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1.
Materials (Basel) ; 16(17)2023 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-37687421

RESUMO

The alkali-activated cementitious material was prepared by partially replacing slag with recycled concrete powder (RCP). The influence of RCP substitution rates (10%, 20%, 30%, 40%, and 50% mass fraction) on the performance of alkali-activated slag-RCP-based (AASR) foamed concrete was studied. The fluidity, water absorption, softening coefficient, compressive strength, flexural strength, drying shrinkage, thermal conductivity, and frost resistance of AASR foamed concrete were studied. The results show that the fluidity and softening coefficient of AASR foamed concrete decreases with the increase in RCP content, and the fluidity range is 230-270 mm. Due to the porous structure of the RCP, the water absorption of AASR increases. With the increase in the curing age, the strength of AASR foamed concrete increases. The addition of RCP reduced the mechanical properties of AASR foamed concrete. Compared with the control group, the compressive strength of AASR50 decreased by 66.7% at 28 days, and the flexural strength decreased by 61.5%. However, the 28 d compressive strength of AASR foamed concrete under all RCP replacement rates still meets the standard value (0.6 MPa). The addition of RCP effectively reduces the thermal conductivity of the AASR foamed concrete, and when the RCP content is 50%, the thermal conductivity is lowest, 0.119 W/(m·K); the drying shrinkage of the AASR foamed concrete can be improved by adding RCP, and the drying shrinkage value is lowest when the RCP is 30%, which is 14.7% lower than that of the control group. The frost resistance of AASR foamed concrete decreases with the increase in the RCP content. When the recycled micropowder content is 20-50% and after 25 freeze-thaw cycles, AASR foamed concrete has reached freeze-thaw damage.

2.
Materials (Basel) ; 16(16)2023 Aug 21.
Artigo em Inglês | MEDLINE | ID: mdl-37630010

RESUMO

The environmental and economic problems caused by gangue accumulation continue to worsen. Therefore, the implementation of a cost-effective method for utilizing gangue resources is urgent. In this study, different gangue powder (GP) contents (0%, 10%, 20%, 30%, 40%, and 50%) for mechanical-thermal activation were used to modify a fly ash-based geopolymer (FAG). Further, the effect of GP was revealed by investigating the setting time, fluidity, porosity, water absorption rate, mechanical properties, drying shrinkage, and microstructure. Results showed that the addition of GP reduced the fluidity and setting time of gangue powder-fly ash-base geopolymer (GPFAG), improved density, and decreased the water absorption rate of GPFAG. Moreover, its mechanical properties gradually improved. Compared with GPFAG0 (FAG with 0% GP), the 28-d compressive and flexural strengths of GPFAG50 (FAG with 50% GP) increased by 246.4% and 136.8%, respectively. The incorporation of GP increased the drying shrinkage. The results of XRD and FTIR analyses showed that the addition of GP increased the production of amorphous silica-aluminate gels, such as N-S-A-H and C-S-A-H. Moreover, strong Si-O-T vibrational peaks appeared in the range 743-1470 cm-1, characterizing the GPFAG strength and reaction degree.

3.
Materials (Basel) ; 16(12)2023 Jun 09.
Artigo em Inglês | MEDLINE | ID: mdl-37374474

RESUMO

Natural river sand resources are facing depletion, and large-scale mining pollutes the environment and harms humans. To utilize fly ash fully, this study used low-grade fly ash as a substitute for natural river sand in mortar. This has great potential to alleviate the shortage of natural river sand resources, reduce pollution, and improve the utilization of solid waste resources. Six types of green mortars were prepared by replacing different amounts of river sand (0, 20, 40, 60, 80, and 100%) with fly ash and other volumes. Their compressive strength, flexural strength, ultrasonic wave velocity, drying shrinkage, and high-temperature resistance were also investigated. Research has shown that fly ash can be used as a fine aggregate in the preparation of building mortar, thereby ensuring that green-building mortar has sufficient mechanical properties and better durability. The replacement rate for optimal strength and high-temperature performance was determined to be 80%.

4.
Materials (Basel) ; 15(21)2022 Oct 22.
Artigo em Inglês | MEDLINE | ID: mdl-36363001

RESUMO

To study the influence of mineral admixtures on concrete's mechanical properties after a low-temperature exposure, green concrete was prepared by mixing fly ash and slag at different replacement rates. By analysing the changes to concrete's mechanical properties and the damage layer thickness under different ambient temperatures (20, -10, -20, -30, and -40 °C), the change rule of concrete at low temperatures was explored. The results revealed that the compressive strength of concrete, containing either fly ash or slag, peaked at 30 °C; moreover, the slag concrete's flexural and splitting tensile strength peaked at -40 °C. The best mechanical properties were observed for a fly ash-to-slag ratio of 1:2 (F10S20; i.e., 10% fly ash and 20% slag) and its compressive strength at different temperatures was higher than that of concrete, containing 30% fly ash (F30) or 30% slag (S30), but the flexural and splitting tensile strength was lower than S30. Further, as the temperature decreased, the fly ash concrete's damaged layer thickness gradually increased. When the content of fly ash and slag were both 15% (F15S15), the damaged layer thickness was minimal at different low temperatures, especially at -30 °C, where the thickness was only 8.31 mm.

5.
Materials (Basel) ; 15(18)2022 Sep 09.
Artigo em Inglês | MEDLINE | ID: mdl-36143598

RESUMO

Foam concrete is fire resistant and durable and has broad applicability as a building insulation material. However, cement has high energy consumption and causes pollution, necessitating an environment-friendly cementitious material to replace the cement used to prepare foam concrete. In this study, foam concrete was prepared through chemical foaming. The influence of the foaming agent material, foam stabiliser, and fly ash on the basic properties of the foam concrete, including the dry bulk density, compressive strength, and thermal conductivity, was studied, and the pore structure was characterised. The results show that with an increase in the hydrogen peroxide (H2O2) content, the dry bulk density, compressive strength, and thermal conductivity of foam concrete decreases, whereas the pore diameter increases (0.495 to 0.746 mm). When the calcium stearate content is within 1.8%, the pore size tends to increase (0.547 to 0.631 mm). With increase in the fly ash content, the strength of foam concrete gradually decreases, and the dry bulk density first decreases and then increases. When the blending ratio of fly ash is 10-40%, the thermal conductivity gradually decreases; an extreme thermal conductivity of 0.0824 W/(m·K) appears at the blending ratio of 40%, and the dry bulk density is 336 kg/m3.

6.
Materials (Basel) ; 15(4)2022 Feb 18.
Artigo em Inglês | MEDLINE | ID: mdl-35208087

RESUMO

Concrete is prepared by substituting an equal volume of fly ash for fine aggregate, and the effect of substitution rate on its carbonation resistance is studied. Using a rapid carbonation test, the distribution law of the internal pH value of concrete with fly ash as fine aggregate (CFA) along the carbonation depth under different substitution rates (10%, 20%, 30%, and 40%) after carbonation is studied and compared with the test results of phenolphthalein solution. Then, to further clarify the damage mechanism of fly ash replacing fine aggregate on concrete carbonation, the changes in the pore structure and micromorphology of CFA after carbonation are studied by means of mercury intrusion pressure and electron microscope scanning tests. The results indicate that the carbonation depth of CFA increases gradually with increasing carbonation time. In particular, in the later stage of carbonation, the carbonation rate of concrete decreases significantly with an increase in the substitution rate. The carbonation depth XC of CFA measured by phenolphthalein solution is approximately 0.24-0.39 times of the complete noncarbonation depth measured by the pH method. The pH value test is a reliable test method that can reveal the carbonation mechanism of CFA. Carbonation can significantly reduce the proportion of more harmful holes in concrete with a large amount of fly ash, but it can also increase the proportion of less harmful and harmful holes. In general, the pore size distribution and micromorphology of concrete can be improved by replacing fine aggregates with fly ash.

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