Molecular detection of per- and polyfluoroalkyl substances in water using time-of-flight secondary ion mass spectrometry.

Detection of per- and polyfluoroalkyl substances (PFASs) is crucial in environmental mitigation and remediation of these persistent pollutants. We demonstrate that time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a viable technique to analyze and identify these substances at parts per trillion (ppt) level in real field samples without complicated sample preparation due to its superior surface sensitivity. Several representative PFAS compounds, such as perfluorooctanesulfonic acid (PFOS), perfluorobutanoic acid (PFBA), perfluoropentanoic acid (PFPeA), perfluoheptanoic acid (PFHpA), and perfluorononanoic acid (PFNA), and real-world groundwater samples collected from monitoring wells installed around at a municipal wastewater treatment plant located in Southern California were analyzed in this work. ToF-SIMS spectral comparison depicts sensitive identification of pseudo-molecular ions, characteristic of reference PFASs. Additionally, principal component analysis (PCA) shows clear discrimination among real samples and reference compounds. Our results show that characteristic molecular ion and fragments peaks can be used to identify PFASs. Furthermore, SIMS two-dimensional (2D) images directly exhibit the distribution of perfluorocarboxylic acid (PFCA) and PFOS in simulated mixtures and real wastewater samples. Such findings indicate that ToF-SIMS is useable to determine PFAS compounds in complex environmental water samples. In conclusion, ToF-SIMS provides simple sample preparation and high sensitivity in mass spectral imaging, offering an alternative solution for environmental forensic analysis of PFASs in wastewater in the future.

Electric-Field-Induced Assembly of an Ionic Liquid-Water Interphase Enables Efficient Heavy Metal Electrosorption.

Controlling ion desolvation, transport, and charge transfer at the electrode-electrolyte interface (EEI) is critical to enable the rational design of the efficient and selective separation of targeted heavy metals and the decontamination of industrial wastewater. The main challenge is to sufficiently resolve and interrogate the desolvation of solvated metal ions and their subsequent electroreduction at the EEI and establish pathways to modulate these intermediate steps to achieve efficient energy transfer for targeted reactive separations. Herein, we obtained a predictive understanding of modulating the desolvation and electrosorption of Pb2+ cations using the hydrophobic ionic liquid 1-ethyl-3-methylimidazolium chloride (EMIMCl) in aqueous electrolyte. We revealed the formation of a compact interphase layer consisting of EMIMCl-Pb complexes under an applied electric field using operando electrochemical Raman spectroscopy, atomic force microscopy, and electrochemical impedance spectroscopy measurements combined with classical molecular dynamics simulations. A lower negative potential was shown to result in the formation of a well-oriented layer with the positive imidazolium ring of EMIMCl lying perpendicular to the electrode and the hydrophobic alkyl chain extending into the bulk electrolyte. This oriented layer, which formed from a dilute concentration of EMIMCl added to the electrolyte, was demonstrated to facilitate desolvation of incoming solvated Pb2+ cations and decrease the charge transfer resistance for Pb electrodeposition, which has important implications for the selective removal of Pb from contaminated mixtures. Overall, our findings open up new opportunities to modulate ion desolvation using hydrophobic ionic liquids in aqueous electrolytes for efficient heavy-metal separation.

Natural colloids facilitated transport of steroidal estrogens in saturated porous media: Mechanism and processes.

Steroid estrogens (SEs) as typical endocrine disrupting compounds (EDCs) are widely detected in terrestrial environment, whilst the transport of SEs in groundwater remains unwell understood. Specifically, the effects of ubiquitous natural colloids on the SEs transport are unclear in subsurface environment, especially in aquifer systems. Here, the influence of inorganic colloids (i.e. silica and illite) and organic colloids, i.e. Humic acid (HA), on the transport of estrone (E1) and estradiol (E2) in saturated porous media was studied utilizing laboratory scale column experiments. Characterization on the colloids and porous aquifer material was conducted to provide a basis for interpretation of the experimental findings. Results showed that the transport of SEs was clearly affected by the natural colloids migrating through the saturated porous media. About 38.5% of E1 and 24.6% of E2 were retained in the column when colloids were absent in the system. When transporting with silica colloids, illite colloids, and HA colloids, the transport of E1 was enhanced by 15.64%, 11.17% and 25.60%, respectively; whilst the transport of E2 was improved by 19.56%, 23.06% and 36.40%, respectively. The SEs transport enhancement by colloids depended upon not only the mobility of the colloids but also their geochemical characteristics. The organic colloids showed 1.5-2.5 times greater ability on promoting the transport of SEs than the inorganic ones tested in this study. The proposed mechanisms of nature colloids facilitated transport of SEs including competing for adsorption sites on the sand surfaces by the colloids resulting mobilization of adsorbed SEs from solid matrix, and transport of colloids as carriers for SEs.

Telemedicine for Preventing and Treating Pressure Injury After Spinal Cord Injury: Systematic Review and Meta-analysis.

BACKGROUND: Pressure injury is a common complication after a spinal cord injury. Long-term multidisciplinary follow-up is difficult after such patients have been discharged. Telemedicine promises to provide convenient and effective support for the prevention and treatment of pressure injury, but previous attempts to demonstrate that have produced inconsistent results. OBJECTIVE: The aim of this study is to evaluate the effectiveness of telemedicine in preventing and treating pressure injury among community-dwelling patients with spinal cord injury, and determine which telemedicine form is more effective. METHODS: This systematic review was performed according to the PRISMA-NMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses extension for Network Meta-Analysis) standards. Ten databases were searched to identify randomized controlled trials and quasi-experimental studies related to the effectiveness of telemedicine intervention in patients with spinal cord injury. Two researchers worked independently and blindly selected studies, extracted data, and assessed the risk of bias. The results were described as relative risk (RR) and weighted mean difference and 95% CI. RESULTS: The 35 studies comprised 25 randomized controlled trials and 10 quasi-experimental studies involving 3131 patients. The results showed that telemedicine can significantly (P<.05) reduce the incidence of pressure injury (RR 0.24, 95% CI 0.14-0.41; P<.05; I2=0%), promote faster healing (RR 0.73, 95% CI 0.62-0.85; P<.05; I2=0%), and yield lower scores on the pressure ulcer scale of healing (weighted mean difference=-1.98, 95% CI -3.51 to -0.46; P<.05; I2=0%). Cumulative ranking estimates showed that combining telemedicine with conventional intervention (93.5%) was the most effective approach. CONCLUSIONS: Telemedicine is a feasible way to prevent pressure injury among patients with spinal cord injuries. It can decrease the incidence and severity of pressure injury and accelerate patients' healing without imposing economic burden. It is best used in tandem with other, more conventional interventions. Due to the limited quality and quantity of included studies, large-scale and well-designed randomized controlled trials are warranted.

Facile Dual-Protection Layer and Advanced Electrolyte Enhancing Performances of Cobalt-free/Nickel-rich Cathodes in Lithium-Ion Batteries.

Despite cobalt (Co)-free/nickel (Ni)-rich layered oxides being considered as one of the promising cathode materials due to their high specific capacity, their highly reactive surface still hinders practical application. Herein, a polyimide/polyvinylpyrrolidone (PI/PVP, denoted as PP) coating layer is demonstrated as dual protection for the LiNi0.96Mg0.02Ti0.02O2 (NMT) cathode material to suppress surface contamination against moist air and to prevent unwanted interfacial side reactions during cycling. The PP-coated NMT (PP@NMT) preserves a relatively clean surface with the bare generation of lithium residues, structural degradation, and gas evolution even after exposure to air with ∼30% humidity for 2 weeks compared to the bare NMT. In addition, the exposed PP@NMT significantly enhances the electrochemical performance of graphite||NMT cells by preventing byproducts and structural distortion. Moreover, the exposed PP@NMT achieves a high capacity retention of 86.7% after 500 cycles using an advanced localized high-concentration electrolyte. This work demonstrates promising protection of Co-free/Ni-rich layered cathodes for their practical usage even after exposure to moist air.

Relationship between dietary niacin intake and diabetes mellitus in the National Health and Nutrition Examination Survey (NHANES) 2003-2018.

PURPOSES: Previous studies show inconsistent associations between niacin supplementation and diabetes mellitus (DM) in high-risk population, but little is known about the relationship between dietary intake of niacin and DM in the generation population. Our study aimed to explore the associations of dietary niacin intake with the risk of DM in the United States (US) adult population. METHODS: These data were derived from the National Health and Nutrition Examination Survey (NHANES) 2003-2018 of 35,606 individuals aged 20 years or older. Niacin intake and food sources were measured by two 24-h dietary recall interviews. The diagnosis of DM was established according to the American Diabetes Association (ADA) criteria. Binary logistic regression and restricted cubic spline models were applied to evaluate the association of dietary niacin intake and DM. RESULTS: Among the 35,606 individuals, the prevalence of DM was 11.47%. The full-adjusted odds ratio(aOR) of DM was 1.27(95%CI 1.06-1.52) for quartile (Q) 4 v. Q1 of dietary niacin intake. In the dose-response analysis, the shape of the association of niacin intake with the risk of DM was approximately J-shaped (non-linear, p < 0.05). Energy-adjusted niacin of 26.08 mg/day was the optimal cut-off value for predicting DM. CONCLUSIONS: High dietary niacin intake was positively associated with DM among US adults. LEVEL OF EVIDENCE: Level V: Opinions of authorities, based on descriptive studies, narrative reviews, clinical experience, or reports of expert committees.

Association of the serum transaminase with mortality among the US elderly population.

BACKGROUND AND AIM: Considering the inconsistent findings of research into the associations between serum levels of liver enzymes (alanine aminotransferase [ALT], aspartate aminotransferase [AST], and gamma-glutamyltransferase [GGT]) and mortality among elderly people, we aimed to investigate the associations of ALT, AST, GGT, and De-Ritis ratio (DRR, defined as AST/ALT) and all-cause or cause-specific mortality among the US elderly people using National Health and Nutrition Examination Surveys data. METHODS: We included 6415 elderly participants (≥ 65 years). Exclusion criteria included positive test for hepatitis B virus, hepatitis C virus, and human immunodeficiency virus infection at baseline. Multivariable-adjusted Cox regression models calculating hazard ratios (HR) and 95% confidence intervals were developed for each of the liver enzyme measures. RESULTS: All-cause cumulative mortality was 33.8%, of which 23.8% were cardiovascular disease (CVD) deaths, 15.6% were cancer deaths, and 60.6% were other cause deaths. Adjusted Cox models found increased all-cause mortality risk for low ALT (HR: 1.70), low AST (HR: 1.13), high GGT (HR: 1.25), and high DRR (HR: 1.68). Low ALT and high DRR predicted CVD mortality. Low ALT (HR: 1.91), low AST (HR: 1.16), high GGT (HR: 1.40), and high DRR (HR: 1.76) predicted other cause mortality. CONCLUSIONS: Low ALT and high DRR were associated with increased CVD and cancer mortality. All serum liver enzyme measures were associated with all-cause mortality and other cause mortality in the US elderly population. Further studies may validate these findings in other elderly populations.

Comparison of obesity indices and triglyceride glucose-related parameters to predict type 2 diabetes mellitus among normal-weight elderly in China.

PURPOSE: Although a significant proportion of type 2 diabetes mellitus (T2DM) cases arose from normal-weight individuals, studies on indicators of T2DM in normal-weight people are limited. Accordingly, this study aims to investigate the predictive value of obesity indices and triglyceride glucose-related parameters (TyG-related parameters) in T2DM among normal-weight Chinese elderly. METHODS: A total of 24,215 normal-weight Chinese elderly (age ≥ 60 years) [body mass index-BMI (18.5-23.9 kg/m2)] were included. Obesity indices and triglyceride glucose-related parameters (TyG-related parameters) included waist circumference (WC), waist-to-height ratio (WHtR), visceral adiposity index (VAI), lipid accumulation product (LAP), and TyG-related parameters (TyG, TyG-BMI, TyG-WC, and TyG-WHtR). Multivariate logistic regression analysis was performed to examine the associations between obesity- and TyG-related indices and T2DM. The areas under the curve (AUC) of the receiver-operating characteristic (ROC) curve analyses were used to evaluate and compare the predictive value of the different indices. RESULTS: The prevalence of T2DM was 14.2% in normal-weight individuals. Among the indices, TyG was significantly associated with T2DM among men and women, respectively, (adjusted odds ratio-aOR per SD 3.46; 95% CI 3.23-3.71) and (aOR per SD 3.64; 95% CI 3.43-3.86). Compared with other indices, TyG had the highest AUC value for T2DM in men (AUC: 0.818, 95% CI 0.810-0.825) and women (AUC: 0.824, 95% CI 0.814-0.833). CONCLUSIONS: TyG is an effective marker and outperforms other indices when predicting T2DM in the normal-weight Chinese elderly population. LEVEL OF EVIDENCE: Level V: Opinions of authorities, based on descriptive studies, narrative reviews, clinical experience, or reports of expert committees.

Enhanced delivery of engineered Fe-Mn binary oxides in heterogeneous porous media for efficient arsenic stabilization.

Heterogeneity in sediment and aquifer is universal, resulting in preferential flows of injected materials in the high permeability regions and forming flow by-passed zones in the low permeability regions during in-situ subsurface remediation. This adverse effect can considerably delay the completion of remedial operations and significantly increase the cost. Column experiments were designed and conducted to study the transport of starch- and starch-xanthan gum modified Fe-Mn binary oxide particles (SFM and SXFM) in saturated heterogeneous porous media and to reveal the particles' arsenic (As) stabilization performance. Fine-in-Coarse (FIC) and Coarse-in-Fine (CIF) patterns of heterogeneous packings were set up in the columns. Testing results demonstrated that starch-xanthan gum dual treatment on Fe-Mn binary oxides successfully improved the particles' migration capability in heterogeneous porous media and their distribution uniformity attributed to the profound shear thinning behavior of xanthan gum solution. The addition of xanthan gum to the system increased the viscosity and shear thinning property of the SXFM suspension, making it a better candidate for delivery. Both SFM and SXFM stabilized As in heterogeneously packed sediment collected from a contaminated site, with SXFM showing better stabilization performance than SFM. The stabilization effects of SXFM were 90.7-97.0%, compared to 82.0-95.2% of SFM.

A combined management scheme to simultaneously mitigate As and Cd concentrations in rice cultivated in contaminated paddy soil.

Paddy soils in southern China are heavily co-polluted by arsenic (As) and cadmium (Cd). The accumulation of these contaminants in rice grains may pose a high health risk. We evaluated the impact of adjusted water management practice (i.e., conventional irrigation and aerobic treatment after heading stage) and the application of two immobilization agents (i.e., CaO and Fe2O3) on the accumulation of As and Cd in rice grains of three rice varieties (i.e., Jinyou-463, Jinyou-268, and Mabayouzhan). The different schemes were tested via conducting a field experiment in paddy soil in Shaoguan, Guangdong Province, China. The results showed that the combined scheme (selecting Jinyou-268, aerobic water management after the heading stage, and 0.09% CaO and 0.5% Fe2O3 amendments) exhibited the best performance in the reduction of As and Cd accumulation in rice grains. This combined scheme decreased the grain As concentration by 26.19% and maintained the Cd at a low level (0.056 mg/kg) as compared to the use of local conventional irrigation patterns. Moreover, health risk assessment demonstrated that by applying the optimal scheme, neither As nor Cd content in rice had carcinogenic risk. However, the grain As remains at a high non-carcinogenic risk. We suggest that future field study design should fully incorporate the uncertainty of the natural environment to make the research conclusions more feasible for popularization and utilization. This study demonstrated an approach of utilizing the synergy effects of various measures for safe rice production in fields subjected to As and Cd contaminations.

Advanced Low-Flammable Electrolytes for Stable Operation of High-Voltage Lithium-Ion Batteries.

Despite being an effective flame retardant, trimethyl phosphate (TMPa ) is generally considered as an unqualified solvent for fabricating electrolytes used in graphite (Gr)-based lithium-ion batteries as it readily leads to Gr exfoliation and cell failure. In this work, by adopting the unique solvation structure of localized high-concentration electrolyte (LHCE) to TMPa and tuning the composition of the solvation sheaths via electrolyte additives, excellent electrochemical performance can be achieved with TMPa -based electrolytes in Gr∥LiNi0.8 Mn0.1 Co0.1 O2 cells. After 500 charge/discharge cycles within the voltage range of 2.5-4.4 V, the batteries containing the TMPa -based LHCE with a proper additive can achieve a capacity retention of 85.4 %, being significantly higher than cells using a LiPF6 -organocarbonates baseline electrolyte (75.2 %). Meanwhile, due to the flame retarding effect of TMPa , TMPa -based LHCEs exhibit significantly reduced flammability compared with the conventional LiPF6 -organocarbonates electrolyte.

Excretory dysfunction and quality of life after a spinal cord injury: A cross-sectional study.

AIMS AND OBJECTIVES: To determine the aspects of excretory dysfunction most influential in determining the quality of life of survivors of spinal cord injury. BACKGROUND: Excretory dysfunction is one of the most common and troublesome sequelae of spinal cord injury. Previous studies have shown that it can restrict social participation restriction, cause readmission and generally influence quality of life substantially. DESIGN: A cross-sectional survey of hospital inpatients following STOBE guidelines. METHODS: A convenience sample of 101 patients with traumatic or non-traumatic spinal cord injury were asked about their experiences of excretory dysfunction, and management and their self-perceived quality of life. Univariate analysis and multiple linear regression were performed to isolate the most important relationships. RESULTS: Only 2 of the 101 subjects professed to be unaffected by excretion dysfunction. Bladder-related dysfunction was the most frequently mentioned type of problem. Quality of life impairment was found to be most often associated with bladder accidents, bowel accidents and having more than one bladder complications. CONCLUSIONS: Excretory dysfunction substantially impacts quality of life after a spinal cord injury. Bladder accidents, bowel accidents and more than one bladder complication are factors independently influencing the quality of life of spinal cord injury survivors. RELEVANCE TO CLINICAL PRACTICE: To improve excretion-related QOL, patients' bladder and bowel self-management training should be strengthened seeking to prevent complications and reduce the risk of bladder and bowel accidents.

Enabling Ether-Based Electrolytes for Long Cycle Life of Lithium-Ion Batteries at High Charge Voltage.

Lithium-ion batteries (LIBs) with high-nickel (Ni) content LiNixMnyCozO2 (x + y + z = 1) (NMC with Ni ≥ 0.6) cathodes operated at high charge voltages have been considered as one of the most promising candidates for addressing the challenge of increasing energy density demand. Conventional LiPF6-organocarbonate electrolytes exhibit incompatibility with such cell chemistries under certain testing conditions because of the instability of electrode/electrolyte interphases. In response to this challenge, ether-based electrolytes with finely tuned structure and composition of solvation sheaths were developed and evaluated in graphite (Gr)∥NMC811 cell chemistry in 2.5-4.4 V, despite ethers being conventionally considered to be unfavorable electrolyte solvents for LIBs because of their anodic instability above 4.0 V and cointercalation into Gr electrodes. The functional ether-based electrolytes in this work enable both excellent cycle life and high rate capability of Gr∥NMC811 cells. Mechanistic studies reveal that the unique structure and composition of the solvation sheath of the functional ether electrolytes are the main reasons behind their excellent anodic stability and effective protection of the Gr electrode and, consequently, the extraordinary cell performances when operated at high charge cutoff voltages. This work also provides a feasible approach in developing highly stable functional electrolytes for high-energy density LIBs.

Benzene homologues contaminants in a former herbicide factory site: distribution, attenuation, risk, and remediation implication.

Benzene homologues often used as organic raw materials or as detergents in chemical industry are prone to accidental release into the environment which can cause serious long-term soil pollutions. In a large former herbicide factory site, we investigated 43 locations for benzene homologues contaminations in soil, soil gas, and groundwater and studied the hydrogeological conditions. An inverse distance weighted interpolation method was employed to determine the pollutants three-dimensional spatial distribution in the soils. Results showed that benzene homologues residues were mainly originated from the herbicide production workshop and that the pollution had horizontally expanded at the deeper soil layer. Contaminants had already migrated 15 m downward from ground surface. Contaminant phase distribution study showed that NAPL was the primary phase (> 99%) for the pollutants accumulated in the unsaturated zone, while it had not migrated to groundwater. The primary mechanism for contaminant transport and attenuation included dissolution of "occluded" NAPL into pore water and pollutant volatilization into soil pore space. Risk assessment revealed that the pollutants brought unacceptable high carcinogenic and non-carcinogenic risks to public health. In order to convert this former chemical processing factory site into a residential area, a remediation to the polluted production workshop sites is urgently required.

Arsenic stabilization performance of a novel starch-modified Fe-Mn binary oxide colloid.

Arsenic (As) is an environmentally hazardous contaminant and can be a serious threat to human health. In China, the remediation needs for a large number of As-contaminated sites renders a strong demand for efficient remedial reagents and cost-effective approaches. In this study, a novel starch-modified FeMn binary oxide (SFM), an amorphous colloidal material, has been synthesized as a remedial reagent and its As stabilization performance has been evaluated. A set of laboratory batch experiments were carried out with SFM of different dosages directly added into three contaminated soils to immobilize As. Results demonstrated that SFM could transform As in soil from non-specifically and specifically sorbed fractions to the more stable form bounded to amorphous iron hydrous oxides, thus reducing the As concentration in TCLP leachates by up to 93.2%. Results from adsorption tests and microscopic analysis indicated that the interactions between SFM and As are mainly controlled by adsorption, oxidation, and precipitation processes. SFM has abundant surface hydroxyl groups, with excellent adsorption properties for both As(V) and As(III), with the maximum adsorption capacities of 160.63 and 284.64 mg/g respectively at pH 7.0. The adsorption process closely fitted pseudo second-order kinetics and Freundlich isotherm model. SFM could increase soil Eh and oxidize As(III) to As(V), which facilitated the As stabilization in soil. Colloidal iron-based material directly used for stabilization in As contaminated soils is reported here for the first time. Starch modification improves both the reactivity and mobility of the stabilization agent in soil. Our findings propose an efficient and convenient reagent for As remediation in soil.

[Stabilization of Arsenic-Contaminated Soils Using Fe-Mn Oxide Under Different Water Conditions].

Fe-Mn oxide (FM) was used to evaluate its stabilization effects on three typical arsenic (As)-contaminated soils in southern China under different water conditions (dry soil, moist soil, and flooded soil). With an increase in moisture content, the toxicity characteristic leaching procedure (TCLP) results for As decreased by 34.78%, 47.62%, and 13.64%, respectively,in Shaoguan,Hechi, and Changde, and then increased by 310.34%, 185.22%, and 23.38%, respectively. The results showed that adding a certain amount of water (30%) had a positive effect on decreasing the As concentration in the TCLP, but excessive amounts (80%) led to As re-release into the soil. The application of FM under flooding conditions has obvious advantages. In the three soils of Shaoguan,Hechi, and Changde, FM significantly reduced the As concentration in the TCLP by more than 99.00%, and reduced the soil available As content by 55.40%, 40.05%, and 16.92%, respectively. FM increased the specificandnon-specific adsorption of As to stabilize the bound fractions of hydrated iron-aluminum oxide, thus significantly reducing the biological effectiveness of soil As and soil environmental risk.FM reduced the available P in the soil in Shaoguan,Hechi, and Changde by 0.60%-6.67%, 15.74%-50.00%, and 32.48-40.39%, respectively. Our study revealed that FM can absorb a small amount of available P, which may limit P uptakeby agricultural products in P-deficient areas, while effectively inhibiting the non-point source pollution of soil to surrounding water bodiesin P-rich areas. The variation in pH after FM application in the three soils was only 0.04-0.07, which had little effect on the soil environment. FM has good prospects for stabilization of flooded As-contaminated soil. The results of this study provide an important scientific basis for soil As stabilization in China.

Microbial Methylation of Iodide in Unconfined Aquifer Sediments at the Hanford Site, USA.

Incomplete knowledge of environmental transformation reactions limits our ability to accurately inventory and predictably model the fate of radioiodine. The most prevalent chemical species of iodine include iodate (IO3 -), iodide (I-), and organo-iodine. The emission of gaseous species could be a loss or flux term but these processes have not previously been investigated at radioiodine-impacted sites. We examined iodide methylation and volatilization for Hanford Site sediments from three different locations under native and organic substrate amended conditions at three iodide concentrations. Aqueous and gaseous sampling revealed methyl-iodide to be the only iodinated compound produced under biotic conditions. No abiotic transformations of iodide were measured. Methyl-iodide was produced by 52 out of 54 microcosms, regardless of prior exposure to iodine contamination or the experimental concentration. Interestingly, iodide volatilization activity was consistently higher under native (oligotrophic) Hanford sediment conditions. Carbon and nutrients were not only unnecessary for microbial activation, but supplementation resulted in >three-fold reduction in methyl-iodide formation. This investigation not only demonstrates the potential for iodine volatilization in deep, oligotrophic subsurface sediments at a nuclear waste site, but also emphasizes an important role for biotic methylation pathways to the long-term management and monitoring of radioiodine in the environment.

Reducing Arsenic Concentration in Panax notoginseng via Contaminant Immobilization in Soil Using Fe-Ce Oxide.

(Burk.) F.H. Chen, a valuable Chinese medicine, is currently confronted with arsenic (As) contamination in China due to soil pollution. Our previous research demonstrated that Fe(0) and zeolite had a certain inhibitory effect on As accumulation in . In order to further reduce As accumulation in the plant, a synthetic iron material (Fe-Ce oxide [FC]) with high As adsorption capacity was tested for As remediation. In the study, after FC was applied to the As-contaminated soil, was planted in the soil. The As leaching behavior of the treated soil and As accumulation in were evaluated. The results showed that FC immobilized As more effectively than Fe(0) and zeolite in soils with high As concentrations. When the FC dosage was 0.5 % (w/w), As concentration of root (the main medicinal part) decreased by 56%, and root biomass increased by 55%. Results indicated FC could reduce the non-specifically adsorbed As fraction (F1) and specifically adsorbed As fraction (F2) by 22 to 31% and 5 to 17%, respectively, thus reducing the toxicity characteristic leaching procedure leachable As concentration by 41 to 67%. The finding of an iron plaque coating on the plant root and its function as a barrier to As uptake by is reported here for the first time. The occurrence of iron plaque led to a reduction in As concentration in the phellem and xylem-phloem by 66 to 80% and 43 to 70%, respectively. Our findings will help in developing As contamination control in areas where is planted and set a foundation for a FC-based As immobilization technology.

Combining phytoremediation with soil flushing for arsenic removal from contaminated soil.

Arsenic (As) contamination poses a high risk to public health in China. Remediation of soil As contamination is an urgent need. Development of more effective remediation technologies is crucial in order to achieve remediation goals. In this study, pot experiments were carried out to study the As removal effectiveness of planting Pteris vittata L. (P.v.) and Lolium multiflorum L. (L.m.) in combination with in situ soil flushing using monopotassium phosphate (KH2PO4) solutions. Results showed that planting P.v. and L.m. in combination with 8 days of KH2PO4 solution soil flushing achieved 35.20% and 52.93%. As removal efficiency in the rhizosphere soil, respectively, which was significantly higher than 9.14% removal from soil flushing alone. Results also indicated that planting P.v. and L.m. changed the speciation of As to labile form, facilitating As removal from soil. Growing P.v. with in situ KH2PO4 flushing was more effective in remediating As-contaminated agricultural soil; L.m. could not be used in place of P.v to achieve the same remediation efficiency. This research provides an important guidance on plant screening for phytoremediation in combination with in situ flushing to remediate As-contaminated soil.

Effect of Water Chemistry and Hydrodynamics on Nitrogen Transformation Activity and Microbial Community Functional Potential in Hyporheic Zone Sediment Columns.

Hyporheic zones (HZ) are active biogeochemical regions where groundwater and surface water mix. N transformations in HZ sediments were investigated in columns with a focus on understanding how the dynamic changes in groundwater and surface water mixing affect microbial community and its biogeochemical function with respect to N transformations. The results indicated that denitrification, DNRA, and nitrification rates and products changed quickly in response to changes in water and sediment chemistry, fluid residence time, and groundwater-surface water exchange. These changes were accompanied by the zonation of denitrification functional genes along a 30 cm advective flow path after a total of 6 days' elution of synthetic groundwater with fluid residence time >9.8 h. The shift of microbial functional potential toward denitrification was correlated with rapid NO3- reduction collectively affected by NO3- concentration and fluid residence time, and was resistant to short-term groundwater-surface water exchange on a daily basis. The results implied that variations in microbial functional potential and associated biogeochemical reactions in the HZ may occur at space scales where steep concentration gradients present along the flow path and the variations would respond to dynamic HZ water exchange over different time periods common to natural and managed riverine systems.