RESUMO
The objective of this paper is to investigate the coupling effect of cement and organosilicon hydrophobic agents on the water resistance of phosphogypsum. Different weight ratios of Portland cement were added to adjust the alkalinity of this system and further improve the work efficiency of the organosilicon hydrophobic agents. Some macroscopic performances, such as the water absorption, the compressive strength, the flexural strength, and the softening coefficient, were measured to characterize the water-resistance of phosphogypsum. The microscopic characteristics were analyzed via contact angle tests, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) to understand the mechanism of organosilicon hydrophobicity. The results indicated that both the compressive and flexural strengths of phosphogypsum first increased and then decreased with the increase of organosilicon hydrophobic agents. Meanwhile, the surface contact angle continued to increase and the softening coefficient exhibited an obvious increase. When the hydrophobic agent was combined with Portland cement, the softening coefficient of phosphogypsum further increased from 0.80 to 0.99, while the water absorption rate was significantly reduced from 16.0% to 0.8%. Microscopic tests proved that the hydrophobic organic molecules can be polymerized under the high alkalinity, and promote the formation of a hydrophobic film, thus significantly improving the water-resistance of phosphogypsum.
RESUMO
Carbon fiber dispersion has a substantial influence on the properties of amorphous calcium silicate hydrate-based contact-hardening composites. In this study, a mixture of carbon fiber and calcium silicate hydrate powder was compressed into solid composites at 40 MPa for one minute. The mechanical properties and electrical resistivity of the solid materials were measured, and the dispersion of carbon fibers was quantitatively evaluated by digital image processing technology. The Taipalu model was used to build the correlation between the electrical resistivity of the composites and the carbon fiber dispersion. The results of the electrical resistivity showed that the down threshold of carbon fiber content in the contact-hardening composites was 1.0 wt.% and the electrical resistivity was 30,000 Ω·cm. As the fiber content increased to 2.0 wt.%, the electrical resistivity dropped to 2550 Ω·cm, which was attributed to the increase in fiber dispersion uniformity in the solid composites, and the value of the fiber distribution coefficient reached a maximum value of 0.743. A subsequent decrease in the uniformity of the fiber dispersion was observed at a high fiber content. In addition, the carbon fiber content showed a slight influence on the fiber orientation in the contact-hardening composites.