RESUMO
Emulsion-templated porous polymers have attracted broad attention due to their great application prospects in many fields. However, scaling up the emulsion-templated technique from the lab to industrial production remains a great challenge, especially for systems involving an oil-in-water (o/w) emulsion template that is used normally for preparing hydrophilic porous polymers. These systems require large amounts of organic solvents to be the internal phase (i.e., major phase) of the emulsion templates, which causes a significant environmental impact and cost. Herein, a water-in-water (w/w) emulsion-templated technique is presented to prepare porous hydrophilic polymers. The w/w emulsion is prepared by mixing a PEG aqueous solution and a dextran aqueous solution with cellulose nanocrystals (CNCs) as a stabilizer. With varying the mass ratio of dextran/PEG in the range of 1/2 to 8/1, a series of dextran-rich-phase-in-PEG-rich-phase (dextran/PEG) emulsions are obtained. Subsequently, monomers, such as acrylamide, acrylic acid, and/or 2-acrylamido-2-methylpropanesulfonic acid, are introduced to the emulsions to fabricate porous hydrophilic polymers. These polymers have an open-cell structure like those of o/w emulsion-templated polymers. The system developed herein is an environmentally friendly, low cost, and universal emulsion-templated method toward porous hydrophilic polymers, which avoids the defects caused by the presence of large amounts of organic solvents in an o/w emulsion-templating method and can be moved from the lab to industrial-scale production.
RESUMO
Green technology innovation is a crucial factor in the global quest for sustainability. In 2017, China approved the establishment of Pilot Zones for Green Financial Reform and Innovations to build and improve the green financial system. Using a difference-in-difference (DID) model, this paper examines the impact of this pilot policy on corporate green technology innovation and its transmission mechanism based on the data of green patents of Chinese A-share listed manufacturing companies between 2014 and 2019. It is found that Pilot Zones for Green Financial Reform and Innovations have contributed to the growth of green technology innovations. This conclusion is confirmed after a series of robustness tests. The pilot policy's promotion of green technology innovations is mainly reflected in the application of corporate green invention patents. However, it is more significant for non-heavy polluting enterprises, high-tech certified enterprises, and large enterprises. The paper also finds that the pilot policy promotes corporate green technology innovation by promoting social financing, talent support, and government financial support.
Assuntos
Indústria Manufatureira , Crescimento Sustentável , Tecnologia , Certificação , China , ComércioRESUMO
In correlated oxides the coupling of quasiparticles to other degrees of freedom such as spin and lattice plays critical roles in the emergence of symmetry-breaking quantum ordered states such as high temperature superconductivity. We report a strong lattice coupling of photon-induced quasiparticles in spin-orbital coupling Mott insulator Sr2IrO4 probed via optical excitation. Combining time-resolved x-ray diffraction and optical spectroscopy techniques, we reconstruct a spatiotemporal map of the diffusion of these quasiparticles. Due to the unique electronic configuration of the quasiparticles, the strong lattice correlation is unexpected but extends the similarity between Sr2IrO4 and cuprates to a new dimension of electron-phonon coupling which persists under highly non-equilibrium conditions.