New and highly efficient Ultra-thin g-C3N4/FeOCl nanocomposites as photo-Fenton catalysts for pollutants degradation and antibacterial effect under visible light.

The photo-Fenton reaction was widely used in the removal of pollutants in waste water, which makes it exhibit great potential in the field of environmental remediation. Hence, it is crucial to explore a new efficient and stable photo-Fenton catalyst driven by visible light. In this work, a simple two-step calcination method was used to synthesize sheet-like stacked Ultra-thin g-C3N4/FeOCl (CNF) materials. The morphology, composition, photo-Fenton performance, and antibacterial properties were systematically analyzed. Research results exhibited that the synthesized CNF catalysts showed enhanced visible light absorption capacity and excellent photo-Fenton performance. Compared with FeOCl alone, CNF displayed stronger degradation ability for rhodamine B (RhB) and could achieve 97% degradation within 9 min, which was about 10 times that of pure FeOCl. At the same time, the composite catalysts exhibited excellent antibacterial effects under photo-Fenton conditions. The antibacterial rate of CNF composite catalyst under photo-Fenton conditions can reach almost 99%, which was 3 times that of photocatalysis alone and 2 times that of Fenton alone. The heterojunction formed between Ultra-thin g-C3N4 and FeOCl promoted the separation of e- and h+. Simultaneously, the presence of e- promoted the cycle of Fe3+ and Fe2+ in FeOCl, thereby promoting the generation of hydroxyl radicals (OH) from H2O2 and improving the photo-Fenton activity to achieve the effect of degrading pollutants and antibacterial. The photo-Fenton catalysis and degradation mechanism were analyzed in detail. This work provided a theoretical basis for the application of CNF material in the removal of wastewater.

New g-C3N4/GO/MoS2 composites as efficient photocatalyst for photocathodic protection of 304 stainless steel.

Photocathodic protection is an economical and environmental metal anticorrosion method. In this research, we successfully synthesized the g-C3N4/GO (15 wt%)/MoS2 catalytic materials by a facile hydrothermal method. The results show that the as-prepared g-C3N4/GO (15 wt%)/MoS2 composites prominently enhanced photocatalytic activities for the photocathodic protection of 304 stainless steel (SS) compared with the corresponding pristine g-C3N4 and MoS2. Notably, the AC impedance results demonstrated that the Rct value of 304 SS coupled with g-C3N4/GO (15 wt%)/MoS2 decreased to 35.66 Ω•cm2, which is 29 and 37 times lower than that of g-C3N4 and MoS2 alone. In addition, g-C3N4/GO (15 wt%)/MoS2 provided the highest current density (77.19 µA•cm2) for the 304 SS, which is four times that of pristine g-C3N4. All results indicate that as-prepared g-C3N4/GO (15 wt%)/MoS2 photocatalysts have produced a distinct enhancement on photocathodic protection performance. An optimum decorating amount of MoS2 onto g-C3N4 forms heterojunctions of g-C3N4/MoS2, which favor the separation of electrons and holes efficiently. Furthermore, the addition of GO further promotes the separation and transfer of photo-induced carriers.