RESUMO
Recovering ammonia from waste streams (e.g., urine) is highly desirable to reduce natural gas-based NH3 production and nitrogen discharge into the water environment. Electrochemical membrane stripping is an attractive alternative because it can drive NH4+ transformation to NH3 via cathodic OH- production; however, the conventional configurations suffer from relatively low ammonia recovery (<80 %) and significant acid/material usage for ammonia adsorption. To this end, we develop a novel stack system that simply uses an oxygen evolution reaction to in-situ produce acid from water, enabling chemical-free ammonia recovery from synthetic urine. In batch mode, the percentage removal and recovery increased respectively from 74.5 % to 97.9 % and 81.8 % to 92.7 % when the electrode pairs increased from 2 to 4 in the stack system. To address the gas-sparging issue that deteriorated ammonia recovery in continuous operation, pulsed electric field (PEF) mode was applied, resulting in â¼100 % recovery under optimized conditions. At an ammonia removal rate of 35.1 g-N m-2 h-1 and electrical energy consumption of 28.9 kWh kg-N-1, our chemical-free system in PEF mode has achieved significantly higher ammonia recovery (>90 %) from synthetic urine. The total cost to recover 1 kg of NH3-N from real human urine was $15.9 in the proposed system. Results of this study demonstrate that this novel approach holds great promise for high ammonia recovery from waste streams, opening a new pathway toward sustainable nitrogen management.
Assuntos
Amônia , Nitrogênio , Humanos , Eletrodos , ÁguaRESUMO
The biological treatment of source-separated human urine to produce biofuel, nutraceutical, and high-value chemicals is getting increasing attention. Especially, photoautotrophic microalgae can use human urine as media to achieve environmentally and economically viable large-scale cultivation. This review presents a comprehensive overview of the up-to-date advancements in microalgae cultivation employing urine in photobioreactors (PBRs). The standard matrices describing algal growth and nutrient removal/recovery have been summarized to provide a platform for fair comparison among different studies. Specific consideration has been given to the critical operating factors to understand how the PBRs should be maintained to achieve high efficiencies. Finally, we discuss the perspectives that emphasize the impacts of co-existing bacteria, contamination by human metabolites, and genetic engineering on the practical microalgal biomass production in urine.