Design and dynamic analysis of a novel compound bending hollow piezoelectric beam miniature rotary actuator.

In this paper, a miniature hollow piezoelectric beam rotary actuator is proposed and designed based on the compound bending vibration modes. The structure body is designed as an elastic hollow square beam with symmetrical piezoelectric patches attached at both ends, which directly eliminates the step of the frequency tuning. A conical rotor is driven by the hollow piezoelectric beam through the elliptical motions of the points on its inner surface. Based on the Timoshenko beam theory and Lagrange equation, the numerical continuum model is established to analyze the working mechanism. A prototype of the miniature rotary actuator with a size of 50 × 6 × 6 mm (2 mm through-hole) is manufactured and its performance under various excitation parameters is characterized in rotor speed experiments. The experimental results show that the maximum speed of the conical rotor is 913 rpm at the excitation voltage of 400 V. With a maximum load of 70.31 mN, the spherical rotor can achieve a speed of 450 rpm. The numerical results are in great agreement with the experimental results, so the output characteristics of the rotary actuator can be estimated. The simulation and test results demonstrate that the proposed rotary actuator has outstanding output performance and controllability. In addition, the simple structure design is easy to realize the frequency tuning and miniaturization.

High-Performance Quantum Dots with Synergistic Doping and Oxide Shell Protection Synthesized by Cation Exchange Conversion of Ternary-Composition Nanoparticles.

The insertion of cation impurities into quantum dots (QDs) as a dopant has been proved to be an efficient way to tailor their optical, electronic, and magnetic properties; however, the low quantum yield (QY) and poor photostability strongly limit their further applications. We report a strategy to coat a thin oxide shell around the heterovalent doped QDs to enhance their QYs and photostabilities simultaneously. In the case of Ag+-doped CdS QDs, the controlled cation exchange reaction between Cd2+ and ternary Ag3SbS3 nanoparticles not only realizes the Ag+ doping in CdS QDs but also generates a thin Sb2O3 shell around the surface of the QDs. Enabled by such, as-prepared CdS:Ag@Sb2O3 QDs exhibited enhanced photostability and high QY of 66.5%. We envision that the findings presented here will inspire more novel protocols for advancing the practical applications of doped QDs.

Porous platinum-silver bimetallic alloys: surface composition and strain tunability toward enhanced electrocatalysis.

Promoting surface strains in heterogeneous catalysts and heteroatomic interactions in alloying offer an effective strategy for the development of electrocatalysts with greatly enhanced activity. In this work, we design platinum-silver nanotubes (PtAg NTs) with tunable surface compositions by a controlled galvanic replacement reaction of well-defined Ag nanowires (NWs). The optimized and porous PtAg NTs (PtAg-4 NTs), with the Pt5Ag3 surface composition and (111) facet-dominant surface features, exhibit an extraordinary oxygen reduction reaction (ORR) activity that reaches a specific activity of 1.13 mA cm-2 and a mass activity of 0.688 A mg-1Pt at 0.9 V versus a reversible hydrogen electrode (RHE), which are 4.5 times and 4.3 times those of commercial Pt/C catalysts (0.25 mA cm-2 and 0.16 A mg-1Pt). Moreover, PtAg-4 NTs/C can endure under the ORR conditions over the course of 10 000 cycles with negligible activity decay. Remarkably, density functional theory simulations reveal that the porous PtAg-4 NTs exhibit enhanced adsorption interaction with adsorbates, attributed to the catalytically active sites on high-density (111) facets and modulation of the surface strain, further boosting the ORR activity and durability.