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1.
Nanoscale ; 16(7): 3379-3392, 2024 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-38227469

RESUMO

Sodium (Na) metal batteries represent an optimal choice for the forthcoming generation of large-scale, cost-effective energy storage systems. However, Na metal anodes encounter several formidable challenges during the Na plating and stripping processes, which encompass the formation of an unstable solid electrolyte interface, uncontrollable dendrite growth, and infinite volume expansion. These issues result in a reduced Coulombic efficiency, shortened battery lifespan, and potential safety hazards, thereby constraining their commercial development. Therefore, addressing these challenges to ensure the cycling stability of Na metal anodes stands as a paramount requirement for practical applications. Among the reported strategies, three-dimensional conductive scaffolds possessing a high surface area and porous structure are acknowledged for their significant potential in stabilizing Na metal anodes. Compared with conventional electron-conducting scaffolds, emerging mixed ion/electron-conductive (MIEC) scaffolds provide rapid ion/electron transport pathways, which enable uniform Na+ flux and promote dendrite-free Na deposition, thus improving the cycle life of Na metal anodes, even at high current densities and large areal capacities. Therefore, this review primarily emphasizes the recent progress in applying MIEC scaffolds to Na metal anodes. It introduces diverse design methods, examines the electrochemical performance of MIEC scaffolds, and delves into their regulation mechanisms over Na deposition behaviour. Finally, the development prospects and research strategies for MIEC scaffolds from both fundamental research and practical application perspectives are discussed, suggesting directions for further designing high-performance Na metal batteries.

2.
World J Gastrointest Surg ; 15(6): 1169-1177, 2023 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-37405107

RESUMO

BACKGROUND: Radical gastrectomy (RG) is commonly used in the treatment of patients with gastric cancer (GC), but this procedure may lead to stress responses, postoperative cognitive dysfunction, and blood coagulation abnormalities in patients. AIM: To investigate the influences of dexmedetomidine (DEX) on stress responses and postoperative cognitive and coagulation functions in patients undergoing RG under general anesthesia (GA). METHODS: One hundred and two patients undergoing RG for GC under GA from February 2020 to February 2022 were retrospectively reviewed. Of these, 50 patients had received conventional anesthesia intervention [control group (CG)] and 52 patients had received DEX in addition to routine anesthesia intervention [observation group (OG)]. Inflammatory factor (IFs; tumor necrosis factor-α, TNF-α; interleukin-6, IL-6), stress responses (cortisol, Cor; adrenocorticotropic hormone, ACTH), cognitive function (CF; Mini-Mental State Examination, MMSE), neurological function (neuron-specific enolase, NSE; S100 calcium-binding protein B, S100B), and coagulation function (prothrombin time, PT; thromboxane B2, TXB2; fibrinogen, FIB) were compared between the two groups before surgery (T0), as well as at 6 h (T1) and 24 h (T2) after surgery. RESULTS: Compared with T0, TNF-α, IL-6, Cor, ACTH, NSE, S100B, PT, TXB2, and FIB showed a significant increase in both groups at T1 and T2, but with even lower levels in OG vs CG. Both groups showed a significant reduction in the MMSE score at T1 and T2 compared with T0, but the MMSE score was notably higher in OG compared with CG. CONCLUSION: In addition to a potent inhibitory effect on postoperative IFs and stress responses in GC patients undergoing RG under GA, DEX may also alleviate the coagulation dysfunction and improve the postoperative CF of these patients.

3.
Sci Total Environ ; 849: 157862, 2022 Nov 25.
Artigo em Inglês | MEDLINE | ID: mdl-35934044

RESUMO

Bioavailability-based probabilistic risk assessment is an effective approach for risk characterization of trace metals towards aquatic species. However, it has not been routinely applied in lake management due to limited research. In this study, Chaohu Lake (Anhui Province, China) was selected as a case study, and total and bioavailable concentrations of trace metals in surface sediment were investigated using chemical extraction and diffusive gradients in thin films (DGT). Probabilistic risk assessment (PRA) was performed using Monte Carlo simulation. In addition, the species sensitivity distribution (SSD) was constructed using acute toxicity data to model the sensitivity of aquatic species towards metals. Three evaluation methods, namely, toxic units based on total content, modified potential ecological risk index (RI) based on chemical fractionation and DGT-SSD coupled PRA, were implemented and compared. Results showed that trace metals, especially Cd, were significantly affected by anthropogenic activities. Chemical fractionation analysis revealed that the majority of Cd was readily available to aquatic organisms, while Cr was stable under normal conditions. Toxic units based on the total content demonstrated that metals in sediment were at 91.6 % low and 8.4 % medium toxicity levels, while the modified RI based on chemical fractionation found toxicity levels of 84.1 % low and 15.9 % medium. Furthermore, the combined toxicity calculated from DGT-SSD coupled PRA showed that trace metals in sediment had a 24.8 % probability of toxic effects towards aquatic organisms, with Cu, Zn, Cd, and Ni being the main contributors. Comparative analysis suggested that the DGT-SSD coupled PRA could provide a more objective and scientific evidence for lake management with regard to metal contamination.


Assuntos
Metais Pesados , Oligoelementos , Poluentes Químicos da Água , Organismos Aquáticos , Disponibilidade Biológica , Cádmio/análise , China , Monitoramento Ambiental/métodos , Sedimentos Geológicos/química , Lagos/química , Metais Pesados/análise , Medição de Risco , Oligoelementos/análise , Poluentes Químicos da Água/análise
4.
Environ Pollut ; 305: 119325, 2022 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-35439598

RESUMO

The Nanfei River was one of dominant inflowing rivers of the fifth largest freshwater Chaohu Lake in China, which had been subjected to increasing nutrients and contaminants from population expansion, rapid industrialization and agricultural intensification in recent decades. In present study, surface sediment from the Nanfei River was collected to investigate the anthropogenic impact on distribution and bioavailability of heavy metals. Possible Cd sources along the river were constrained by using Cd isotope signatures and labile concentrations of heavy metals in sediment were determined through the DGT technique for risk assessment. Results showed that Cd in river sediment showed greatest enrichment (EF 0.8-9.4), indicating massive pollution from anthropogenic activities. Among the various possible Cd source materials, urban road dust, industrial soil and chicken manure, displayed higher Cd abundance and enrichment that might contribute to Cd accumulation in river sediment. Cadmium isotopic composition in river sediment was ranged from -0.21 ± 0.01‰ to 0.13 ± 0.03‰, whereas yielded relative variation from -0.31 ± 0.02‰ to 0.23 ± 0.01‰ in source materials. Accordingly, Cd sources along the river were constrained, i.e. traffic and industrial activities in the upper and middle reaches whereas agricultural activities in the lower reaches. Furthermore, the evaluation on ecological risk of heavy metals in sediment on basis of SQGs and DGT-labile concentrations demonstrated that Pb and Zn might pose higher risk on aquatic species. The present study confirmed that Cd isotopes were promising source tracer in environmental studies.


Assuntos
Metais Pesados , Poluentes Químicos da Água , Cádmio , China , Monitoramento Ambiental/métodos , Sedimentos Geológicos , Isótopos , Metais Pesados/análise , Medição de Risco , Rios , Poluentes Químicos da Água/análise
5.
Clin Pediatr (Phila) ; 61(2): 150-158, 2022 02.
Artigo em Inglês | MEDLINE | ID: mdl-34753343

RESUMO

Background. This case-control study aims to investigate the clinical characteristics in pediatric patients with pneumonia infected with severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), influenza A, and human adenoviruses (HAdVs). Methods. Hospitalized pediatric patients with pneumonia infected with SARS-CoV-2 at Wuhan Children's Hospital and pneumonia infected with influenza A, and HAdVs at Qilu Children's Hospital were compared. Clinical manifestations, laboratory examinations, and imaging characteristics were analyzed. Results. The proportions of hyperpyrexia (54.3%, 33.9%), cough (100%, 99.2%), wheezing (45.7%, 53.7%), diarrhea (31.4%, 14.9%), and fever (100%, 75.2%) in patients with influenza A and HAdVs were higher than those of patients with SARS-CoV-2 (9.4%, P < .001; 48.5%, P < .001; 0%, P < .001; 8.8%, P = .002; 41.5%, P < .001; respectively). Laboratory examinations revealed the proportions of leukocytosis (37.1%, 52.9%), abnormal rates of neutrophils (40%, 40.5%), and lymphocytosis (42.9%, 65.3%) in influenza A and HAdV pneumonia groups were significantly higher than coronavirus disease 2019 (COVID-19) group (0%, P < .001; 0%, P < .001; 0%, P < .001; respectively). The proportion of elevated procalcitonin (5.7%, 14%) in patients with influenza A and HAdVs was significantly lower than those in patients with SARS-CoV-2 (64%, P < .001). In chest computed tomography, ground-glass opacities near the pleura were more common in patients with COVID-19 than those in patients with influenza A and HAdVs (32.7% vs 0% vs 0%, P < .001). Conclusion. Fever, cough, and wheezing are more common in the influenza A and HAdVs groups, whereas procalcitonin and computed tomography findings are likely to be pronounced in COVID-19 pneumonia. It provides a variety of methods except polymerase chain reaction for differentiating COVID-19 pneumonia from influenza A and HAdVs pneumonia.


Assuntos
Infecções por Adenovirus Humanos/fisiopatologia , COVID-19/fisiopatologia , Criança Hospitalizada/estatística & dados numéricos , Influenza Humana/fisiopatologia , Pneumonia/fisiopatologia , Infecções por Adenovirus Humanos/epidemiologia , Adolescente , COVID-19/epidemiologia , Estudos de Casos e Controles , Criança , Pré-Escolar , China/epidemiologia , Feminino , Humanos , Lactente , Recém-Nascido , Vírus da Influenza A/patogenicidade , Influenza Humana/epidemiologia , Masculino , Pneumonia/epidemiologia , Pneumonia/etiologia , Estudos Retrospectivos
6.
Environ Monit Assess ; 193(3): 151, 2021 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-33641075

RESUMO

Air and dust borne heavy metals can be deposited and bioaccumulated by plants; therefore, biomonitoring employing plants is an effective tool for environmental impact assessment in urban environments. In this study, in addition to road dust, leaves and bark were collected from four common tree species at roadside and urban park sampling sites within the metropolitan area of Hefei, China. A range of heavy metals were analyzed by ICP-MS and AFS. The metal accumulation index (MAI) was adopted to compare the bioaccumulation capacity. Results showed that Cd was highly enriched in road dust although its abundance was low in comparison with that of other elements. The MAI values presented a narrow range (1.8-2.7); however, significant differences (p < 0.05) were found for Al, Cu, Zn, and As among the tree species. Moreover, deciduous Platanus orientalis bioaccumulated more nonessential As than the other species and deserved further risk management. In addition, bark samples from Cinnamomum camphora bioaccumulated more heavy metals than the other species as a result of its morphological and anatomical characteristics. The distribution patterns of heavy metals in tree tissues showed obvious spatial heterogeneity, as impacted by anthropogenic activities to varying degrees. This study examined the biomonitoring potential of roadside trees and the distribution pattern of heavy metals in an urban area under rapid development. Results from the present study could provide baseline data for urban environmental impact assessment and the design of green belts.


Assuntos
Metais Pesados , Árvores , Monitoramento Biológico , China , Cidades , Poeira/análise , Monitoramento Ambiental , Metais Pesados/análise
8.
Environ Sci Pollut Res Int ; 26(29): 29585-29596, 2019 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-31440974

RESUMO

An exhaustive overview of heavy metal pollution in Chaohu Lake illustrating enrichment intensity, temporal and spatial distribution, chemical speciation, and ecological risk under natural and anthropogenic changes was conducted. Low concentrations of heavy metals excluding Hg were found in water whereas high Hg might be ascribed to surrounding coal-fired power plants. Copper, Pb, Zn, Cd, and Hg were enriched in sediment whereas Cr and Ni were comparable to background values. Besides, As demonstrated an equal accumulation from natural and anthropogenic fluxes. Heavy metals were at a low level prior to the 1950s; it increased gradually during the 1950s-1960s owing to population growth and agricultural expansion; then it displayed abrupt increase since the late 1970s due to rapid modern urbanization and industrialization and agricultural intensification. Spatial distribution of heavy metals was a good indicator of natural and anthropogenic changes, where higher enrichment was found in the western lake. Apart from fluvial input, anthropogenic disturbances such as land use changes, atmospheric deposition, and algae-derived organic matter, along with natural stressors including climate change, hydrological alteration, and soil erosion, made significant contribution to the biogeochemical cycle of heavy metals in the lake. Heavy metals mainly from anthropogenic sources were dominantly partitioned in non-residual fractions, whereas those mainly from natural sources were predominantly distributed in residual form. Mercury and Cd were below the threshold effect concentration (TEC) indicating that adverse effects were excluded. However, result of chemical speciation demonstrated Cd would pose a considerable potential ecological risk. Besides, most of the heavy metals were in the range of TEC-PEC suggesting possible toxicity.


Assuntos
Sedimentos Geológicos/análise , Lagos/análise , Metais Pesados/análise , Poluentes Químicos da Água/análise , China , Monitoramento Ambiental , Sedimentos Geológicos/química , Indústrias , Lagos/química , Solo , Análise Espaço-Temporal , Urbanização
9.
Chemosphere ; 218: 1122-1130, 2019 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-30414697

RESUMO

Chaohu Lake is one of the five largest freshwater lakes in China situated in Anhui Province. Water, sediment and aquatic organisms were collected from Chaohu Lake. Trace metals were measured to investigate their bioaccumulation pattern and trophic transfer in the food web as well as potential health risk assessment through fish consumption. Trophic interactions were investigated by stable nitrogen isotope. Linear regression of log metal concentration versus δ15N was used to determine whether there is biomagnification or biodilution. Results showed that concentrations of trace metals in water were rather low except Hg, some of which surpassed the scope of quality standard. Trace metals in sediment exceeded background values nevertheless within the range for the protection of aquatic life. Therein, geochemical fractionation showed that Cd would pose a considerable potential ecological risk. Trace metals were higher in plankton except for Cu and Zn was higher in shrimp due to metabolic needs. Decreasing trend was observed in Pb, Cr, Cd, As and Hg levels with increasing trophic level whereas increasing trend was observed in Zn. Trace metals in fish were lower than legislation thresholds except for Cr in two samples that exceeded the threshold value. Nonetheless, total target hazard quotient values and target cancer risk were lower than unit and within acceptable range, indicating there was no health risk for inhabitants from trace metals through fish consumption.


Assuntos
Cadeia Alimentar , Lagos/química , Oligoelementos/análise , Animais , China , Monitoramento Ambiental , Peixes/metabolismo , Metais Pesados/análise , Medição de Risco , Poluentes Químicos da Água/análise
10.
Chemistry ; 25(9): 2330-2336, 2019 Feb 11.
Artigo em Inglês | MEDLINE | ID: mdl-30549117

RESUMO

As one of the most efficient systems for photocatalytic hydrogen evolution, the Z-Scheme system, consisting of different semiconductors with a reversible donor-acceptor pair, has attracted great attention. Considering the non-toxicity and low cost of photocatalysts, a series of g-C3 N4 /α-Fe2 O3 hybrids were rationally constructed based on the Z-Scheme mechanism for the first time, using a metal-organic framework template approach that can fine tune the compositions and properties of the hybrids. An optimized hybrid, g-C3 N4 /α-Fe2 O3 -2, exhibited prominent photocatalytic water splitting performance with a visible light response. Under irradiation of visible light (λ>420 nm), the hybrid shows a high durability and superior hydrogen production rate of 2066.2 µmol g-1 h-1 from water splitting, which is approximately three times greater than that of bulk g-C3 N4 because of the effective separation of photo-excited charge carriers by two narrow band gap semiconductors, tightly coupled with the Z-Scheme structural feature.

11.
Angew Chem Int Ed Engl ; 57(31): 9790-9794, 2018 Jul 26.
Artigo em Inglês | MEDLINE | ID: mdl-29888442

RESUMO

Photocatalytic water splitting for hydrogen production using sustainable sunlight is a promising alternative to industrial hydrogen production. However, the scarcity of highly active, recyclable, inexpensive photocatalysts impedes the development of photocatalytic hydrogen evolution reaction (HER) schemes. Herein, a metal-organic framework (MOF)-template strategy was developed to prepare non-noble metal co-catalyst/solid solution heterojunction NiS/Znx Cd1-x S with superior photocatalytic HER activity. By adjusting the doping metal concentration in MOFs, the chemical compositions and band gaps of the heterojunctions can be fine-tuned, and the light absorption capacity and photocatalytic activity were further optimized. NiS/Zn0.5 Cd0.5 S exhibits an optimal HER rate of 16.78 mmol g-1 h-1 and high stability and recyclability under visible-light irradiation (λ>420 nm). Detailed characterizations and in-depth DFT calculations reveal the relationship between the heterojunction and photocatalytic activity and confirm the importance of NiS in accelerating the water dissociation kinetics, which is a crucial factor for photocatalytic HER.

12.
Adv Sci (Weinh) ; 5(4): 1700590, 2018 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-29721410

RESUMO

Developing highly active, recyclable, and inexpensive photocatalysts for hydrogen evolution reaction (HER) under visible light is significant for the direct conversion of solar energy into chemical fuels for various green energy applications. For such applications, it is very challenging but vitally important for a photocatalyst to simultaneously enhance the visible-light absorption and suppress photogenerated electron-hole recombination, while also to maintain high stability and recyclability. Herein, a metal-organic framework (MOF)-templated strategy has been developed to prepare heterostructured nanocatalysts with superior photocatalytic HER activity. Very uniquely, the synthesized photocatalytic materials can be recycled easily after use to restore the initial photocatalytic activity. It is shown that by controlling the calcination temperature and time with MOF-5 as a host and guest thioacetamide as a sulfur source, the chemical compositions of the formed heterojunctions of ZnO/ZnS can be tuned to further enhance the visible-light absorption and photocatalytic activity. The nanoscale heterojunction ZnO/ZnS structural feature serves to reduce the average free path of charge carriers and improve the charge separation efficiency, thus leading to significantly enhanced HER activity under visible-light irradiation (λ > 420 nm) with high stability and recyclability without any cocatalyst.

13.
Inorg Chem ; 57(9): 5030-5037, 2018 May 07.
Artigo em Inglês | MEDLINE | ID: mdl-29667839

RESUMO

Two stable 3D polyoxometalate-based metal-organic frameworks (PMOFs), [CuI12(trz)8(H2O)2][α-SiW12O40]·2H2O (1) and [CuI12(trz)8Cl][α-PW12O40] (2) (Htrz = 1- H-1,2,4-triazole) based on Keggin-type POMs were successfully obtained and fully characterized. The basic building units of the two PMOFs are [CuI12(trz)8], but polyoxoanion (POA) template effect leads to different structures and properties: 1 represents an interesting example that [α-SiW12O40]4- locate in the nine-membered Cu-trz rings through Cu···O weak interactions to form a 3D framework, whereas 2 shows a 3D structure constructed from 2D bilayer cationic network [CuI12(trz)8Cl]3+ and [α-PW12O40]3- lying in the adjacent layers via Cu···O weak interactions. PMOF 1 as unusual visible-light photocatalyst exhibit significantly enhanced photocatalytic activity under visible-light and excellent stability during the photocatalysis process for recovering and recycling, as well as photocatalytic hydrogen evolution activity.

14.
Exp Ther Med ; 15(1): 755-760, 2018 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-29399082

RESUMO

Tuberculosis (TB), which is caused by the mycobacterium TB, is the major cause of human death worldwide. The aim of this study was to identify the biomarkers involved in child TB. Gene expression data were obtained from the Array Express Archive of Functional Genomics Data. Gene expression data and protein-protein interaction (PPI) data were downloaded to construct differential gene co-expression networks (DCNs). The Benjamini-Hochberg algorithm was used to correct the P-value. In total, 3,820 edges (PPIs) and 1,359 nodes (genes) were obtained from the human-related PPIs data and gene expression data at the criteria of absolute value of Pearson's correlation coefficient >0.8. The DCNs were formed by these edges and nodes. Thirteen seed genes were obtained by ranging z-scores. Eight significant multiple different modules were identified from DCNs using the statistical significant test. In conclusion, the seed genes and significant modules constitute potential biomarkers that reveal the underlying mechanisms in child TB. The new identified biomarkers may contribute to an understanding of TB and provide a new therapeutic method for the treatment of TB.

15.
Biomed Pharmacother ; 93: 57-61, 2017 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-28623783

RESUMO

Activation of hepatic stellate cells (HSCs) plays a critical role in liver fibrosis. Scoparone, a major constituent isolated from Artemisia capillaris, was reported to possess hepatoprotective effect. However, the role of scoparone in liver fibrosis remains unknown. In the present study, we investigated the effects of scoparone on liver fibrosis in HSCs. Our results demonstrated that scoparoene inhibited the proliferation of HSCs exposed to transforming growth factor (TGF)-ß1. In addition, scoparoene significantly suppressed TGF-ß1-induced the expression of α-smooth muscle actin (α-SMA) and collagen I in HSC-T6 cells, as well as attenuated the expression of NADPH oxidase (NOX) isoforms expression and ROS production in TGF-ß1-stimialted HSC-T6 cells. Mechanistically, scoparoene suppressed the phosphorylation level of Smad3 in TGF-ß1-stimialted HSC-T6 cells. In conclusion, these findings showed that scoparone significantly inhibited the proliferation and activation of HSCs through the inactivation of TGF-ß/Smad signaling pathway. These data provide that scoparone may have potential to treat liver fibrosis.


Assuntos
Cumarínicos/farmacologia , Células Estreladas do Fígado/efeitos dos fármacos , Transdução de Sinais/efeitos dos fármacos , Proteína Smad3/metabolismo , Fator de Crescimento Transformador beta1/metabolismo , Actinas/metabolismo , Animais , Linhagem Celular , Proliferação de Células/efeitos dos fármacos , Colágeno Tipo I/metabolismo , Células Estreladas do Fígado/metabolismo , Cirrose Hepática/tratamento farmacológico , Cirrose Hepática/metabolismo , NADPH Oxidases/metabolismo , Fosforilação/efeitos dos fármacos , Ratos
16.
Environ Sci Pollut Res Int ; 24(18): 15390-15400, 2017 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-28508333

RESUMO

Chaohu Lake is the fifth largest freshwater lake in China, which tolerates substantial amount of anthropogenic discharge from surrounding cities that resulting in the degradation of water and damage of aquatic ecosystem. Metal analysis of sediment and aquatic organisms can provide important information on the environmental contamination and potential impact of aquatic food consumption. Thus, the concentrations of Cu, Pb, Zn, Cr, Cd, As, and Hg in sediment and fish from Chaohu Lake were analyzed with inductively coupled plasma mass spectrometry and atomic fluorescence spectrometry. The mean content of Cu, Pb, Zn, Cr, Cd, As, and Hg in the sediment samples were 27.4 ± 6.3, 40.5 ± 12.3, 136.8 ± 65.5, 68.5 ± 9.1, 0.357 ± 0.141, 10.8 ± 1.7, and 0.117 ± 0.049 mg/kg, respectively. The results were compared with background values and evaluation methods, to characterize the potential ecological risk. The concentrations of Cu, Pb, Zn, Cr, Cd, As, and Hg in the fish muscle samples were 1.68-5.31, 0.078-0.31, 15.55-372.98, 0.31-0.93, 0.001-0.033, 0.29-1.03, and 0.04-0.197 mg kg-1 of dry mass, respectively. Most of the concentrations of the studied metals in muscles were found to be below the safe limits; however, the concentration of inorganic As (10% of total As) in two specimens exceeded the maximum allowance in fish. The ecological risk evaluation showed that the metals in sediment posed low to medium risk. The health risk assessment suggested that the consumption of fish from Chaohu Lake is currently safe with respect to the metals.


Assuntos
Peixes , Metais Pesados/análise , Animais , China , Monitoramento Ambiental , Contaminação de Alimentos , Sedimentos Geológicos , Humanos , Lagos , Medição de Risco , Poluentes Químicos da Água
17.
Small ; 13(9)2017 03.
Artigo em Inglês | MEDLINE | ID: mdl-27991720

RESUMO

Zeolitic imidazolate framework-8 (ZIF-8)-derived N-doped graphene analogous polyhedrons (ZNGs) obtained via the direct carbonation of ZIF-8 are applied to photocatalytic hydrogen evolution for the first time. The contents of different types of nitrogen atoms in ZNGs can be fine-tuned via the calcination temperature, which significantly influences the hydrogen evolution rate of the ZNGs.

18.
Eur J Protistol ; 53: 20-30, 2016 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-26773905

RESUMO

Previous studies have shown that ciliate plankton is generally controlled by food resources (e.g., algae) and predators (e.g., metazooplankton). Among lakes with similar trophic levels but different distributions of phyto- and metazooplankton, the main forces acting on ciliate assemblages may be different. We investigated the relationship between ciliate communities and bottom-up versus top-down variables based on a survey of four subtropical eutrophic lakes (China). Two of the lakes (Chaohu, Taihu) are located on the Mid-lower Yangtze Plain near sea level, and the other two (Dianchi, Xingyunhu) on the Yunnan-Kweichow Plateau at 1700 m above sea level. Blooms of cyanobacteria developed during summer in Lakes Chaohu and Taihu and throughout the year in Lakes Dianchi and Xingyunhu. Ciliate functional feeding groups differed significantly between lakes. The results of canonical correspondence analysis (CCA) and variation partitioning showed that cyanobacteria significantly influence ciliate species, whereas 'edible' algae (cryptophytes, diatoms) and cladocerans were the important variables in explaining the ciliate community structure of Lakes Dianchi and Xingyunhu compared with Lakes Taihu and Chaohu. Our results highlight the importance of consistent cyanobacterial blooms in shaping the ciliate community in subtropical eutrophic shallow lakes by interacting with top-down and bottom-up factors.


Assuntos
Biodiversidade , Cilióforos/classificação , Cilióforos/fisiologia , Lagos/parasitologia , China , Criptófitas/fisiologia , Cianobactérias/fisiologia , Diatomáceas/fisiologia , Ecossistema , Eutrofização
19.
Int J Clin Exp Med ; 8(3): 4545-50, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-26064382

RESUMO

Transforming growth factor beta 3 (TGFb3) was mainly expressed by liver satellite cells in the normal liver, but it may be expressed by various liver cells during liver diseases, e.g. hepatitis and cirrhosis. However, whether TGFb3 level may be used to predict development of nonalcoholic fatty liver disease (NAFLD) has not been investigated before. Here we evaluated the relationship between TGFb3 and the susceptibility for developing NAFLD by comparing the incidence rates of developing NAFLD and serum TGFb3 levels in 1322 healthy subjects without other risk factors during a 4-year period. These healthy subjects were grouped into tertiles based on their serum TGFb3 levels that were measured in 2009. After 4 years, the odds ratios (ORs) of NAFLD development were analyzed based on the tertiles of TGFb3 levels in 2013. The cumulative incidence of NAFLD was 25.3% (334/1322) after four years. The NAFLD-developing group had higher serum TGFb3 levels in 2009 than those in the group that did not develop NAFLD (554±287 pg/ml vs. 285±173 pg/ml; P=0.002). When the serum TGFb3 levels in 2009 were grouped into tertiles, we found that the incidence of NAFLD in 2013 was significantly higher with increasing tertiles (6.3%, 38.0%, and 55.7%, respectively; P<0.05). Thus, our study demonstrate that higher serum TGFb3 levels in subjects devoid of NAFLD may have a higher chance of its future development, and highlight serum TGFb3 level as a novel predictor for development of NAFLD.

20.
Environ Sci Pollut Res Int ; 22(18): 14144-56, 2015 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-25966883

RESUMO

Temporal and spatial variations in the phytoplankton community and environmental variables were investigated from February to July 2014, in the upper lake of Shengjin Lake, China. We identified 192 species of phytoplankton belonging to 8 phyla and 84 genera, of which 46.4% of Chlorophyta, 29.2% of Bacillariophyta, and 12.5% of Cyanophyta. There were 14 predominant species. Marked temporal and spatial variations were observed in the phytoplankton community. The total abundance of phytoplankton ranged from 3.66 × 10(5) to 867.93 × 10(5) cells/L and total biomass ranging from 0.40 to 20.89 mg/L. The Shannon-Wiener diversity index varied from 3.50 to 8.35 with an average of 5.58, revealing high biodiversity in the phytoplankton community. There were substantial temporal changes in the dominant species, from Bacillariophyta and Cryptophyta to Cyanophyta and Chlorophyta. Phytoplankton biomass and abundance showed a similar increasing trend from February to July. Pearson correlations and Redundancy analysis revealed that the most significant environmental factors influencing phytoplankton community were water temperature (T), transparency (SD), and nutrient concentration. The positive correlation between the key water bird areas and phytoplankton biomass indicated that the droppings of wintering water birds had an important influence on the phytoplankton community in the upper lake of Shengjin Lake.


Assuntos
Meio Ambiente , Lagos , Fitoplâncton , Análise Espaço-Temporal , Animais , Biodiversidade , Biomassa , China , Humanos , Fitoplâncton/classificação , Estações do Ano , Temperatura
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