Causes of PM2.5 pollution in an air pollution transport channel city of northern China.

To develop effective mitigation policies, a comprehensive understanding of the evolution of the chemical composition, formation mechanisms, and the contribution of sources at different pollution levels is required. PM2.5 samples were collected for 1 year from August 2016 to August 2017 at an urban site in Zibo, then chemical compositions were analyzed. Secondary inorganic aerosols (SNA), anthropogenic minerals (MIN), and organic matter (OM) were the most abundant components of PM2.5, but only the mass fraction of SNA increased as the pollution evolved, implying that PM2.5 pollution was caused by the formation of secondary aerosols, especially nitrate. A more intense secondary transformation was found in the heating season (from November 15, 2016, to March 14, 2017), and a faster secondary conversion of nitrate than sulfate was discovered as the pollution level increased. The formation of sulfate was dominated by heterogeneous reactions. High relative humidity (RH) in polluted periods accelerated the formation of sulfate, and high temperature in the non-heating season also promoted the formation of sulfate. Zibo city was under ammonium-rich conditions during polluted periods in both seasons; therefore, nitrate was mainly formed through homogeneous reactions. The liquid water content increased significantly as the pollution levels increased when the RH was above 80%, indicating that the hygroscopic growth of aerosol aggravated the PM2.5 pollution. Source apportionment showed that PM2.5 was mainly from secondary aerosol formation, road dust, coal combustion, and vehicle emissions, contributing 36.6%, 16.5%, 14.7%, and 13.1% of PM2.5 mass, respectively. The contribution of secondary aerosol formation increased remarkably with the deterioration of air quality, especially in the heating season.

Acute cardiovascular effects of traffic-related air pollution (TRAP) exposure in healthy adults: A randomized, blinded, crossover intervention study.

Exposure to traffic-related air pollution (TRAP) may enhance the risk of cardiovascular disease. However, the short-term effects of TRAP components on the cardiovascular system are not well understood. We conducted a randomized, double-blinded, crossover intervention study in which 39 healthy university students spent 2 h next to a busy road. Participants wore a powered air-purifying respirator (PAPR) or an N95 mask. PAPRs were equipped with a filter for particulate matter (PM), a PM and volatile organic compounds (VOCs) filter or a sham filter. Participants were blinded to PAPR filter type and underwent randomized exposures four times, once for each intervention mode. Blood pressure (BP), heart rate (HR) and heart rate variability (HRV) were measured before, during and for 6 h after the roadside exposure. Linear mixed-effect models were used to evaluate the effects of the interventions relative to baseline controlling for other covariates. All HRV measures increased during and following exposure for all intervention modes. Some HRV measures (SDNN and rMSSD during exposure and SDNN after exposure) were marginally affected by PM filtration. Wearing the N95 mask affected VLF power and rMSSD responses to traffic exposure differently than the PAPR interventions. Both systolic and diastolic BP increased slightly during exposure, but then were generally lower than baseline after exposure for the sham and filter interventions. HR, which fell during exposure and mostly remained lower than baseline after exposure, was lower yet with all filter interventions compared to the sham mode following exposure. Therefore, short-term exposure to traffic acutely affects HRV, BP and HR, but N95 mask and PAPR interventions generally show little efficacy in reducing these effects. Removing the PM component of TRAP has some limited effects on HRV responses to exposure but exaggerates the traffic-related decrease in HR. HRV findings from N95 mask interventions need to be interpreted cautiously.

Aircraft-based observation of gaseous pollutants in the lower troposphere over the Beijing-Tianjin-Hebei region.

To investigate the spatial and vertical distribution of atmospheric pollutants (SO2, NOx, CO and O3), aircraft-based measurements (model: Yun-12, 12 flights, 27 h total flight time) were conducted from near the surface up to 2400 m over the Beijing-Tianjin-Hebei (BTH) region between June 17th and July 22nd 2016. The results showed that high concentrations of primary gaseous pollutants (SO2, NOx, CO) were generally present in Beijing, Tianjin, Langfang and Tangshan areas, while high values of O3 frequently appeared in areas far from the city. The flights at noon and dusk measured higher O3 concentrations at 600 m and lower O3 concentrations at higher altitudes, implying a strong influence by photochemical production. Back trajectory analysis suggested that the high levels of gaseous pollutants, especially at 600 m, were associated with pollution sources transported from the southerly direction during the observation period. The first simultaneous vertical distribution measurements using aircraft and tethered balloon were conducted in Gaocun (a rural site between Beijing and Tianjin) on June 17th. The results indicated that an inversion layer at the top of the planetary boundary layer (PBL) significantly suppressed vertical exchange through the PBL and resulted in a "two-layer" vertical distribution of pollutants above and below the PBL. Additionally, a residual high O3 layer (79.9 ± 2.5 ppb, 500-1000 m) was observed above the PBL, and it contributed to the surface peak O3 level at noon through downward transport along with the opening up of the PBL. These results indicate that coupled effects of horizontal and vertical transport should be investigated in future studies to improve the chemical transport models used to study the vertical distribution and regional transport over the BTH region.

Vertical distribution of volatile organic compounds conducted by tethered balloon in the Beijing-Tianjin-Hebei region of China.

Volatile organic compounds (VOCs) as precursors of ozone and secondary organic aerosols can cause adverse effects on the environment and human health. However, knowledge of the VOC vertical profile in the lower troposphere of major Chinese cities is poorly understood. In this study, tethered balloon flights were conducted over the juncture of Beijing-Tianjin-Hebei in China during the winter of 2016. Thirty-six vertical air samples were collected on selected heavy and light pollution days at altitudes of 50-1000 meters above ground level. On average, the concentration of total VOCs (TVOCs) at 50-100 m was 4.9 times higher than at 900-1000 m (46.9 ppbV vs. 8.0 ppbV). TVOC concentrations changed rapidly from altitudes of 50-100 to 401-500 m, with an average decrease of 72%. With further altitude increase, the TVOC concentration gradually decreased. The xylene/benzene ratios of 34/36 air samples were lower than 1.1, and the benzene/toluene ratios of 34/36 samples were higher than 0.4, indicating the occurrence of aged air mass during the sampling period. Alkenes contributed most in terms of both OH loss rate (39%-71%) and ozone formation potential (40%-72%), followed by aromatics (6%-38%). Finally, the main factors affecting the vertical distributions of VOCs were local source emission and negative dispersion conditions on polluted days. These data could advance our scientific understanding of VOC vertical distribution.

Combined use of principal component analysis and artificial neural network approach to improve estimates of PM2.5 personal exposure: A case study on older adults.

Accurate exposure estimate of the air pollutant PM2.5 is required to evaluate its health impacts in epidemiological studies, due to its adverse effects on human's respiratory and cardiovascular systems. However, traditional personal sampling is time and cost consuming. Thus, modeling techniques are needed to accurately predict the personal exposure level to PM2.5. In this study, a total of 117 older adults over 60 were recruited in Tianjin, a heavily polluted city in northern China, for indoor, outdoor and personal PM2.5 sampling. Eighteen variables which may increase the exposure level of older adults were recorded for artificial neural network (ANN) simulation. Four modeling techniques, including time-integrated activity modeling, Monte Carlo simulation, ANN modeling, and combined use of principal component analysis (PCA) and ANN model, were used to evaluate their ability for predicting real exposure values of PM2.5. The results of traditional time-weighted activity modeling showed the lowest correlation with measured values with R2 of 0.57 and 0.42 in winter and summer, respectively. For Monte Carlo simulation, high correlation was obtained (R2 of 0.93 and 0.92 in winter and summer, respectively) between percentiles of the predicted and the real exposure values. Compared with the simple ANN models, the combined use of PCA and ANN produced the most accurate results with R2 of 0.99 and RMSE lower than 15. Since the information of the input variables for the PCA-ANN model can be obtained from the questionnaire and fixed air quality monitoring sites, this technique shows a great potential in predicting personal exposure level to the air pollutant because no additional concentration measurement is needed.

[Characterization of PM10 and PM2.5 Source Profiles for Emissions from Nonmetal Mineral Products Manufacturing Processes].

In view of the insufficient source profiles for emissions from nonmetal mineral products manufacturing processes in China, a dilution sampling system was used to collect PM10 and PM2.5 samples from glassmaking, ceramics, and firebrick manufacturing sources between February and June of 2017. The characteristics of 50 chemical components in the samples were studied to identify source profiles. The results showed that the dominant composition of particulate matter in glassmaking plant profiles was Na, with percentages ranging from 9.2% to 18.5%. Ceramics profiles were enriched in Al, Si, Ca, and Fe, with percentages ranging from 1.7% to 8.7%. Refractory brick and shale manufacturing process profiles were characterized by high abundances of SO42- (36.9%-48.1%) and NH4+ (7.7%-17.0%). Chemical components in the source profiles varied with the different fuel types and desulfurization, denitrification, and dedusting methods. The coefficients of divergence (CD) between PM2.5 and PM10 from the same process were similar except for the results from the shale manufacturing process (CD values>0.3), thus indicating that the elements profiles of PM2.5 might be similar to those in PM10. Profiles of the same particle size from different processes were significantly different from one another, with CD values ranging from 0.42 to 0.76. The CD values for float glass and medicinal glass, and the CD values for the two ceramic enterprises were relatively small. The distributions of weighted differences (R/U ratios) were used to compare the differences of components between the source profiles, and results showed that the identified components for glass manufacturing, ceramic manufacturing, fireproof bricks, and page rock bricks were Na and As, Al and Ti, NO3- and NH4+, and SO42- and NH4+, respectively.

A randomized, double-blind, crossover intervention study of traffic-related air pollution and airway inflammation in healthy adults.

BACKGROUND: Traffic-related air pollution (TRAP) may increase the risk of respiratory disease. The components of TRAP that are responsible for its respiratory toxicity are largely unknown. The objective was to identify the component(s) of TRAP that cause airways inflammation using fractional exhaled nitric oxide (FENO) and randomized interventions. METHODS: A randomized, double-blind, crossover intervention study was conducted in which 39 healthy university students spent 2 hours next to a busy road. During exposure, participants wore either a powered air-purifying respirator (PAPR) or an N95 facemask. PAPRs were fitted with a fine particle (PM2.5) filter, a PM2.5 and volatile organic carbon (VOC) filter, or a sham filter, and were blinded to filter type. The four interventions (three PAPR filters and N95) were assigned randomly for each participant and separated by at least 1 week. FENO was measured before and immediately after each roadside exposure, and at 1, 2, 4, and 6 hours after exposure. RESULTS: With the sham PAPR filter, the mean postexposure FENO increased an average of 2.3 ppb (±4.4) compared with the pre-exposure level. Similar increases in FENO were seen with both the PM2.5 PAPR filter and the N95 mask, but no increase was seen with the combination PM2.5 and VOC PAPR filter. CONCLUSIONS: Because PAPR filters do not filter inorganic gases (e.g., NO2 or carbon monoxide), it is concluded that the VOC component of TRAP rather than either the particulate matter or the inorganic gases component is responsible for the airway inflammation caused by TRAP exposure.

Chemical characteristic of PM2.5 emission and inhalational carcinogenic risk of domestic Chinese cooking.

To illustrate chemical characteristic of PM2.5 emission and assess inhalational carcinogenic risk of domestic Chinese cooking, 5 sets of duplicate cooking samples were collected, using the most used 5 types of oil. The mass abundance of 14 elements, 5 water-soluble ions, organic carbon (OC), elemental carbon (EC) and 11 polycyclic aromatic hydrocarbons (PAHs) were calculated; the signature and diagnostic ratio of cooking in the domestic kitchen were analyzed; and carcinogenic risks of heavy metals and PAHs via inhalation were assessed in two scenarios. The analysis showed that OC was the primary composition in the chemical profile; Na was the most abundant element that might be due to the usage of salt; Cr and Pb, NO3- and SO42-, Phe, FL and Pyr were the main heavy metals/water-soluble ions/PAHs, respectively. Phe and FL could be used to separate cooking and stationary sources, while diagnostic ratios of BaA/(BaA + CHR), BaA/CHR, BaP/BghiP and BaP/BeP should be applied with caution, as they were influenced by various cooking conditions. Carcinogenic risks of heavy metals and PAHs were evaluated in two scenarios, simulating the condition of cooking with no ventilation and with the range hood on, respectively. The integrated risk of heavy metals and PAHs was 2.7 × 10-3 and 5.8 × 10-6, respectively, during cooking with no ventilation. While with the usage of range hood, only Cr(VI), As and Ni might induce potential carcinogenic risk. The difference in the chemical abundance in cooking sources found between this and other studies underlined the necessity of constructing locally representative source profiles under real conditions. The comparison of carcinogenic risk suggested that the potentially adverse health effects induced by inorganic compositions from cooking sources should not be ignored. Meanwhile, intervention methods, such as the operation of range hood, should be applied during cooking for health protection.

Health risk assessment for vehicle inspection workers exposed to airborne polycyclic aromatic hydrocarbons (PAHs) in their work place.

Inhalatory and dermal exposures of on-duty vehicle inspection workers to polycyclic aromatic hydrocarbons (PAHs) in Beijing were investigated from April 18 to May 17, 2011. Exposure levels to particulate PAHs for the vehicle inspection workers at gasoline, bus and diesel lines were found to be 56.07 ng m(-3), 111.72 ng m(-3) and 199.80 ng m(-3), respectively. A probabilistic risk assessment framework was integrated with the toxic equivalence factors (TEFs) and the incremental lifetime cancer risk (ILCR) approaches to quantitatively estimate the exposure risk for vehicle inspection workers of the three work lines. The median values of inhalation risk were estimated to be 3.7 × 10(-7), 5.0 × 10(-7) and 1.37 × 10(-6), respectively, while the median dermal ILCR values were 7.05 × 10(-6), 6.98 × 10(-6) and 1.28 × 10(-5), respectively for gasoline, bus, and diesel inspection workers. Total ILCR was higher than the acceptable risk level of 10(-6), indicating unacceptable potential cancer risk.