Observational evidence for the non-suppression effect of atmospheric chemical modification on the ice nucleation activity of East Asian dust.

Airborne mineral dust triggers ice formation in clouds and alters cloud microphysical properties by acting as ice-nucleating particles (INPs), potentially influencing weather and climate at regional and global scales. Anthropogenic pollution would modify natural mineral dust during the atmospheric transport process. However, the effects of anthropogenic pollution aging on the ice nucleation activity (INA) of mineral dust remain not well-understood. In this study, we investigated the immersion mode ice nucleation properties and particle chemical characterizations of collected size-resolved Asian dust samples (eight particle size classes ranging from 0.18 to 10.0 µm), and testified the chemical modification of aged dust particles via particle chemistry and morphology analyses including the mass concentrations of particulate matter, the water-soluble ion concentrations, the mental element concentrations, and single-particle morphology. The mass fraction of Ca2+ in element Ca and the mean relative mass proportions of supermicron Ca2+ increased by 67.0 % and 3.5-11.2 % in aged Asian dust particles, respectively, suggesting the occurrence of heterogeneous reactions. On the other hand, the total INP concentrations (total NINP) and total ice nucleation active site densities (total ns(T)) were consistent between aged and normal dust particles (0.62-1.18 times) without a statistically significant difference. And the NINP and ns(T) of chemically aged supermicron dust (1.0-10.0 µm) in each particle size class were nearly equal to or slightly higher than those of normal Asian dust, which were 0.70-2.45 times and 0.64-4.34 times at -18 °C, respectively. These results reveal that anthropogenic air pollution does not notably change the INP concentrations and does not impair the INA of Asian dust. Our work provides direct observational evidence and clarifies the non-suppression effect of anthropogenic air pollution on the INA of East Asian dust, advancing the understanding of the ice nucleation of airborne aged mineral dust.

Mitigation effects of alternative aviation fuels on non-volatile particulate matter emissions from aircraft gas turbine engines: A review.

Global air transportation has grown rapidly in the past decade until the recent coronavirus pandemic. Previous research has demonstrated that particulate matter (PM) emissions from aircraft gas turbine engines can impair human health and environment, and may play a significant role in global climate change via direct absorption of solar radiation and indirect effect by their interaction with clouds. Using alternative aviation fuels (AAFs) from different sources have become a promising means to reduce aviation PM emissions and ensure energy sustainability. This work presents a review of non-volatile PM (nvPM) emission characteristics of aircraft gas turbine engines burning conventional aviation fuel (CAF) and CAF/AAF blends from recent ground and cruise tests. Current engine emission regulations, as well as available aviation PM emission prediction models and inventories are also discussed. Available nvPM emission characteristics, including particle number, particle mass, and particle size distribution (PSD), are analyzed and compared among different studies. The synthesized results indicate that burning AAFs tends to generate smaller size nvPM and reduce up to 90% nvPM number as well as 60-85% nvPM mass. The reduction is the most significant at low engine power settings, but becomes marginal at high engine power settings. The utilization of AAF blends reduces nvPM emission yet increases water vapor emission, which may promote contrail and even widespread cirrus cloud formation. Therefore, more investigation is required to quantify the potential impact of burning AAF at cruise altitudes on cloud formation and climate change. An appropriate estimation method for the particle number emissions from aircraft gas turbine engines fueled by both CAF and CAF/AAF blends is also in need aiming to establish a global aviation nvPM emission inventory and improve relevant global climate models.