapor with a rapid response (~30 s) and recovery (~200 s) is demonstrated using this PDMS nano-resistor at room temperature.

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