Damage and Recovery Behavior of Low-Replacement-Rate Fly Ash Concrete after Different High-Temperature Exposures.

This study focuses on investigating the strength recovery of fire-damaged fly ash concrete (FAC) with a low substitution rate of 10% through post-fire curing. The chemical and microstructural changes were analyzed using X-ray diffraction (XRD), derivative thermogravimetry (DTG), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDS), and nitrogen adsorption. The findings indicate that the incorporation of fly ash slightly enhanced the strength after exposure to 400 °C; this was attributed to improved pozzolanic reactions, which were not observed at higher temperatures of 600 °C and 800 °C. Moreover, a positive effect on the recovery of compressive strength was observed due to the pozzolanic reaction. However, due to the relatively low fly ash content, depletion occurred at a later age, resulting in the inability to inhibit microstructural damage caused by the production of portlandite, thereby weakening the compressive strength. Interestingly, fly ash influenced the morphology of calcium carbonate and calcium silicate hydrate crystals, which is potentially ascribed to the role of high aluminum content acting as a crystallization-guiding agent.

Association of air temperature exposure during pregnancy with risk of preeclampsia in Guangzhou, China.

Environmental exposures during pregnancy have been associated with adverse obstetric outcomes. However, limited and inconsistent evidence exists regarding the association between air temperature exposure and the risk of preeclampsia (PE). This study aimed to evaluate the correlation between ambient temperature exposure during pregnancy and PE risk, as well as identify the specific time window of temperature exposure that increases PE risk. A population-based cohort study was conducted from January 2012 to April 2022 in Guangzhou, China. Pregnant women were recruited in early pregnancy and followed until delivery. A total of 3,314 PE patients and 114,201 normal pregnancies were included. Ambient temperature exposures at different gestational weeks were recorded for each participant. Logistic regression models were used to evaluate the correlation between ambient temperature exposure and PE risk. Stratified analyses were conducted based on maternal age and pre-pregnancy BMI. Distributed lag models were employed to identify the time window of temperature exposure related to PE. Exposure to extreme high temperature (aOR = 1.24, 95 % CI 1.12-1.38) and moderate high temperature (aOR = 1.22, 95 % CI 1.10-1.35) during early pregnancy was associated with an increased risk of PE. Furthermore, women with higher pre-pregnancy BMI had a higher risk of developing PE when exposed to high temperature during early pregnancy compared to normal-weight women. The time window of temperature exposure related to PE was identified as pregnancy weeks 1 to 8. This study provides evidence for the association of high temperature exposure during early pregnancy with the risk of PE, as well as identifies the specific time window of temperature exposure related to PE. These findings have implications for developing potential strategies to protect pregnant women, particularly those with higher pre-pregnancy BMI, from the adverse effects of extreme temperatures during early pregnancy.

A novel mathematical model for estimating the relative risk of mortality attributable to the combined effect of ambient fine particulate matter (PM2.5) and cold ambient temperature.

Exposures to ambient fine particulate matter (PM2.5) and cold ambient temperatures have been identified as important risk factors in contributing towards the global mortality from chronic obstructive pulmonary disease (COPD). Despite China currently being the country with the largest population in the world, previous relative risk (RR) models have considered little or no information from the ambient air pollution related cohort studies in the country. This likely provides a less accurate picture of the trend in air pollution attributable mortality in the country over time. A novel relative risk model called pollutant-temperature exposure (PTE) model is proposed to estimate the RR attributable to the combined effect of air pollution and ambient temperature in a population. In this paper, the pollutant concentration-response curve was extrapolated from the cohort studies in China, whereas the temperature response curve was extracted from a study in Yangtze River Delta (YRD) region. The performance of the PTE model was compared with the integrated exposure-response (IER) model using the data of YRD region, which revealed that the estimated relative risks of the PTE model were noticeably higher than the IER model during the winter season. Furthermore, the predictive ability of the PTE model was validated using actual data of Ningbo city, which showed that the estimated RR using the PTE model with 1-month moving average data showed a good result with the trend of actual COPD mortality, indicated by a lower root mean square error (RMSE = 0.956). By considering the combined effect of ambient air pollutant and ambient temperature, the PTE model is expected to provide more accurate relative risk estimates for the regions with high levels of ambient PM2.5 and seasonal variation of ambient temperature.

Experimental and Theoretical Study on Flexural Behavior of GFRP- and CFRP-Reinforced Concrete Beams after High-Temperature Exposure.

In this study, in order to study the flexural behavior of fiber-reinforced polymer (FRP) bars with reinforced concrete beams under static loads after high-temperature exposure, seven pieces of FRP-reinforced concrete beams were subjected to static bending tests and calculation model derivations. Four-point bending tests were carried out on FRP-reinforced concrete beams after high temperature treatment. The effects of high temperature and types of FRP bars on the cracking load, crack development, deflection and ultimate capacity, and failure mode of concrete beams were investigated. The test results show that the maximum crack width, deflection, and ultimate bearing capacity of GFRP- and CFRP-reinforced concrete beams decrease obviously with a rise in high temperature. After the exposure of 400 °C for 2 h, compared with the behavior of concrete beams at room temperature, the maximum crack width of GFRP and CFRP-reinforced concrete beams increased by 42.9% and 41.7%, respectively, the deflection increases by 103.6% and 22.0%, and the ultimate bearing capacity decrease by 11.9% and 3.9%. Meanwhile, through the analysis of the existing research results and test results, the calculation models for the maximum crack width, deflection, and residual ultimate capacity of FRP-reinforced concrete beams after exposure of high temperature were proposed. For FRP-reinforced concrete beams after high-temperature exposure, the errors between the measured maximum crack width, stiffness, residual bearing capacity, and their corresponding calculated values using the model were mostly less than 10%. The calculated value using the proposed model in this research is in good agreement with the measured value. The mechanical properties of FRP-reinforced high-strength concrete structures after high-temperature exposure can be preliminarily predicted, which provides a new theoretical basis for the application of FRP-reinforced concrete structures.

Effects of early low temperature exposure on the growth, glycolipid metabolism and growth hormone (gh) gene methylation in the late stage of Chinese perch (Siniperca chuatsi).

Temperature is an important factor affecting the early development, growth and physiology of fish, as well as on aspects of feeding and metabolism. Here, we investigated the impact of low temperature on the growth, glycolipid metabolism and growth hormone (gh) gene methylation in the late stage of Chinese perch (Siniperca chuatsi). Chinese perch larvae were exposed to temperatures with 21 °C (low temperature group (LT)) and 25 °C (control group) for 7 days, and then the LT group was slowly heated to 25 °C and raised at this temperature for two months. Results indicated that the LT group exhibited significantly lower growth rate and weight gain rate than the control group (p < 0.05), but no obvious food intake (FI) were detected yet between LT group and control group. The larvae exposed at 21 °C relative to the 25 °C group had significant decreased transcript levels of GH-IGF axis genes (gh, igf1 and igf2) in Chinese perch juvenile (p < 0.05). Further analysis of the DNA methylation levels of gh showed that the LT group had higher at the CpG sites of -3029 and - 3032 than the control group in larvae (p < 0.05), whereas the DNA methylation levels at CpG sites of -2982 and - 3039 of gh were significantly lower compared with the control group in juveniles (p < 0.05). In addition, the plasma glucose was significantly increased in the LT group (p < 0.05), suggesting the metabolism of blood glucose slowed at low temperature. In larvae, the expressions of glycolipid metabolism genes (ins-ra and ins-rb) in LT group were significantly up-regulated compared to control group in larvae (p < 0.05), while down-regulated in juveniles (p < 0.05). The expression level of ucp2 mRNA was continuously up-regulated under low temperature stress. All these data demonstrate that early exposure to low temperature affected the growth and glycolipid metabolism of Chinese perch.

Hybrid Plasmonic/Photonic Nanoscale Strategy for Multilevel Anticounterfeit Labels.

Innovative goods authentication strategies are of fundamental importance considering the increasing counterfeiting levels. Such a task has been effectively addressed with the so-called physical unclonable functions (PUFs), being physical properties of a system that characterize it univocally. PUFs are commonly implemented by exploiting naturally occurring non-idealities in clean-room fabrication processes. The broad availability of classic paradigm PUFs, however, makes them vulnerable. Here, we propose a hybrid plasmonic/photonic multilayered structure working as a three-level strong PUF. Our approach leverages on the combination of a functional nanostructured surface, a resonant response, and a unique chromatic signature all together in one single device. The structure consists of a resonant cavity, where the top mirror is replaced with a layer of plasmonic Ag nanoislands. The naturally random spatial distribution of clusters and nanoparticles formed by this deposition technique constitutes the manufacturer-resistant nanoscale morphological fingerprint of the proposed PUF. The presence of Ag nanoislands allows us to tailor the interplay between the photonic and plasmonic modes to achieve two additional security levels. The first one is constituted by the chromatic response and broad iridescence of our structures, while the second by their rich spectral response, accessible even through a common smartphone light-emitting diode. We demonstrate that the proposed architectures could also be used as an irreversible and quantitative temperature exposure label. The proposed PUFs are inexpensive, chip-to-wafer-size scalable, and can be deposited over a variety of substrates. They also hold a great promise as an encryption framework envisioning morpho-cryptography applications.

[Comparative morphological assessment of the damaging effects of cold plasma and radio wave energy on the mucous membrane of the lip in the experiment]. / Sravnitel'naya morfologicheskaya otsenka povrezhdayushchego vozdeistviya kholodnoplazmennoi i radiovolnovoi energii na slizistuyu obolochku guby v eksperimente.

The aim of this study was a comparative morphological assessment of changes in the mucous membrane of the lip in the field of radio wave and cold plasma exposure in the experiment. MATERIAL AND METHODS: Experimental animals removed a portion of the mucous membrane of the inner surface of the lip with a Surgitron radio knife (group 1) and an electrode of the Coblator II cold plasma apparatus (observation group 2). Tissue was taken from the edge of the surgical wound as a trapezoidal flap containing mucous and submucous membranes immediately after the incision and 3 weeks after the surgery. Histological sections were prepared, which were stained with hematoxylin and eosin, as well as according to van Gieson. RESULTS: It was found that, both in cases of using a radio knife and a coblator along the edges and in the depth of the wound, coagulation tissue necrosis was observed, which was more evident in group 1 of observations. In addition, after the radio wave exposure, in the areas close to the defect, the epithelial lining was disrupted to one degree or another, which was not observed when using the coblator. After 3 weeks of the experiment, the stratified squamous non-keratinizing epithelium in both groups had a normal histological structure. At the same time, when using the coblator, the lamina propria of the mucous membrane was completely restored, and in cases with the use of a radio knife, sclerotic processes with the formation of scar tissue took place in the lamina propria of the mucous membrane in some areas. CONCLUSIONS: The use of a coblator should be recognized as a more gentle method, since a comparative analysis of histological changes immediately after the incision showed a more intense damaging effect of the radio knife on the surrounding tissues, which in later stages was accompanied by incomplete regeneration (substitution) of the lip mucosa.

Effect of Elevated Temperature on Mechanical Properties of High-Volume Fly Ash-Based Geopolymer Concrete, Mortar and Paste Cured at Room Temperature.

This paper presents results from experimental work on mechanical properties of geopolymer concrete, mortar and paste prepared using fly ash and blended slag. Compressive strength, splitting tensile strength and flexural strength tests were conducted on large sets of geopolymer and ordinary concrete, mortar and paste after exposure to elevated temperatures. From Thermogravimetric analyzer (TGA), X-ray diffraction (XRD), Scanning electron microscope (SEM) test results, the geopolymer exhibits excellent resistance to elevated temperature. Compressive strengths of C30, C40 and C50 geopolymer concrete, mortar and paste show incremental improvement then followed by a gradual reduction, and finally reach a relatively consistent value with an increase in exposure temperature. The higher slag content in the geopolymer reduces residual strength and the lower exposure temperature corresponding to peak residual strength. Resistance to elevated temperature of C40 geopolymer concrete, mortar and paste is better than that of ordinary concrete, mortar and paste at the same grade. XRD, TGA and SEM analysis suggests that the heat resistance of C-S-H produced using slag is lower than that of sulphoaluminate gel (quartz and mullite, etc.) produced using fly ash. This facilitates degradation of C30, C40 and C50 geopolymer after exposure to elevated temperatures.

Comparing temperature-related mortality impacts of cool roofs in winter and summer in a highly urbanized European region for present and future climate.

Human health can be negatively impacted by hot or cold weather, which often exacerbates respiratory or cardiovascular conditions and increases the risk of mortality. Urban populations are at particular increased risk of effects from heat due to the Urban Heat Island (UHI) effect (higher urban temperatures compared with rural ones). This has led to extensive investigation of the summertime UHI, its impacts on health, and also the consideration of interventions such as reflective 'cool' roofs to help reduce summertime overheating effects. However, interventions aimed at limiting summer heat are rarely evaluated for their effects in wintertime, and thus their overall annual net impact on temperature-related health effects are poorly understood. In this study we use a regional weather model to simulate the winter 2009/10 period for an urbanized region of the UK (Birmingham and the West Midlands), and use a health impact assessment to estimate the impact of reflective 'cool' roofs (an intervention usually aimed at reducing the UHI in summer) on cold-related mortality in winter. Cool roofs have been shown to be effective at reducing maximum temperatures during summertime. In contrast to the summer, we find that cool roofs have a minimal effect on ambient air temperatures in winter. Although the UHI in summertime can increase heat-related mortality, the wintertime UHI can have benefits to health, through avoided cold-related mortality. Our results highlight the potential annual net health benefits of implementing cool roofs to reduce temperature-related mortality in summer, without reducing the protective UHI effect in winter. Further, we suggest that benefits of cool roofs may increase in future, with a doubling of the number of heat-related deaths avoided by the 2080s (RCP8.5) compared to summer 2006, and with insignificant changes in the impact of cool-roofs on cold-related mortality. These results further support reflective 'cool' roof implementation strategies as effective interventions to protect health, both today and in future.

The winter urban heat island: Impacts on cold-related mortality in a highly urbanized European region for present and future climate.

Exposure to heat has a range of potential negative impacts on human health; hot weather may exacerbate cardiovascular and respiratory illness or lead to heat stroke and death. Urban populations are at increased risk due to the Urban Heat Island (UHI) effect (higher urban temperatures compared with rural ones). This has led to extensive investigation of the summertime UHI and its effects, whereas far less research focuses on the wintertime UHI. Exposure to low temperature also leads to a range of illnesses, and in fact, in the UK, annual cold-related mortality outweighs heat-related mortality. It is not clearly understood to what extent the wintertime UHI may protect against cold related mortality. In this study we quantify the UHI intensity in wintertime for a heavily urbanized UK region (West Midlands, including Birmingham) using a regional weather model, and for the first time, use a health impact assessment (HIA) to estimate the associated impact on cold-related mortality. We show that the population-weighted mean winter UHI intensity was +2.3 °C in Birmingham city center, and comparable with that of summer. Our results suggest a potential protective effect of the wintertime UHI, equivalent to 266 cold-related deaths avoided (~15% of total cold-related mortality over ~11 weeks). When including the impacts of climate change, our results suggest that the number of heat-related deaths associated with the summer UHI will increase from 96 (in 2006) to 221 in the 2080s, based on the RCP8.5 emissions pathway. The protective effect of the wintertime UHI is projected to increase only slightly from 266 cold-related deaths avoided in 2009 to 280 avoided in the 2080s. The different effects of the UHI in winter and summer should be considered when assessing interventions in the built environment for reducing summer urban heat, and our results suggest that the future burden of temperature-related mortality associated with the UHI is likely to increase in summer relative to winter.

Mechanical Performance of High-Strength Sustainable Concrete under Fire Incorporating Locally Available Volcanic Ash in Central Harrat Rahat, Saudi Arabia.

This study investigated the effect of elevated temperatures on the mechanical properties of high-strength sustainable concrete incorporating volcanic ash (VA). For comparison, control and reference concrete specimens with fly ash (FA) were also cast along with additional specimens of VA and FA containing electric arc furnace slag (EAFS). Before thermal exposure, initial tests were performed to evaluate the mechanical properties (compressive strength, tensile strength, and elastic modulus) of cylindrical concrete specimens with aging. Additionally, 91 day moist-cured concrete specimens, after measuring their initial weight and ultrasonic pulse velocity (UPV), were exposed up to 800 °C and cooled to air temperature. Subsequently, the weight loss, residual UPV, and mechanical properties of concrete were measured with respect to exposure temperature. For all concrete specimens, test results demonstrated a higher loss of weight, UPV, and other mechanical properties under exposure to higher elevated temperature. Moreover, all the results of concrete specimens incorporating VA were observed before and after exposure to elevated temperature as either comparable to or slightly better than those of control and reference concrete with FA. According to the experimental results, a correlation was developed between residual UPV and residual compressive strength (RCS), which can be used to assess the RCS of fire-damaged concrete (up to 800 °C) incorporating VA and EAFS.

[The dynamics of hemodynamic, psychophysiological parameters and adaptive potential of men of working age engaged in water-cold hardening]. / Izmenenie gemodinamicheskikh, psikhofiziologicheskikh pokazatelei i adaptatsionnogo potentsiala muzhchin trudosposobnogo vozrasta, zanimayushchikhsya vodno-kholodovym zakalivaniem.

The article shows the influence of repeated repetition of contrasting temperature effects on hemodynamic, psychophysiological parameters and the adaptive potential of men of working age. OBJECTIVE: To assess changes of hemodynamic and psychophysiological parameters, as well as the adaptive potential in healthy men of working age under the influence of repeated contrasting temperature exposures, the difference of which is about 70 °C. MATERIAL AND METHODS: Blood pressure, heart rate and Luscher test were measured 20 minutes before and 20 minutes after repeated exposure of contrasting temperature changes (alternation of temperature cycles). The following parameters were calculated: dynamics of pulse pressure and mean arterial pressure, Stroke volume (SV), Cardiac output (CO), the Kerdo vegetative index (KVI). Assessment of adaptive potential (AP) was carried out according to the Baevsky's Stress Index and Robinson index. Also, integral parameters of psychophysiological status were evaluated by the Luscher test. RESULTS: In the course of the study, it was proved that 20 minutes before repeated contrast temperature exposure, the level of SBP and heart rate was increased (p<0.01), and 20 minutes after the completion of procedures the decrease of SBP level was observed (p<0.05). The CO level before the start of temperature exposure was decreased (p<0.01), and 20 minutes after the finish of the contrasting effects this dynamics was preserved (p<0.01). The AP level before the start of contrasting exposure was 2.79±0.10, and after contrasting exposure it was decreased (p<0.05). The Robinson index (RI) was higher than the established normal values before temperature effects (112.53±6.82), then its decrease was noted (p<0.01). According to Luscher's test, the integral parameters «Heteronomy-autonomy¼, «Balance of personal properties¼, «Vegetative coefficient¼ significantly changed psychophysiological characteristics. The parameter «Total deviation¼ indicated an average level of unproductive neuropsychic tension (before - 14.71±2.19, after - 14.36±2.26) both before and after repeated temperature exposures. The VIC parameter of the study participants testified to the predominance of parasympathicotonia (before - -2.07±5; after - -7.23±5.62). At the same time, correlations were established only before repeated contrast exposure. CONCLUSIONS: Repeatedly repeated contrasting temperature effects cause ambiguous reactions of the body. Changes in hemodynamic, psychophysiological parameters and adaptive potential are observed some time before the alternation of cycles of contrasting exposures. Most likely, this reaction of the body is a reaction to the upcoming temperature stress. If the model of stress exposure, when the temperature variation is about 70 °C, occurs regularly and systematically (once a week throughout the entire winter season), in this case, the main recommendation is to control the blood pressure level before the start of contrast exposure as a precautionary measure to prevent the development of adverse cardiovascular reactions.

Performance of Optical Coupling Materials in Scintillation Detectors Post Temperature Exposure.

In this paper, the room-temperature performance of different optical coupling materials post temperature exposure was tested. The tested couplers included OC431A-LVP, OG0010 optical grease, BLUESIL V-788, and SAINT-GOBAIN BC-630. This was done by subjecting the whole detector with newly applied optical coupling materials to a 2-h temperature exposure-ranging from -20 to 50 °C and then by letting it return to room temperature before collecting a spectrum from a Cs-137 source. The energy resolution at 662 keV was computed as the metric for evaluating the performance. Three trials were run at each coupler-temperature combination. Our results reveal that the performance of all coupling agents do indeed change with temperature after the 2-h exposure. Over all the tested temperature trials, the energy resolution ranged from 11.4 to 14.3% for OC431A-LVP; 10.2 to 14.6% for OG0010; 10 to 13.4% for BLUESIL V-788; and 9.8 to 13.3% for SAINT-GOBAIN BC-630. OC431A-LVP had the lowest variance over the full range, while BC-630 was the most constant for temperatures above 20 °C. Ultraviolet-visible (UV-Vis) spectra experiments were also performed on isolated optical coupling materials to measure the light absorption coefficient. The results show that the temperature-induced variance in light absorption coefficient of each optical coupling materials is one of the reasons for the variance in energy resolution performance. Our findings suggest the need for further investigation into this effect and the recommendation that optical coupling materials need to be selected for the task at hand with greater scrutiny.

Analysis of Changes in the Microstructure of Geopolymer Mortar after Exposure to High Temperatures.

The inorganic structure formed at the stage of setting of the geopolymer binder ensures high durability of the material under high-temperature conditions. However, changes in the microstructure of the material are observed. The purpose of the study was to analyze changes in the structure of geopolymer mortar after exposure to high temperatures T = 200, 400, 600, 800, and 1000 °C. Mortars with a binder based solely on fly ash (FA) and mixed in the 1:1 ratio with a binder containing fly ash and ground granulated blast-furnace slag (GGBFS) were tested. The descriptions of their microstructures were prepared based on digital microscope observations, scanning electron microscope (SEM) observations, EDS (energy dispersive spectroscopy) analysis, and mercury intrusion porosimetry (MIP) porosity test results. Changes in the material due to high temperature were observed. The differences in the microstructure of the samples are also visible in the materials that were not exposed to temperature, which was influenced by the composition of the materials. Porosity increases with increasing annealing temperature. The distribution of individual pores also changes. In both materials, the proportion of pores larger than 1000 nm increases with the temperature increase. Moreover, the number of cracks and their width also increases, reaching 20 µm in the case of GGBFS. Furthermore, the color of geopolymers has changed. The obtained results extend the current state of knowledge in the field of changes in the microstructure of geopolymers subjected to high temperature.

Household income inequality aggravates high-temperature exposure inequality in urban China.

The exposure to extremely high temperatures varies across population groups. Those with better adaptation strategies (such as air conditioning) suffer less. This paper combines China's daily mean temperature data with comprehensive national survey data at the household level and estimates the relationship between high-temperature exposure and adaptation behavior of urban dwellers. We find that the usage of air conditioning and electric fans by urban households in China increases with their summer high-temperature exposures. The rise in the number of days with extreme heat (mean temperature exceeding 80 °F) induces the purchase and use of air conditioning. High-temperature adaptability varied across households-the rich are more likely to increase air conditioning usage to cope with the high-temperature discomfort; while the poor are less likely to afford such a market product for adaptation, they suffer more from high-temperature exposure. Such a variation in the affordability and usage of market products to adapt to climate risks will exacerbate the climate-induced inequality.

Thermo-TRPs and gut microbiota are involved in thermogenesis and energy metabolism during low temperature exposure of obese mice.

Ambient temperature and food composition can affect energy metabolism of the host. Thermal transient receptor potential ion channels (thermo-TRPs) can detect temperature signals and are involved in the regulation of thermogenesis and energy homeostasis. Further, the gut microbiota have also been implicated in thermogenesis and obesity. In the present study, we tested the hypothesis that thermo-TRPs and gut microbiota are involved in reducing diet-induced obesity (DIO) during low temperature exposure. C57BL/6J mice in obese (body mass gain >45%), lean (body mass gain <15%) and control (body mass gain <1%) groups were exposed to high (23±1°C) or low (4±1°C) ambient temperature for 28 days. Our data showed that low temperature exposure attenuated DIO, but enhanced brown adipose tissue (BAT) thermogenesis. Low temperature exposure also resulted in increased noradrenaline (NA) concentrations in the hypothalamus, decreased TRP melastatin 8 (TRPM8) expression in the small intestine, and altered composition and diversity of gut microbiota. In DIO mice, there was a decrease in overall energy intake along with a reduction in TRP ankyrin 1 (TRPA1) expression and an increase in NA concentration in the small intestine. DIO mice also showed increases in Oscillospira, [Ruminococcus], Lactococcus and Christensenella and decreases in Prevotella, Odoribacter and Lactobacillus at the genus level in fecal samples. Together, our data suggest that thermos-TRPs and gut microbiota are involved in thermogenesis and energy metabolism during low temperature exposure in DIO mice.

Strength Development and Elemental Distribution of Dolomite/Fly Ash Geopolymer Composite under Elevated Temperature.

A geopolymer has been reckoned as a rising technology with huge potential for application across the globe. Dolomite refers to a material that can be used raw in producing geopolymers. Nevertheless, dolomite has slow strength development due to its low reactivity as a geopolymer. In this study, dolomite/fly ash (DFA) geopolymer composites were produced with dolomite, fly ash, sodium hydroxide, and liquid sodium silicate. A compression test was carried out on DFA geopolymers to determine the strength of the composite, while a synchrotron Micro-Xray Fluorescence (Micro-XRF) test was performed to assess the elemental distribution in the geopolymer composite. The temperature applied in this study generated promising properties of DFA geopolymers, especially in strength, which displayed increments up to 74.48 MPa as the optimum value. Heat seemed to enhance the strength development of DFA geopolymer composites. The elemental distribution analysis revealed exceptional outcomes for the composites, particularly exposure up to 400 °C, which signified the homogeneity of the DFA composites. Temperatures exceeding 400 °C accelerated the strength development, thus increasing the strength of the DFA composites. This appears to be unique because the strength of ordinary Portland Cement (OPC) and other geopolymers composed of other raw materials is typically either maintained or decreases due to increased heat.

Evolution of phenolic and volatile compounds during bottle storage of a white wine without added sulfite.

BACKGROUND: Bottle storage can affect color, aroma and phenolic composition of white wine. Very little information is reported about the bottle evolution during storage of white wines without added sulfites and/or using other antioxidants. This work is aimed at studying the evolution of the main enological parameters, phenolic and volatile profiles of a white wine without added sulfites, during 15 months of storage in bottle at different light and temperature conditions, compared with a control stored with sulfur dioxide. Dark storage at 12 °C (D12-S, D12-NS) and 30 °C (D30-S, D30-NS) were compared to investigate the temperature effect, meanwhile uncontrolled temperature and light condition (UTL-S, UTL-NS) simulated improper storage conditions. RESULTS: Volatile acidity, absorbance at 420 nm and total phenols were higher in UTL-NS and D30-NS wines. The trans forms of hydroxycinnamic esters decreased, whereas, the cis forms, as well as caffeic acid derivatives, significantly increased in samples without added sulfites. The storage without sulfites also accelerated the hydrolysis of acetate esters. However, it did not affect most of the ethyl esters whose content remained almost the same between sulfite added (S) and no sulfite added (NS) wines. CONCLUSION: The presence of sulfites in the bottle helped to preserve the volatile compounds of young wines; however, even more important seemed to be the optimal storage (dark and low temperature), as unsuitable conditions favored aroma degradation of bottled wine, regardless of sulfite protective action. © 2019 Society of Chemical Industry.

Socio-economic, infrastructural and health-related risk factors associated with adverse heat-health effects reportedly experienced during hot weather in South Africa.

INTRODUCTION: Poor urban communities are likely to bear the brunt of climate change impacts on health and well-being. The City of Johannesburg, South Africa, is predicted to experience an average increase in ambient temperature of 4°C by 2100. Focusing on the urban environment, this study aimed to determine socio-economic, infrastructural and health-related risk factors for heat-related adverse health effects. METHODS: This was a cross-sectional study. Data of interest were collected using a pretested and validated questionnaire administered to parents of children attending schools participating in a school heat study. Information related to demographic, socio-economic and household-level determinants of health, which has an impact on the individual prevalence of adverse heat-health effects associated with hot weather, was collected for 136 households and 580 individuals. RESULTS: Sweating (n = 208 individuals; 35%), headache and nausea (n = 111; 19%) and weakness, fatigue and dizziness (n = 87; 15%) were the most common heat-health effects reportedly experienced by individuals (n = 580) during hot weather. Individuals who suffered from hypertension (OR = 2.32, 95% CI: 1.34 - 4.05, p = 0.003) and individuals older than 60 years (OR = 1.81, 95% CI: 1.27-1.99, p < 0.001) compared to other age groups were more likely to experience 'any heat-health effects'. Living in government-sponsored detached housing and in houses with asbestos roofs were associated with an increase in reported experience of 'any heat-health effects' compared to living in other housing types. CONCLUSION: Heat-health awareness campaigns should target people suffering from pre-existing diseases and the elderly, as these groups are especially vulnerable to heat. Focus should also be given to appropriate roofing and insulation in government-sponsored housing since summertime temperatures are projected to increase.

Liver proteome dataset of Sparus aurata exposed to low temperatures.

We report the proteomic dataset of livers from Sparus aurata exposed to low temperature during growth. Gilthead sea bream juveniles were reared in Recirculating Aquaculture Systems (RAS) and exposed to a temperature ramp made of two phases of four weeks each: a Cooling phase from 18 °C (t0) to 11 °C (t1) and a Cold Maintenance phase at 11 °C (t1-t2) in a 8 week feeding trial. At the end of the experiment, sea bream livers were collected and analyzed with a shotgun proteomics approach based on filter-aided sample preparation followed by tandem mass spectrometry, peptide identification carried out using Sequest-HT as search engine within the Proteome Discoverer informatic platform, and label-free differential analysis. The mass spectrometry data have been deposited to the ProteomeXchange Consortium via the PRIDE partner repository with the dataset identifier PXD011059 (Vizcaíno et al., 2016; Deutsch et al., 2017; Perez-Riverol et al., 2016). The dataset described here is also related to the research article entitled "Liver proteomics of gilthead sea bream (Sparus aurata) exposed to cold stress" (Ghisaura et al., 2019).