Potential for large losses of carbon from non-native conifer plantations on deep peat over decadal timescales.

Peatland drainage is a large source of anthropogenic CO2 emissions. While conversion to agriculture is widely acknowledged to lead to "irrecoverable" carbon (C) losses, in contrast the C impacts of peatland forestry are poorly understood, especially in intensively managed plantations. Losses of C from peat oxidation are highly variable and can be compensated for by gains of C in trees, depending on the lifecycle of the timber and timescale considered. Here, we used ITRAX scanning to enable rapid detection of the Hekla 4 cryptotephra layer as a reliable chronological marker above which peat properties and C stocks could be compared between open and afforested blanket bog cores in the Flow Country of Northern Scotland. At one site, Bad a' Cheò, we combine replicated core pair comparisons (n = 19) with timber extraction data to derive net ecosystem C balance over the lifetime of the plantation. Here the reduction in peat C carbon storage above Hekla 4 in afforested samples (67 t C ha-1) is only partially compensated by tree C sequestration (47 t C ha-1), leading to a net ecosystem C balance indicating a loss of 20 t C ha-1 over the 50 years since the plantation was established. At that site, ∼65 % of tree C rapidly returned to the atmosphere, as it was primarily used for heat and power generation. Across the wider Flow country region, a simplified paired sampling method was adopted at eight further sites, finding a either a loss or negligible change in peat C storage above Hekla 4 in afforested samples with a mean loss of 86 t C ha-1 and median loss of 50 t C ha-1. This study suggests that potentially substantial C losses have been an unintended consequence of non-native conifer afforestation over deep blanket bogs.

Peat profile database from peatlands in Canada.

Peatlands cover approximately 12% of the Canadian landscape and play an important role in the carbon cycle through their centennial- to millennial-scale storage of carbon under waterlogged and anoxic conditions. In recognizing the potential of these ecosystems as natural climate solutions and therefore the need to include them in national greenhouse gas inventories, the Canadian Model for Peatlands module (CaMP v. 2.0) was developed by the Canadian Forest Service. Model parameterization included compiling peat profiles across Canada to calibrate peat decomposition rates from different peatland types, to define typical bulk density profiles, and to describe the hydrological (i.e., water table) response of peatlands to climatic changes. A total of 1217 sites were included in the dataset from published and unpublished sources. The CORESITES table contains site location and summary data for each profile, as well as an estimate of total carbon mass per unit area (in megagrams of C per hectare). Total carbon mass per unit area at each location was calculated using bulk density and carbon content through each profile. The PROFILES table contains data for depth (in centimeters), bulk density (in grams per cubic meter), ash and carbon content (in percentage), and material descriptions for contiguous samples through each peat profile. Data gaps for bulk density and C content were filled using interpolation, regression trees, and assigned values based on material description and/or soil classification to allow for the estimation of total carbon mass per unit area. A subset of the sites (N = 374) also have pH and pore water trace-elemental geochemistry data and are found in the WATER table. The REFERENCES table contains the full citation of each source of the data and is linked to each core location through the SOURCEDATA table. The LOOKUP table defines codes in the database that required more space that what was sufficient in the metadata tables. The data can be accessed on Open Government Canada and will be useful for future work on carbon stock mapping and ecosystem modeling. All metadata and data are provided © Her Majesty the Queen in Right of Canada, 2023 and information contained in this publication may be reproduced for personal or public noncommercial purposes with attribution, whereas commercial reproduction and distribution are prohibited except with written permission from NRCan; complete details are noted in the Supporting Information file Metadata S1 (see Class III.B.3: Copyright restrictions).

Impact of vermicompost addition on water availability of differently textured soils.

Vermicompost is an organic material that is abundant in humic acids and nutrients. It is obtained through the bio-oxidation and stabilization processes carried out by earthworms. It has been proven to bring several benefits to different soil properties, including bulk density, soil structure, and plant available water capacity (PAWC). This investigation was conducted to fill the knowledge gap in some critical factors related to vermicompost application, specifically the short-term influence of a single vermicompost application with increasing doses on soil wettability and physical quality of differently textured soils. Water repellency of vermicompost and soil/vermicompost mixtures was investigated at different moisture contents by the water drop penetration time test, whereas physical quality was assessed by 35 soil indicators related to bulk density, soil water retention curve, and pore size distribution function. Despite vermicompost showed from strong to severe hydrophobicity at moisture content lower than the field capacity, amended soils were at the most slightly water repellent thus indicating that, under field conditions, the hydrophobicity attributable to soil amendment with vermicompost could be considered negligible. Soil physical quality was effectively affected by vermicompost addiction with different outcomes depending on soil texture. Indicators linked to PAWC generally increased at increasing the vermicompost rate in the coarse soils whereas no significant effect was observed for intermediate and fine soils. For example, plant available water capacity of coarse-textured soils increased from an average initial value of 0.056 cm3 cm-3 to an optimal value of 0.15 cm3 cm-3 when a vermicompost addition dose of about one-third by volume (34 %) was applied. In the finest soil, drainable porosity significantly increased from an initial value of 0.09 cm3 cm-3 to 0.23 cm3 cm-3 when the maximum vermicompost dose (43 %) was applied thus indicating that amendment could be effective in enhancing water and air circulation.

Soil properties predict below-ground community structure, but not nematode microbiome patterns in semi-arid habitats.

Microbial and microeukaryotic communities are extremely abundant and diverse in soil habitats where they play critical roles in ecosystem functioning and services that are essential to soil health. Soil biodiversity is influenced by above-ground (vegetation) and below-ground factors (soil properties), which together create habitat-specific conditions. However, the compound effects of vegetation and soil properties on soil communities are less studied or often focused on one component of the soil biota. Here, we integrate metabarcoding (16S and 18S rRNA genes) and nematode morphology to assess the effects of habitat and soil properties shaping microbial and microeukaryotic communities as well as nematode-associated microbiomes. We show that both vegetation and soil properties (soil bulk density) were major factors structuring microbial and microeukaryotic communities in semi-arid soil habitats. Despite having lower nutrients and lower pH, denser soils displayed significantly higher alpha diversity than less dense soils across datasets. Nematode-associated microbiomes have lower microbial diversity, strongly differ from soil microbes and are more likely to respond to microscale variations among samples than to vegetation or soil bulk density. Consequently, different nematode lineages and trophic groups are likely to display similar associated microbiomes when sharing the same microhabitat. Different microbiome taxa were enriched within specific nematode lineages (e.g. Mycobacterium, Candidatus Cardinium) highlighting potentially new species-specific associations that may confer benefits to their soil nematode hosts. Our findings highlight the importance of exploring above- and below-ground effects to assess community structure in terrestrial habitats, and how fine-scale analyses are critical for understanding patterns of host-associated microbiomes.

Soil properties modulate actual evapotranspiration and precipitation impacts on crop yields in the USA.

Crop yields are affected by hydroclimatic and edaphic conditions, but their interacting roles are often neglected when assessing crop yields at the regional scale. Moreover, often used hydroclimatic conditions such as precipitation and temperature are not as physiologically linked to primary production and yields as actual evapotranspiration. Using statistical models, we quantified the combined effects of edaphic and hydroclimatic conditions on county yields of irrigated rice and rainfed corn, soybean, and spring and winter wheat in the USA (2000-2019). Precipitation and temperature, or actual evapotranspiration, aggregated during the growing season or before and after flowering/silk emergence, in interaction with soil sand content or bulk density, explained up to 87 % of the yield variability. However, actual evapotranspiration explained yields better than precipitation and temperature and their interactions for most combinations of crops and growth periods. At high actual evapotranspiration, yield plateaued or, for spring wheat, decreased. Yields were generally most sensitive to changes in hydroclimatic conditions during part of rather than the entire growing season, and most often after flowering. Soil texture and bulk density modulated the impacts of hydroclimatic conditions: corn and soybean yields were higher in finer soils compared with sandy soils under high evapotranspiration, but lower at low evapotranspiration. Additionally, the yield-maximizing precipitation decreased with sand content and increased with bulk density for most crops. Increasingly available actual evapotranspiration estimates, combined with soil properties, offer an alternative, and more physiologically-based, yield predictor over large climatic gradients to the more widely used precipitation and temperature.

Structure Formation in Engineered Wood Using Wood Waste and Biopolyurethane.

This research aims to find suitable processing methods that allow the reuse of wood waste to produce wood waste-based engineered wood logs for construction that meet the strength requirements for structural timber for sawn structural softwood. Three types of wood waste were examined: wood packaging waste (W), waste from the construction and furniture industry (PLY), and door manufacturing waste (DW). The wood waste was additionally crushed and sieved, and the granulometric composition and shape of the particles were evaluated. The microstructure of the surface of the wood waste particles was also analysed. A three-component biopolyurethane adhesive was used to bind wood waste particles. An analysis of the contact zones between the particles and biopolyurethane was performed, and the adhesion efficiency of their surfaces was evaluated. Analysis was performed using tensile tests, and the formation of contact zones was analysed with a scanning electron microscope. The wood particles were chemically treated with sodium carbonate, calcium hypochlorite, and peroxide to increase the efficiency of the contact zones between the particles and the biopolyurethane adhesive. Chemical treatment made fillers up to 30% lighter and changed the tensile strength depending on the solution used. The tensile strength of engineered wood prepared from W and treated with sodium carbonate increased from 8331 to 12,702 kPa compared to untreated waste. Additionally, the compressive strength of engineered wood made of untreated and treated wood waste particles was determined to evaluate the influence of the wood particles on the strength characteristics.

Soil carbon stocks in temperate grasslands reach equilibrium with grazing duration.

Lost soil organic carbon (SOC) in degraded grasslands can be restored via the 'grazing exclusion' practice, but it was unknown how long (# of years) the restoration process can take. A synthesis of four decades of studies revealed that grazing exclusion increased SOC stocks in the topsoil (0-0.30 m) by 14.8 % (±0.8 Std Err), on average, compared to moderate-to-heavy grazing (MtH); During which SOC stock increased steadily, peaked in Year 18.5, and then declined. At peak, SOC stock was 42.5 % greater under grazing exclusion than under MtH due to 100.4 ± 4.2 % increase in aboveground biomass and 80.3 ± 33.5 % increase in root biomass. Grazing exclusion also increased soil C:N ratio by 7.6 % while decreasing bulk density by 9.4 %. Grazing exclusion could be ceased 18.5 years after initiation of grazing exclusion as plant biomass input balances carbon decomposition and SOC equilibrium occurs then additional benefits start diminishing.

Mapping global distributions of clay-size minerals via soil properties and machine learning techniques.

Clay-size mineral is a vital ingredient of soil that influences various environment behaviors. It is crucial to establish a global distribution map of clay-size minerals to improve the recognition of environment variations. However, there is a huge gap of lacking some mineral contents in poorly accessible remote areas. In this work, machine learning (ML) approaches were conducted to predict the mineral contents and analyze their global abundance changes through the relationship between soil properties and mineral distributions. The average content of kaolinite, illite, smectite, vermiculite, chlorite, and feldspar were predicated to be 28.69 %, 22.30 %, 12.42 %, 5.43 %, 5.03 %, and 1.44 % respectively. Model interpretation showed that topsoil bulk density and drainage class were the most significant factors for predicting all six minerals. It could be seen from the feature importance analysis that bulk density notably reflected the distribution of 2:1 layered minerals more than that of 1:1 mineral. High drainage favored secondary minerals development, while low drainage was more benefited for primary minerals. Moreover, the content variation of different minerals aligned with the distribution of corresponding soil properties, which affirmed the accuracy of established models. This study proposed a new approach to predict mineral contents through soil properties, which filled a necessary step of understanding the geochemical cycles of soil-related processes.

Impact dynamics of granular debris flows based on a small-scale physical model.

The peak pressure of a granular debris flow at low Froude conditions can be calculated with knowledge of the stress anisotropy and the bulk density as well as the run-up height at impact. Based on a small-scale physical model, measurements of stress anisotropy and flow density values at impact are presented and applied to existing run-up prediction models, and further compared with back-calculated run-up coefficients from measured maximum impact pressures. For this purpose, we conducted 17 experiments with impact measurements and six experiments without impact measurements at Froude numbers, ranging from 0.84 to 2.41. Our results indicate that run-up heights are best reproduced by predictive models, either based on energy or mass and moment conservation, when anisotropic stress conditions, found in this study to range from 1.2 to 5.0, and bulk density variations due to impact, ranging in this study from 0.8 to 2.3, are considered. The influence of stress anisotropy and density variation on the run-up prediction differs, depending on the modelling approach. For the calculation of run-up heights based on the energy conservation concept, the influence of stress anisotropy becomes more significant with increasing Froude number, whereas for models based on mass and momentum conservation, bulk density variations have a greater influence on the estimation of the potential run-up.

Use of Alkaline-Activated Energy Waste Raw Materials in Geopolymer Concrete.

Silica fly ash, Certyd aggregate, and an alkaline solution were used to produce lightweight geopolymer concretes. The compressive strength, water absorption, and bulk density results, along with SEM photos showing the structure of the obtained composite, were obtained. Tests conducted on the specifications of lightweight geopolymer concretes have revealed significant chemical interactions between the ash aggregate and the geopolymer mortar, particularly when the coarse aggregate surface has been pre-treated with an alkaline solution. A statistical analysis of the experimental data, which investigated the influence of three key variables on the compressive strength, water absorption, and bulk density of lightweight geopolymer concrete (LBG), identified the following factors as having the most substantial impact: the quantity of alkali used, the curing temperature, and the concentration of alkali in the mixture. The optimal test series exhibited a commendable compressive strength of 20.14 megapascals (MPa), accompanied by a water absorption rate of 14.72%, and a bulk density of 1486.6 kg per cubic meter (kg/m³). These findings underscore the importance of alkali content, curing temperature, and alkali concentration in tailoring the properties of lightweight geopolymer concrete to meet specific performance requirements.

On the detailed mapping of peat (raised bogs) using airborne radiometric data.

This study concerns the applied use of the natural radioactivity in soils. The relevance of airborne radiometric (gamma ray) survey data to peat mapping is now well established and such data have been used in a stand-alone sense and as covariates in machine learning algorithms. Here we present a method to use these data to accurately map the boundaries of peat (raised bogs). This has the potential to assist with the estimation of carbon stocks using a property-based assessment of soil. The significance of such regionally-uniform survey data lies in the subsurface information carried by the measurement which contrasts with the surficial nature of many other covariates. Soils attenuate radiometric flux by virtue of their bulk density (and associated carbon content) and water saturation level. The high attenuation levels in low density, wet peat materials give rise to a distinctive soil response. Here an entirely physics-based assessment of flux attenuation is carried out both theoretically and empirically. Radiometric data from the ongoing Tellus airborne survey of Ireland are used. The study area is characterised by an extensive assemblage of discrete raised peat bogs in a framework of largely mineral soils. Peat is detected by a property contrast with adjacent soils and so we consider all soils within the study area. The relatively low lateral resolution of the airborne data is demonstrated by modelling and we examine the behaviour of a combined spatial derivative of the data. The procedure allows the identification of the edges of the 128 peat polygons considered and indicates other additional potential areas of subsurface peat. The data appear to resolve the differences that exist across three available soil/peat databases that are used for the validation of the results obtained.

Effect of Biostimulant, Manure Stabilizer, and Manure on Soil Physical Properties and Vegetation Status.

Food production sustainability is one of contemporary agriculture's fundamental challenges. Farmers are currently facing high input prices in crop production and declining organic matter in the soil. For this reason, a field experiment was established to assess the effect of the biostimulant NeOsol (NS), the manure stabilizer Z'fix (ZF), farmyard manure (FM), and their combination in farm practice. In situ measurements provided information on the change in bulk density (BD), unit draft (UD), saturated hydraulic conductivity (SHC), and cone index (CI). Furthermore, the vegetation status was investigated via vegetation indices, and the yield and quality parameters were assessed. Management of the experimental field resulted in an overall decrease in BD over time for the treated variants compared to the control (CL). The decrease with time was also verified in the case of UD and CI at the depth zone of 10-20 cm. Variants FM (by 8.0%), FM_NS (by 7.3%), and FM_ZF_NS (by 3.8%) proved to have lower UD values than CL. An overall increase in SHC and in yield was observed over time. Concerning SHC, only FM (by 58.5%) proved different from CL. The yield of all the treated variants, i.e., NS (by 8.2%), FM (by 10.8%), FM_NS (by 14.1%), FM_ZF (by 17.8%), and FM_ZF_NS (by 20.1%), surpassed CL. Simultaneously, none of the examined treatments proved to have any adverse effect either on soil or on plant-related variables.

Carbon content and other soil properties of near-surface peats before and after peatland restoration.

Peatland restoration usually aims at restarting the peatlands' function to store carbon within peat. The soil properties of the near-surface peat can give a first understanding of this process. Therefore, we sampled pH value, total organic carbon content (TOC), total nitrogen content (TN), C/N ratio as well as dry bulk density (BD), and describe the structure of near-surface peats in six restored fens in North-East Germany before (2002-2004) and after (2019-2021) restoration. Before restoration, the study sites showed peat degradation to various extents in their near-surface peats. pH values remained relatively stable over time. Comparing the degraded peat horizons, TOC increased significantly in four study sites, ranging from 35.7% to 47.8% in 2002-2004 and from 42.5% to 54.0% in 2019-2021. TN varied from 1.5% to 3.5% in 2002-2004 and from 1.8% to 3.2% in 2019-2021, but changes were only significant in one site, showing a slight decrease. In three sites, the increase in C/N ratio was significant, indicating lower nutrient availability. BD ranged from 0.08 to 0.48 g/cm3 in 2002-2004 and from 0.10 to 0.16 g/cm3 in 2019-2021, decreasing significantly in four sites. The structure of the degraded peat horizons changed after restoration to a more homogenous, sludge mass with larger re-aggregates. In three sites, new peat moss peat layers above the degraded soil horizon were present in 2019-2021, with a mean thickness of 6.8 to 36.1 cm. The structure was comparable to typical, slightly decomposed peat moss peat. Our findings suggest that within about 17 years after fen restoration, and thereby a water table rise close to surface, TOC of the near-surface peats increased to values that are typical for undisturbed peatlands. This indicates that restoration can lead to the re-establishment of peatlands as potential carbon sinks, with TOC within the near-surface peat as one key factor in this process. Further, we assume that the decrease in nutrient availability, decrease of BD, and new, undisturbed peat layers can favor the establishment of mire-specific biodiversity and support ecosystem services similar to near-natural mires.

Dynamics of soil penetration resistance, moisture depletion pattern and crop productivity determined by mechanized cultivation and lifesaving irrigation in zero till blackgram.

Rice fallow black gram is grown under the residual moisture situation as a relay crop in heavy texture montmorillonite clay soil under zero till condition. Since the crop is raised during post monsoon season, the crop often experiences terminal stress due to limited water availability and no rainfall. Surface irrigation in montmorillonite clay soil is determent to pulse crop as inundation causes wilting. Therefore, zero tilled rice fallow black gram has to be supplemented with micro irrigation at flowering stage (35 days after sowing) to alleviate moisture stress and to increase the productivity as well. Hence micro farm pond in a corner of one ha field was created to harvest the rain water during monsoon season and the same was utilized to supplement the crop with lifesaving irrigation through mobile sprinkler at flowering stage for the crop grown under conservation agriculture. Soil cracking is also the common phenomena of montmorillonite clay soil where evaporations losses would be more through crack surfaces. The present study was therefore conducted to study the changes in the soil physical properties, crop establishment and productivity in conjunction with mechanized sowing and harvest and supplemental mobile sprinkler irrigation. Sowing of black gram by broadcasting 10 days prior to the manual harvest of rice, manual drawn single row seed drill after the machine harvest of rice and sowing by broadcasting at 4 days prior to machine harvest of rice was experimented separately and in combination with lifesaving irrigation. Results indicated that the number of wheel passes and lifesaving irrigation had a very strong impact on soil penetration resistance and soil moisture. Combined harvester followed by no till seed drill increased the soil penetration resistance in all the layers (0-5 cm, 5-10 cm and 10-15 cm). Two passes of wheel increased the mean soil penetration resistance from 407 KPa to 502 KPa. The soil penetration resistance (0-5 cm) at harvest shown that black gram sown by manual broadcasting 10 days prior to manual harvest of paddy supplemented with life irrigation on 30 DAS reduced the soil penetration resistance from 690 Kpa to 500 Kpa, 740 Kpa to 600 Kpa and 760 Kpa to 620 Kpa respectively at 0-5 cm, 5-10 cm and 10-15 cm layer. In general, moisture depletion rate was rapid in the surface layer of 0-5 cm as compared to other layers of 5-10 cm and 10-15 cm up to 30 DAS (Flowering stage). The moisture content and the soil penetration resistance had an inverse relationship. The soil penetration resistance also had an inverse relationship with the root length in which the root length lowers as the soil penetration resistance increases. The soil crack measured at 60 DAS was deeper with no till seed drill (width of 3.94 cm and depth of 13.67 cm) which was mainly due to surface layer compaction. The relative water content, specific leaf weight and chlorophyll content were significantly improved through the supplemental irrigation given on 30 DAS irrespective of crop establishment methods. The results further indicated that compaction of ploughed layer in the moist soil due to combined harvester and no till seed drill had a negative impact on yield (457 kg ha-1), which was improved by 19.03 per cent due to increased soil moisture with supplemental irrigation. The mean yield increase across different treatments due to supplemental lifesaving irrigation through mobile sprinkler was 20.4 per cent.

Dataset of physical properties of histosols topsoils effected by wildfire in Indonesia.

Physical properties of peat are widely applied to detect the quality of peatland ecosystem. A comprehensive dataset on the peat properties is the foundation for the development tool and model of peat ecosystem, especially in region with frequent wildfire. Here we established a tabular dataset for physical properties of lowland tropical peatland in Indonesia. The data were obtained in dry season 2019 and 2023, respectively, at Jambi and Central Kalimantan peatlands. The dataset comprises of 66 peat samples from two land-uses namely secondary forest and ex-burned lowly vegetation. The physical properties are bulk density, porosity, water retention at four pressures (-1, -10, -25, and -1500 kPa), and water holding capacity. In addition, a set parameter of van Genuchten for water retention curve is available. The field-observed dataset provides a solid base for a better understanding of physical peat properties and can be used as a first step to develop peat water retention database in lowland tropical peatlands.

Influence of Cement Kiln Dust on Long-Term Mechanical Behavior and Microstructure of High-Performance Concrete.

Cement production in the world market is steadily increasing. In 2000, it was 1600 million tons, while as of 2013, the annual amount exceeded 4000 million tons. The burning of cement clinker is associated with the generation of waste. It is estimated that the amount of cement kiln dust (CKD), during combustion, reaches about 15-20%, which means 700 million tons per year. However, not all types of by-products are reusable due to high alkali, sulfate, and chloride contents, which can adversely affect the environment. One environmentally friendly solution may be to use CKD in the production of high-performance concrete (HPC), as a substitute for some of the cement. This paper presents a study of the short- and long-term physical and mechanical properties of HPC with 5%, 10%, 15%, and 20% CKD additives. The experiments determined density, water absorption, porosity, splitting tensile strength, compressive strength, modulus of elasticity, ultrasonic pulse velocity, and evaluated the microstructure of the concrete. The addition of CKD up to 10% caused an increase in the 28- and 730-day compressive strengths, while the values decreased slightly when CKD concentration increased to 20%. Splitting tensile strength decreased proportionally with 5-20% amounts of CKD regardless of HPC age. Porosity, absorbability, and ultrasonic pulse velocity decreased with increasing cement dust, while the bulk density increased for HPC with CKD. Microstructure analyses showed a decrease in the content of calcium silicate hydrate (C-S-H), acceleration of setting, and formation of wider microcracks with an increase in CKD. From the results, it was shown that a 15% percentage addition of CKD can effectively replace cement in the production of HPC and contribute to reducing the amount of by-product from the burning of cement clinker.

Pyrolysis kinetics and potential utilization analysis of cereal biomass by-products; an experimental analysis for cleaner energy productions in India.

The optimal utilization of biomass relies heavily on the specific material and individual needs. Cereal biomass by-products can potentially be employed in thermochemical processes such as pyrolysis and gasification. To compare biomass sources, ultimate analysis, biochar potential, proximate analysis, thermal gravimetric analysis, price per megajoule generated heat, surface texture, and availability are used. A global survey of biomass wastes and opportunities for heat generation is presented in the current article. Here, nine different cereal-based agricultural waste products (barley, wheat, millet, oats, rice, rye straw, sorghum straw/stalk, and maize cob) are studied. Cereal wastes are compared based on calorific value, water content, volatile matter, ash content and ash chemical composition, bulk density, charring properties, availability, and transportation. According to the estimate, 156 million metric tonnes per year, or 6% of India's total emissions, could be eliminated by rice husk alone. Wheat straws, on the other hand, can cut emissions by 2%. Additionally, processing these nine feedstocks might result in the production of 40 GW of electrical energy, which would increase the installed capacity of India's national electric grid by 9%.

The importance of accounting method and sampling depth to estimate changes in soil carbon stocks.

BACKGROUND: As interest in the voluntary soil carbon market surges, carbon registries have been developing new soil carbon measurement, reporting, and verification (MRV) protocols. These protocols are inconsistent in their approaches to measuring soil organic carbon (SOC). Two areas of concern include the type of SOC stock accounting method (fixed-depth (FD) vs. equivalent soil mass (ESM)) and sampling depth requirement. Despite evidence that fixed-depth measurements can result in error because of changes in soil bulk density and that sampling to 30 cm neglects a significant portion of the soil profile's SOC stock, most MRV protocols do not specify which sampling method to use and only require sampling to 30 cm. Using data from UC Davis's Century Experiment ("Century") and UW Madison's Wisconsin Integrated Cropping Systems Trial (WICST), we quantify differences in SOC stock changes estimated by FD and ESM over 20 years, investigate how sampling at-depth (> 30 cm) affects SOC stock change estimates, and estimate how crediting outcomes taking an empirical sampling-only crediting approach differ when stocks are calculated using ESM or FD at different depths. RESULTS: We find that FD and ESM estimates of stock change can differ by over 100 percent and that, as expected, much of this difference is associated with changes in bulk density in surface soils (e.g., r = 0.90 for Century maize treatments). This led to substantial differences in crediting outcomes between ESM and FD-based stocks, although many treatments did not receive credits due to declines in SOC stocks over time. While increased variability of soils at depth makes it challenging to accurately quantify stocks across the profile, sampling to 60 cm can capture changes in bulk density, potential SOC redistribution, and a larger proportion of the overall SOC stock. CONCLUSIONS: ESM accounting and sampling to 60 cm (using multiple depth increments) should be considered best practice when quantifying change in SOC stocks in annual, row crop agroecosystems. For carbon markets, the cost of achieving an accurate estimate of SOC stocks that reflect management impacts on soils at-depth should be reflected in the price of carbon credits.

Characterization of different solid fuels from waste for an advanced online fuel control system designed for large-scale incineration plants.

Despite many years of experience in the incineration of solid fuels from waste, the heterogeneity of solid fuels and their varying properties still pose a challenge for a stable and clean combustion in large-scale incineration plants. In modern facilities such as municipal waste incineration plants there still exists a lack of knowledge on the exact amount and calorific value of waste entering onto the grate. Based on the works of Warnecke et al. and Zwiellehner et al., in our project 'AdOnFuelControl', we determined the initial bulk density at the feed hopper by measuring the weight of the waste via the crane weigher and the volume via a high-performance 3D laser scanner. With the help of the determined bulk density, the lower heating value (LHV) and the compression in the feed hopper were calculated. All this information was integrated into the combustion control system, which provided a high potential for an optimized operation of the plant. In this article, six different fuels (fresh and aged municipal solid waste, refuse-derived fuel (fluff), refuse-derived fuel (fine grain), waste wood and dried, grained sewage sludge) were examined for the elemental composition, the LHV, fuel-specific parameters and the compression behaviour. In addition, initial tests with the 3D laser scanner as well as formulas for the calculation of the density in the feed hopper were presented. Based on the results of the experiments, the chosen approach seems very promising for optimized combustion control in large-scale incineration plants. As a next step, the gained knowledge and technology should be integrated in the municipal waste incineration plant.

Temporal and vertical dynamics of carbon accumulation potential under grazing-excluded grasslands in China: The role of soil bulk density.

Despite the progress made in understanding relevant carbon dynamics under grazing exclusion, previous studies have underestimated the role of soil bulk density (BD), and its implications for potential accumulation of soil organic carbon (SOC), especially at regional scale over long term. In this study, we first constructed a database covering a vast majority of the grasslands in northwestern China based on 131 published literatures. A synthesis was then conducted by analyzing the experimental data to comprehensively investigate the mechanisms of vegetation recovery, carbon-nitrogen coupling, and the importance of changed soil BD in evaluating SOC sequestration potential. The results showed that although the recovery of vegetation height and cover were both critical for improving vegetation biomass, vegetation height required a longer recovery period. While the SOC accumulation was found to be greater in surface layers than deeper ones, it exhibited a reduced capacity for carbon sequestration and an increased risk of SOC loss. Grazing exclusion significantly reduced soil BD across different soil profiles, with the rate of change influenced by soil depth, time, geographical and climatic conditions. The potential for SOC accumulation in the top 30 cm of soil based on data of 2003-2022 was 0.78 Mg ha-1 yr-1 without considering BD effects, which was significantly underestimated compared to that of 1.16 Mg ha-1 yr-1 when BD changes were considered properly. This suggests that the efficiency of grazing exclusion in carbon sequestration and climate mitigation may have been previously underreported. Furthermore, mean annual precipitation represented the most relevant environmental factor that positively correlated to SOC accumulation, and a wetter climate may offer greater potential for carbon accumulation. Overall, this study implies grazing exclusion may play an even more critical role in carbon sequestration and climate change mitigation over long-term than previously recognized, which provides essential scientific evidence for implementing stepwise ecological restoration in grasslands.