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1.
ACS Omega ; 9(14): 16687-16700, 2024 Apr 09.
Artigo em Inglês | MEDLINE | ID: mdl-38617666

RESUMO

Tunnels and shaft mining roadways are often subjected to varying degrees of asymmetric loading due to terrain relief or project excavation. In order to analyze the influence of the asymmetric degree of loading on the mechanical properties and damage rupture law of coal rock, uniaxial compression tests of coal rock under four asymmetric loading modes were carried out, the influence of the asymmetric coefficients of loading on macro- and micromechanical properties of coal and rock was analyzed, and a statistical damage constitutive model of coal and rock was established to reflect the asymmetric loading degree. The results of the study show that the peak stress of the coal rock decreases gradually with the increase in the asymmetric coefficient of loading, and the two are linear functions of each other. The distribution of the acoustic emission ringing count peak value is concentrated under uniform loading, while the acoustic emission ringing count rate presents a multipeak phenomenon under asymmetric loading, and the peak value points are scattered. In the case of asymmetric loading, the stress concentration on the edge of the upper loading plate leads to shear failure, and the microscopic cracks are concentrated near the interface between the loading zone and the nonloading zone. According to the established damage constitutive model, when the damage degree is the same, the larger the asymmetric coefficient, the smaller the strain value, which indicates that the asymmetric loading promotes the damage of coal and rock.

2.
Sci Rep ; 14(1): 8491, 2024 Apr 11.
Artigo em Inglês | MEDLINE | ID: mdl-38605150

RESUMO

The primary objective of this study was to develop soil quality indexes (SQIs) to reveal the changes in SQ during the restoration of vegetation in the reclaimed waste dumps of the Hequ open-pit coal mine. The study built an SQI evaluation model for waste dumps based on the soil management assessment framework. The total data set (TDS) consisted of nine physicochemical property indicators. The selection of the minimum data set (MDS) involved the utilization of principal component analysis (PCA) and Norm values. The SQ was comprehensively evaluated for nine indicators, taking into account the non-linear membership function and the improved Nemerow index. The findings suggested a notable disparity in the SQ between the reclaimed area and the unreclaimed area, yet the overall SQ fell short. In the TDS index system, the organic matter has the highest weight and a greater contribution to the soil quality of the waste dumps. In the MDS indicator system, the weights of organic matter and total nitrogen are both 0.5. According to Nemerow index method, the average SQIN of 5 plots is calculated to be 0.4352 ± 0.194. The average value obtained from TDS is 0.581 ± 0.236, and the average value obtained from MDS is 0.602 ± 0.351. The weighted additive method was employed to compute three SQIs, all of which yielded satisfactory outcomes. And the above evaluation methods indicate that the overall soil quality level of the waste dumps is at a moderate level. The sequence of SQ in various waste dumps was as follows: No.4lower > No.1 > No.2 > No.3 > No.4upper. Specifically, the non-linear membership function indicated that pH, available nitrogen (AN), available phosphorus (AP), surface moisture content (SMC), and bulk density (BD) were crucial in limiting SQIs in total waste dumps. The crucial limiting SQIs in unreclaimed areas were total phosphorus (TP) and total nitrogen (TN). This analysis demonstrates its efficacy in formulating strategies for the SQ evaluation and targeted soil reclamation plans of waste dumps.

3.
ACS Omega ; 9(10): 12101-12115, 2024 Mar 12.
Artigo em Inglês | MEDLINE | ID: mdl-38497005

RESUMO

To minimize errors in calculating coal flue gas adsorption capacity due to gas compressibility and to preclude prediction inaccuracies in abandoned mine flue gas storage capacity for power plants, it is imperative to account for the influence of compression factor calculation accuracy while selecting the optimal theoretical adsorption model. In this paper, the flue gas adsorption experiment of a power plant with coal samples gradually pressurized to close to 5 MPa at two different temperatures is carried out, and the temperature and pressure data obtained from the experiment are substituted into five different compression factor calculation methods to calculate different absolute adsorption amounts. The calculated adsorption capacities were fitted into six theoretical adsorption models to establish a predictive model suitable for estimating the coal adsorption capacity in power plant flue gas. Results reveal significant disparities in the absolute adsorption capacity determined by different compression factors, with an error range of 0.001278-7.8262 (cm3/kg). The Redlich-Kwong equation of state emerged as the most suitable for the flue gas of the selected experimental coal sample and the chosen composition ratio among the five compression factors. Among the six theoretical adsorption models, the Brunauer-Emmett-Teller model with three parameters demonstrated the highest suitability for predicting the adsorption capacity of coal samples in power plant smoke, achieving a fitting accuracy as high as 0.9922 at 49.7 °C.

4.
Sci Rep ; 14(1): 5909, 2024 Mar 11.
Artigo em Inglês | MEDLINE | ID: mdl-38467679

RESUMO

The mining of the protective coal seam usually produces different pressure relief effects on the different areas of protected coal seam, the reason is that the stress paths of protected seam coal body in different areas caused by mining effect are different. In order to explore the differential pressure relief damage effect of coal body under different pressure relief conditions, the stress evolution path of coal body in different areas of the protected coal seam is obtianed by using theoretical analysis and the macro-micro damage characteristics of coal body under different stress paths by using numerical simulation in this paper. The results show that: The damage characteristics of the sample models are basically the same in the in-situ stress recovery stage and the mining disturbance stage of the two stress paths. With ith the sequence of stress stages experienced by the sample model, the distribution of acoustic emission events concentrates in the high-intensity area and the porosity continues to decrease. The number of cracks increases slowly in the stage of in-situ stress recovery stage, most of which are tensile cracks, while the number of cracks increases sharply in the mining disturbance stage, most of which are shear cracks. The difference of the deformation and macro meso damage characteristics of the sample models under the two stress paths is mainly reflected in the post mining pressure relief stage. At the post mining pressure relief stage of path 1, the number of cracks in the sample has little growth, and most of them are small energy tensile cracks, and the porosity increases, which verifies its obvious pressure relief activation antireflection effect; At this stage of path 2, the crack growth of the sample is obvious, and most of them are high-energy shear cracks, and the porosity continues to decrease. Compared with path 1, the pressure relief expansion effect of the sample model is suppressed and the compression damage continues to develop in this stage of path 2.

5.
ACS Omega ; 9(1): 1156-1165, 2024 Jan 09.
Artigo em Inglês | MEDLINE | ID: mdl-38222614

RESUMO

Functional groups and small-molecule organic matter are two key parts of coal. To explore the microscopic mechanism underlying the synergistic effect of both parts on methane adsorption, the oxygen-containing (-OH, -COOH, and -C=O) and nitrogen-containing (-NH2) functional groups and two common small molecular organic matter methylbenzene and tetrahydrofuran-2-alcohol in coal are selected. The quantum chemical meta-GGA functional method is used to optimize all structures. The electrostatic potential analyses, weak interaction analyses, and theory of atoms in molecules have been used to delve further into the nature of this synergistic effect. Our results show that functional groups inhibit methane adsorption by coal molecules, and the inhibition effect is enhanced in the presence of methylbenzene. Interestingly, the synergistic effects between functional groups and small molecular organic matter are changed from inhibition to promotion after introducing tetrahydrofuran-2-alcohol, wherein -COOH has the best synergistic effect. This work not only offers a theoretical foundation for exploring the synergistic effect of small molecular organic matter and functional groups on methane adsorption by coal molecules but also lays a foundation for further research on gas prevention and extraction.

6.
PLoS One ; 18(9): e0291467, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-37768898

RESUMO

Jointed rocks under local load are ubiquitous in civil engineering. The instability and failure of jointed rocks are fatal to engineering safety. This paper numerically investigated the effects of loading area and joint angle on the strength dividing points, energy evolution, and crack distribution characteristics of non-persistent jointed rocks. The results demonstrated that the closer the absolute value of joint angle to 45° and the smaller the loading area, the lower the strength dividing points of rocks. The curves of rock joint angle versus total energy at peak and of elastic energy versus amplitude of post-peak abrupt energy change render a W-shape distribution. Meanwhile, compared with joint angle, loading area has more influence on rock energy input. The larger the loading area, the higher the crack fractal dimension, the crack entropy, and the penetration rate. Tensile cracks outnumber shear cracks when jointed rocks are damaged, and shear cracks increases significantly at the post-peak stage.

7.
Sci Rep ; 12(1): 16560, 2022 Oct 03.
Artigo em Inglês | MEDLINE | ID: mdl-36192628

RESUMO

The strength of the different materials specimens containing a central hole subjected to varying loading areas constitutes lots of underground engineering such as entry arrangement and mining process. In this study, the failure resulted from micro-fracturing in the specimen, which can be characterized by the crack propagation path if the damage events are monitored by using Digital Image Correlation (DIC), infrared thermal imager and high-speed camera. The experimental results demonstrate that there are three different types of typical failure modes for specimens with central holes according to the loading areas. The evolution of the temperature field is shown for various loading areas, the smaller loading area, the greater the stress concentration, and the more pronounced the thermodynamic features. The temperature field can also be associated with material properties in addition to loading area. Additionally, failure around the hole with redistributed stress has been observed, and strain energy density (SED) can help explain the failure mechanisms. The progressive damage process, which takes into account the heterogeneity in elastic modulus and rock strength characteristic, is demonstrated by developing a constitutive model that uses the uniaxial compression and Brazilian disc tests to parameterize it. By comparison with plastic zone, the proposed constitutive model is used to quantitatively evaluate the accumulation of damage. Failure mechanisms are established based on this work and are anticipated to be extensively utilized in engineering applications.

8.
Sci Rep ; 12(1): 7994, 2022 05 14.
Artigo em Inglês | MEDLINE | ID: mdl-35568720

RESUMO

Starting from the source of mining, scientific understanding of surface damage law and assessment method in longwall mining of shallow coal seam is conducive to solving the problems of geological hazards and deterioration of the ecological environment, and promoting the coordinated development of efficient coal mining and environmental protection. Based on numerical simulation and theoretical analysis, the surface damage process and spatiotemporal evolution of fracture field are discussed. The influencing factors and assessment method of surface damage are clarified. The results show that surface damage undergone the immediate roof caving stage, the fracture and instability stage of main roof, the spatial amplification stage of separation layer, the instability stage of surface damage control layer and the mining damage stability stage. Under the critical extraction condition, the cracks above the goaf are divided into the crack area outside the cut, the crack area inside the cut, the re-compaction area in the middle goaf, the crack area behind the longwall face, and the crack area in front of the longwall face. The overburden reaches critical failure ahead of surface critical mining. The sensitivity of loose layer thickness to surface subsidence coefficient is greater than that of mining thickness to surface subsidence coefficient. Surface damage control should be adjusted to local conditions, and finally realize zoning treatment and zoning repair. Through the three-step method of "longwall face rapid advancing method, local grouting reinforcement overburden method and zoning treatment ground fissures method", the surface damage control of 12,401 longwall face is realized. This research provides theoretical guidance and application value for surface ecological restoration in similar mining area.


Assuntos
Minas de Carvão , Carvão Mineral , Cavernas , Minas de Carvão/métodos , Simulação por Computador , Água
9.
Appl Opt ; 59(34): 10959-10966, 2020 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-33361918

RESUMO

In this paper, the digital image correlation was innovatively applied to study the deformation and damage process of raw coal and briquette under a complex stress environment. The results show that under symmetrical loading, briquette coal shows tensile failure and that the strain field goes through three stages. The raw coal shows shear failure; the stage characteristic of the strain field is not obvious. Under asymmetric loading, the strain field evolution of raw coal and briquette shows three characteristic stages, but the briquette is more likely to form a localization phenomenon. The displacement value of the crack in the shear direction is greater than that in the tension direction, so the raw coal and briquette mainly undergo shear failure. The localized starting stress is determined by the defined statistical index function, and the localized starting stress of the raw coal and the briquette coal has a quadratic function relationship with the asymmetric coefficient.

10.
ScientificWorldJournal ; 2014: 385039, 2014.
Artigo em Inglês | MEDLINE | ID: mdl-25531000

RESUMO

Taking the standard size coal block samples defined by ISRM as research objects, both properties of methane diffusion of coal block under triaxial compressive stress and characteristic influences caused by methane pressure were systematically studied with thermo-fluid-solid coupling with triaxial servocontrolled seepage equipment of methane-containing coal. The result shows the methane diffusion property of coal block under triaxial compressive stress was shown in four-stage as follow, first is sharply reduce stage, second is hyperbolic reduce stage, third is close to a fixed value stage, fourth stage is 0. There is a special point making the reduced rate of characteristic curve of methane diffusion speed become sharply small; the influences of shape of methane diffusion speed characteristic curve caused by methane pressure are not obvious, which only is shown in numerical size of methane diffusion speed. Test time was extended required by appear of the special point makes the reduce rate of methane diffusion speed become sharply small. The fitting four-phase relation of methane diffusion of coal block under triaxial compressive stress was obtained, and the idea is proposed that influences of the fitting four-phase relation caused by methane pressure were only shown in value of fitting parameters.


Assuntos
Força Compressiva , Metano/análise , Estresse Mecânico , Carvão Mineral , Difusão , Pressão
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