Patterns distribution, concentrations and sources of radioactive elements from black sand in the Red Sea coast, Egypt.

In Egypt, the distribution of black sand in various coastal regions has been readily apparent by thorough research. Unfortunately, these investigations did not measure radioactivity in black sand, particularly in the vicinity of the Red Sea. Gamma-ray spectroscopy was used to detect the naturally occurring radioactivity from 238U, 232Th, 40K, and 226Ra in black sand samples from eight locations along the Red Sea coast: Ras Elbehar, Gemsa, Hurghada Elahiaa, Hurghada Titanic, Safaga, Qusier Elsharm Alqbly, Gabal Alrosass, and Marsa Alam. The resultant data were interpolated to represent the spatial distribution. Additionally, the potential rocks sources of radionuclides were geologically mapped to elucidate the relationship between rock components and radioactivity. The results showed that 226Ra, 232Th and238U were higher at samples collected from Ras Elbehar, Hurghada Elahiaa and Hurghada Titanic compared to the other sites. On the other hand, 40K showed the lowest mean value (75.3 ± 3.8 Bq/kg) in Hurghada Titanic samples, while it peaked (563 ± 28 Bq/kg) in Qusier Elsharm Alqbly samples. The interpolated results show notable differences in radioactive amounts between the north and south, which are indicative of several environmental conditions and human activities. Alkaline syenite, syenogranite, older granites (tonalite and granodiorite), and minor acidic volcanic/metavolcanic rocks make up the upstream area of the basin area draining into, for example, the Ras Elbehar locality (highest activity concentrations for 238U (1596 ± 80 Bq/kg) and 226Ra (886 ± 44 Bq/kg)), while alkali-feldspar granite, schist, and shale rocks make up the mid-stream area. The findings provide a basis for scientific forecasting on the impact of synthetic or naturally occurring radioactive isotopes introduced into aquatic environments.

Assessment of physicochemical properties and radioactivity in groundwater at households living in bac Lieu province, vietnam.

This paper presents findings on groundwater physiochemical composition and radioactivity levels in households in Bac Lieu province, Vietnam. Through discriminant analysis, it was observed that groundwater quality exhibits spatial variations corresponding to saline intrusion zones. The paired-samples T-tests revealed significantly different ratios of Ra-224, Ra-226, and Ra-228 isotopes between Na-Cl and Ca-Na-HCO3 water types. All three water types had a ratio of Ra-226/Ra-228 of approximately one, indicating the presence of groundwater aquifers beneath the crust and fluvial marine sediment. Furthermore, strong associations between sulfate and calcium suggest that CO2 enrichment in groundwater aquifers indicates anoxic aquatic environments. Twenty-five of the thirty-three evaluated samples exceeded the national technical regulations for domestic water quality with parameters such as chloride, sulfate, sodium, gross alpha, or total dissolved solids. Fifteen samples exceeded gross alpha's allowable contamination threshold of 0.1 Bq/L. The combination of Ra-226 and Ra-228 did not surpass the U.S. Environmental Protection Agency's recommended limit of 0.185 Bq/L. However, nineteen samples exhibited annual committed effective doses of radium isotopes for infants that exceeded the WHO recommendation of 0.1 mSv/year.

Radionuclides transfer from soil-to-tea leaves and concomitant doses to the Malaysian populace.

One of the most well-liked energizing drinks is now tea, which is primarily used in Malaysia. The natural radioactivity in the associated soils where tea plants are cultivated plays a major role in determining the presence of radionuclides in tea leaves. The present study assesses the transfer of radionuclides from soil-to-tea leaves and then estimates the committed effective doses through tea consumption. Tea leaves and the associated soils were obtained from the largest tea plantation area, which is located in the Cameron Highlands, Malaysia. The marketed tea leaves in powdered form were obtained from the supermarkets in Kuala Lumpur. HPGe gamma-ray spectrometry was used to determine the prevailing concentrations of long-lived radioactive materials in tea leaves. Activity concentrations of 226Ra, 232Th, and 40K in tea soils ranged from 49 to 101.7 Bq kg-1, 74.5-124.1 Bq kg-1 and 79.6-423.2 Bq kg-1, respectively, while the respective values in tea leaves are 14.4-23.8 Bq kg-1, 12.9-29.5 Bq kg-1 and 297-387.5 Bq kg-1. Transfer factors of radionuclides showed typical values (<1.0) except for the 40K. The threshold tea consumption rates suggest that one should not consume more than 67 g of tea leaves per day (around 4 g of tea leaves are needed for making 1 cup of tea, so 17 cups per day) to avoid negative health effects. Committed effective doses due to tea consumption are found to be lower (5.18-6.08 µSv y-1) than the United Nations Scientific Committee on the Effects of Atomic Radiation (2000) reference dose guidance limit of 290 µSv y-1 for foodstuffs; however, it should be noted that the guidance limit is recommended for all foodstuffs collectively. Providing data on natural radioactivity in tea leaves grown in Malaysia, this study may help people manage a healthy lifestyle.

A multi-disciplinary approach for uranium exploration using remote sensing and airborne gamma-ray spectrometry data in the Gebel Duwi area, Central Eastern Desert, Egypt.

Uranium exploration plays a pivotal role in meeting global energy demands and advancing nuclear technology. This study presents a comprehensive approach to uranium exploration in the Gebel Duwi area of the Central Eastern Desert of Egypt, utilizing remote sensing and airborne gamma-ray spectrometric data. Multispectral remote sensing techniques, including Principal Component Analysis (PCA), Minimum Noise Fraction (MNF), and Band Ratioing (BR), are employed to identify lithological units and hydrothermal alteration zones associated with uranium deposition, such as iron oxides, argillic, propylitic, and phyllic alterations. Additionally, airborne gamma-ray spectrometry data provide insights into the spatial distribution of radioelements, including uranium (eU), thorium (eTh), and potassium (K), as well as radioelement ratios (eU/eTh, eU/K, and eTh/K). The uranium migration index map (eU-(eTh/3.5)) and the F-parameter map (K*(eU/eTh)) have been generated to investigate the movement of uranium within various geological zones and characterize anomalous uranium concentrations. Statistical analyses, including mean (X), standard deviation (S), and coefficient of variability (C.V.), are conducted to identify uranium-rich zones. The integration of these datasets enables the generation of a uranium potential map highlighting areas of elevated concentrations indicative of uranium mineralization. Field observations and mineralogical analyses of collected samples validate our findings, confirming the presence of minerals associated with uranium mineralization in mapped high-potential areas. The significance of minerals like Fe-Chlorite, Fe-Mg-Chlorite, ferrihydrite, goethite, calcite, muscovite, dolomite, actinolite, vermiculite, and gypsum in indicating potential uranium mineralization processes underscores the importance of our results.

Integrating remote sensing and geophysical data for mapping potential gold mineralization localities at Abu Marawat area, central Eastern Desert, Egypt.

Abu Marawat area in the Central Eastern Desert of Egypt is a very promising mineralization district located in the Golden Triangle area. The current study provides an integrated approach from multisource datasets including; remote sensing, airborne geophysical spectrometry and magnetic data supported by field studies and spectroscopic analyses for delineating potential mineralization localities. Several remote sensing techniques were adopted including; Band Ratios, Relative Band Depth, Mineralogical Indices, Spectral Angle Mapper, and Constrained Energy Minimization. These techniques showed that the alteration mineral assemblage is mainly, kaolinite, sericite, and iron oxides, with less abundant chlorite, epidote, and carbonates. In addition, the radiometry data were processed to map the localities with the highest possibility of potassic alteration abundance by integrating the potassium distribution, K/eTh ratio, and the F-parameter maps. The surface and subsurface linear structural features were also mapped using Digital Elevation Model (DEM) and aeromagnetic data, respectively. The surface linear structures were found exhibiting E-W and NE-SW trends, while, the subsurface structures showed dominant NW-SE trend. All the depicted fault trends match well with the local and regional geological and tectonic setting of the study area suggesting structural control on the mineralization in this area. Integration between the results obtained from both the remote sensing and the geophysical data was conducted by a GIS weighted overlay model. The obtained mineralization potentiality map highlights eight potential localities for mineralization. The accuracy of the adopted methodology was demonstrated through fieldwork and spectral analyses; several alteration indicators were observed, including quartz veins, iron oxides, kaolinite, malachite, montmorillonite, chlorite, talc, and sericite alteration indicator minerals. The adopted remote sensing-geophysical approach showed being very effective for mapping the hydrothermal gold-related alteration zones, and is recommended for other similar investigations.

Sustainable extraction and conservation of soil resources: New insights through Natural Gamma-ray Spectrometry based Proximal Sensing Method.

Soil is one the most extracted natural raw materials. The vast expanses of fertile alluvial soils of the Indo Gangetic Plains have long remained as abundant soil resource pool for brick manufacturing and construction sectors. Unmonitored continuous removal of soil is reported to cause depletion of soil reserves, loss of soil fertility and affect crop yield. Excavation and removal of soil from isolated patches of land creates low lying and elevated degraded areas which disrupts normal crop cultivation pattern. Natural gamma-ray spectrometry (NGS) can be used as a non-destructive and rapid geophysical sensing method, for identification and delineation of areas with suitable soils. During this work brick kiln areas were visited to understand soil's availability and extraction pattern. NGS measurements of samples from soil profiles were carried out to find if gamma-ray intensities varied with soil clay content. Soil texture and plasticity of the same samples were obtained following standard testing procedures. Winkler and Plasticity charts were used to assess suitability of the soils. A strong linear relationship between gamma-ray potassium (K) intensity and clay contents of soil profile samples (R2 = 0.88) was observed. NGS based devices can be used to scan soil samples rapidly and log shallow depth boreholes in grid sampling design. The gathered spectral gamma-ray data can be then used to predict and generate high resolution 3D models of soil properties, based on which resource areas of suitable soils can be delineated for long term soil extraction without affecting cultivated areas. This will help in delineating areas restricted for soil extraction, which will not only make soil mining sustainable but also address soil conservation by setting aside large cultivated fertile soil areas untouched. Adopting NGS methods will prevent unsystematic removal of fertile soil and creation of degraded lands. This will ultimately result in efficient soil resource management.

Determination of the activity and nuclear decay data of 157Tb.

Terbium-157 was radiochemically extracted from an irradiated tantalum target. Since the resulting material contained a significant impurity of 158Tb, 157Tb was isotopically purified using laser resonance ionization at the RISIKO mass separator in Mainz and then implanted on an aluminum (Al) foil. The implanted 157Tb was measured by two different calibrated gamma-ray spectrometers to determine photon emission rates. After dissolving the Al foil, a high purity 157Tb solution was obtained. The corresponding activity concentration was determined with a low relative uncertainty of 0.52% through a combination of liquid scintillation counting using the TDCR method and 4π(X,e)(LS)-(X,γ)(CeBr3) coincidence counting. By combining the results from all measurement techniques, emission intensities for K X-rays and gamma-rays were derived and found to be 16.05(31)% and 0.0064(2)%, respectively. The probability for K electron capture of the first forbidden non-unique transition to the ground state was determined to be 17.16(35)%. The probabilities for the electron-capture branch to the excited level and the ground state were found to be 0.084(4)% and 99.916(4)%, respectively. A Q+ value of 60.23(18) keV was estimated based on simplified BetaShape calculations, assuming an allowed transition.

Measurements of the absolute gamma-ray emission intensities from the decay of 166Ho.

166Ho (T1/2≈ 26.8 h) is an emerging theragnostic radionuclide of interest in nuclear medicine due to its peculiar decay scheme, featuring high-energy ß- emission (≈ 1.8 MeV) coupled with the main gamma-ray emission (≈ 80.6 keV). Using the new 166Ho activity standard and the well-calibrated, high-energy resolution HPGe detector, both available at ENEA-INMRI, a new determination of several 166Ho gamma-ray emission intensities, Iγ, was performed with low uncertainty. The new Iγ values contributed to the Decay Data Evaluation Project.

Evaluation of radioactivity concentration in farm fresh milk and concomitant dose to consumer.

In this study, activity concentrations of natural radionuclides in 28 raw milk samples collected from different dairy farms in Dhaka city of Bangladesh were measured using a high-purity germanium (HPGe) detector for the first time. The activity concentration of 226Ra, 232Th, and 40K in the investigated fresh milk samples ranged from BDL (Below detection level) to 26 ± 1.6 Bq/kg, BDL to 11.7 ± 3.3 Bq/kg and 101 ± 17 to 384 ± 32 Bq/kg, respectively. No artificial radionuclides were found in the investigated samples. Present results show inline within the range of available data in the literature. Annual committed effective doses were estimated following the consumption characteristics of raw milk by city population, values are found within the limiting range recommended by international organizations due to consumption of foodstuffs. Additionally, real-time gamma-ray dose rate in the farms/sampling locations was found in the range of 0.12 ± 0.01-0.20 ± 0.01 µSv/h by using a digital gamma survey meter (Gamma Scout) and the calculated maximum annual effective dose due to outdoor absorbed dose was found to be 0.25 mSv/y, which shows lower than the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) recommended limit of 2.4 mSv/y. This study indicates that the concentration of radionuclides in the farm fresh milk of Dhaka city does not pose any unwanted risk to public health, and it is safe to consume by both children and adults with the current intake level.

Absolute emission intensities of the gamma rays from the decay of 224Ra and 212Pb progenies and the half-life of the 212 Pb decay.

Absolute gamma-ray emission intensities for 36 characteristic gamma rays from the decay of 224Ra, 212Pb, and their progeny were determined by measuring sources calibrated for activity by means of primary methods based on well-defined high-purity germanium (HPGe) detectors at both NIST and NPL. Results from the two laboratories agree with recent data evaluations, except for gamma rays with low emission intensities. The decay schemes have been re-balanced based on the new results. In addition, the half-life for 212Pb was measured using several HPGe detectors, ionization chambers, and a well-type NaI(Tl) detector.

Upscaling ground-based backpack gamma-ray spectrometry to spatial resolution of UAV-based gamma-ray spectrometry for system validation.

Advances in the development of gamma-ray spectrometers have resulted in devices that are ideal for use in conjunction with the increasingly reliable systems of autonomously flying uncrewed aerial vehicles (UAVs) that have recently become available on the market. Airborne gamma-ray spectrometry (GRS) measurements have many different applications. Here, the technique is applied to a former uranium mining and processing site, which is characterized by relatively low specific activities and, hence, low count rates, requiring relatively large detectors and correspondingly big size UAVs. The future acceptance of the use of such UAV-based GRS systems for radionuclide mapping depends on their ability to measure absolute specific activities of natural radionuclides such as U-238 in near-surface soil that are consistent with the results of established and proven ground-based systems. To determine absolute specific activities on the ground, the gamma radiation data from airborne detectors must be corrected for attenuation caused by the flight altitude above ground. In recent years, mathematical procedures for altitude correction have been developed, that are specifically tailored to the working range of several tens of meters typical for UAVs. However, very limited experimental validation of these theoretical approaches is available. A very large dataset consisting of about 3000 UAV-based and 19,000 backpack-based measurements was collected at a low-grade uranium ore dump in Yangiabad, Uzbekistan. We applied different geostatistical interpolation methods to compare the data from both survey techniques by upscaling backpack data to airborne data. Compared to backpack systems, UAV-based systems have lower spatial resolution, so measurements average over larger areal units (or in geostatistical terminology: "spatial support"). Taking into account the change in spatial support, we illustrate that (1) the UAV-based measurements show good agreement with the upscaled backpack measurements and that (2) UAV surveys provide good delineation of contrasts of the relatively smooth U-238 specific activity distribution typical for former uranium mining and processing sites. We are able to show that the resolution of UAV-based systems is sufficient to map extended uranium waste facilities.

A benchmark for Monte Carlo simulations in gamma-ray spectrometry Part II: True coincidence summing correction factors.

The goal of this study is to provide a benchmark for the use of Monte Carlo simulation when applied to coincidence summing corrections. The examples are based on simple geometries: two types of germanium detectors and four kinds of sources, to mimic eight typical measurement conditions. The coincidence corrective factors are computed for four radionuclides. The exercise input files and calculation results with practical recommendations are made available for new users on a dedicated webpage.

Latent variable modeling of gamma-ray background in repeated measurements.

We propose a novel approach for background subtraction in repeated gamma-ray spectrometric measurements. This entirely data-driven method eliminates the need for Monte Carlo detector simulation. To accomplish this, we utilized the framework of Latent Variable Modeling, incorporating various matrix factorization techniques and artificial neural networks. Subsequently, we applied this method to estimate radionuclide activity through spectrum unmixing. Significant improvements in sensitivity, surpassing traditional methods, were observed for the test case scenario of aerosol filter measurements.

A novel method to estimate the dead layer of HPGe detector for Monte Carlo FEPE computation.

In this study, a novel method to determine the surface and lateral dead layers of p-type HPGe detector is proposed to compute the full energy peak efficiency (FEPE). The method employed standard radioactive point sources 241Am, 133Ba and FEPE measurement at low energies to estimate the thickness of frontal and lateral dead layers. The method is simple to apply, requires only two standard radioactive sources to estimate the optimum thickness of frontal and lateral dead layers. The proposed method is validated by measuring the efficiency of various point sources and a volume source in the energy range from 59 to 1408 keV. The measured efficiencies agree to simulation with relative deviation less than 4.0% at each energy. The proposed detector model enables to calibrate the detector for environmental radioactivity measurement without standard volume sources.

Towards a radon-in-water primary standard at LNHB.

Despite widespread radon-in-water measurements, no primary radon-in-water standards currently exist. This work aims to bridge this gap by developing a system to produce radon-in-water reference materials. The system relies on cryogenic, loss-free transfer of radon, which is standardized through defined solid angle measurements, to a radon standard in water. It allows for preparation of liquid scintillation and gamma-ray spectrometry samples with traceable radon-in-water concentrations. The system's design, functionality, and the results of pilot performance tests are described.

Natural gamma-ray spectrometry as a rapid sensing method for detecting variations in soil shrinking and cracking behaviour: An application case study.

Soils which develop desiccation cracks after drying are unsuitable for the making of earthenware. The present work was carried out to demonstrate the use of Natural Gamma-ray Spectrometry (NGS) as a rapid sensing method to detect the variation of cracking behaviour and types of clay dominant in soil using samples collected from the study region. Natural gamma-ray intensities due to potassium (K) and equivalent thorium (eTh) radioisotopes present in soil were recorded using an NGS device. Circular soil cakes of set diameter were sun-dried to find shrinking and cracking variations. Other tests included measurement of particle size distribution, Atterberg indices, basic soil physico-chemical properties, exchangeable cation contents using ICP-OES and XRD identification of clays. 6 soil varieties were identified from the distribution of data points in the binary plots of gamma-ray potassium (GR-K) and thorium (GR-eTh) counts per sec (C/s). Variation of GR-K was observed to be wider (2.14 C/s to 2.54 C/s) than GR-eTh (0.44 C/s to 0.63 C/s). The measured GR-K counts reflect changes in illite content. The soils displayed 3 categories of shrinking and cracking behaviour. The soil variety which displayed maximum mild shrinkage without fine desiccation cracks on the set surface area has the highest GR-K counts. The soil shrinking and cracking variations were not clearly defined by the classification based on the texture and plasticity chart, though the latter indicated dominant smectites. A strong linear relationship between GR-K and exchangeable K (R2 = 0.84) indicates K+ contribution mainly from illite and dominance of other clay types in outliers. Higher levels of polyvalent cations known for binding clay aggregates were observed in the non-cracking soils. Concomitant higher GR-K levels indicate that shrinking soils lacking fine desiccation cracks are associated with fluvial sediments of the recent past with parental mica. This research concludes that NGS-based portable devices can be used for rapid sensing of soils to detect variation in shrinking and cracking behaviour and dominant clay type and thus can be used for identification of soil suitable for earthenware making.

Online spectral unmixing in gamma-ray spectrometry.

We introduced in a previous paper a time-dependent full-spectrum analysis algorithm speeding up the estimation of the activity of the radionuclides present in a sample. In this paper, we present a new version of the algorithm allowing online estimation. It uses only on a buffer of few segments while keeping the time information by using a time dependent regularization, thus reducing the size of the data matrices and the length of the processing of each iteration. The algorithm is optimized and tested on both simulated and measured spectra of aerosol samples.

226Ra measurement via gamma-ray spectrometry of 222Rn progeny - quantification of radon losses from sample capsules.

Radium-226 detection in sediment samples is generally executed by means of gamma-ray spectrometry. Data evaluation relies (besides the 186.2 keV 226Ra gamma peak) on the combined analysis of major gamma peaks that are produced by the short-lived radon (222Rn) daughters 214Pb and 214Bi. Precondition for this detection approach is equilibrium decay of all members of the decay chain between 226Ra and 214Bi. In closed systems, this equilibrium is reached after about five half-lives of 222Rn (19 days). However, a closed system can only be guaranteed if the capsule which contains the sample prevents diffusive escape of radon. Such radon-tightness cannot be guaranteed for a wide range of plastic materials. Due to its polymer structure, plastic material generally tends to allow radon diffusion and hence radon loss from the sample resulting in a disturbance of the required decay equilibrium. The paper introduces an approach that allows quantifying radon loss from sample capsules by direct radon measurements using mobile radon detection equipment. The experimental findings are supported by theoretical considerations. An examined alternative approach based on the offset of the 186.2 keV data point from an efficiency function that is calculated exclusively from short-lived radon progeny peaks in the gamma-ray spectrum did not prove to be applicable due to a lack of supporting peaks in the low-energy section of the spectrum.

Measurement of Cumulative fission product yields on 235U induced by 2.8 MeV neutrons.

Off-line gamma-ray spectrometry was used to accurately measure the Cumulative fission product yields (CFPYs) of fission products in the 235U (n, f) reaction induced by 2.8 MeV neutrons. The 2.8 MeV quasi-monoenergetic neutron beam was produced by the CPNG-600 Cockcroft Walton accelerator at the China Institute of Atomic Energy （CIAE）and the gamma spectra were measured by the HPGe γ-ray Spectrometer. After fully considering and revising the sources of uncertainty, high-precision CFPYs of 4 fission products were obtained. This study has important applications in reactor design and operation and is conducive to the establishment of an evaluated nuclear database.

Evaluating the intensity of the 803-keV γ ray of 210Po using a 4παß(LS)-γ(HPGe) measurement system.

The absolute intensity for the 803-keV γ ray of 210Po was evaluated by α-γ coincidence technique. A liquid sample with a known amount of 210Po embedded in scintillation fluid was measured in a coincidence-based system that comprises a Liquid Scintillator (LS) detector and a High-Purity Germanium (HPGe) detector. A photo-reflector assembly that contains the 210Po sample provides 100% efficiency for detecting the α particles. The combination between the HPGe and the LS detectors allows to reject non-coincident α-γ events while maintaining high resolution γ spectroscopy. Consequently, the faint 803-keV photopeak from 210Po could be observed in a background-free environment, and its intensity could be evaluated with good accuracy. Sample measurements were carried out over nine months to gather statistics and verify the reliability of the experimental procedure. The absolute intensity of the 803-keV line was found to be (1.22 ± 0.03) × 10-5, in excellent agreement with the adopted value in a recent data compilation and consistent with previous experimental works.