RESUMO
In the quest for eco-conscious innovations, this research was designed for the sustainable synthesis of magnetite (Fe3O4) nanoparticles, using ferric chloride hexahydrate salt as a precursor and extract of Eucalyptus globulus leaves as both a reducing and capping agent, which are innovatively applied as a photocatalyst for the photocatalytic degradation of antibiotics "ciprofloxacin and amoxicillin". Sugar cane bagasse biomass, sugar cane bagasse pyrolyzed biochar, and magnetite/sugar cane bagasse biochar nanocomposite were also synthesized via environmentally friendly organized approaches. The optimum conditions for the degradation of ciprofloxacin and amoxicillin were found to be pH 6 for ciprofloxacin and 5 for amoxicillin, dosage of the photocatalyst (0.12 g), concentration (100 mg/L), and irradiation time (240 min). The maximum efficiencies of percentage degradation for ciprofloxacin and amoxicillin were found to be (73.51%) > (63.73%) > (54.57%) and (74.07%) > (61.55%) > (50.66%) for magnetic nanocomposites, biochar, and magnetic nanoparticles, respectively. All catalysts demonstrated favorable performance; however, the "magnetite/SCB biochar" nanocomposite exhibited the most promising results among the various catalysts employed in the photocatalytic degradation of antibiotics. Kinetic studies for the degradation of antibiotics were also performed, and notably, the pseudo-first-order chemical reaction showed the best results for the degradation of antibiotics. Through a comprehensive and comparative analysis of three unique photocatalysts, this research identified optimal conditions for efficient treatment of drug-contaminated wastewater, thus amplifying the practical significance of the findings. The recycling of magnetic nanoparticles through magnetic separation, coupled with their functional modification for integration into composite materials, holds significant application potential in the degradation of antibiotics.
RESUMO
In a stride towards sustainable solutions, this research endeavors to address the critical issue of water pollution via heavy metals by coupling the power of magnetic nanotechnology, in combination with a green chemistry approach, to eliminate two noxious inorganic pollutants: chromium(vi) and nickel(ii) from aqueous environments. The synthesis of magnetite (Fe3O4) nanoparticles was achieved using ferric chloride hexahydrate (FeCl3·6H2O) as a precursor, with the assistance of Ziziphus mauritiana Lam. leaves extract, known for its remarkable salt-reducing properties. A range of bio-adsorbents, derived from corncob biomass, corncob pyrolyzed biochar, and magnetite/corncob biochar nanocomposite (NC), were engineered for their eco-friendly and biocompatible characteristics. Extensive parametric optimizations, including variations in pH, contact time, dose rate, and concentration, were carried out to gain insights into the adsorption behavior and capacity of these bioadsorbents concerning Cr(vi) and Ni(ii). Equilibrium and kinetic studies were undertaken to comprehensively understand the adsorption dynamics. In the case of Ni(ii), the Freundlich isotherm model provided a satisfactory fit for all bio-adsorbents, demonstrating R2 values of 0.91, 0.95, and 0.96 for BM, BC, and NC, respectively. Furthermore, the pseudo 1st order model emerged as the most suitable fit for Cr(vi) sequestration in corncob BM with an R2 value of 0.98, while pseudo 2nd order models were robustly fitted for BC and NC, yielding R2 values of 0.88 and 0.99, respectively. The magnetite/corncob nanocomposite outperformed other bioadsorbents in removing heavy metals from wastewater due to its environmental friendliness, larger surface area, reusability, and cost-effectiveness at an industrial scale.