Heterogeneous Nucleating Agent for High-Boiling-Point Nonhalogenated Solvent-Processed Organic Solar Cells and Modules.

High-boiling-point nonhalogenated solvents are superior solvents to produce large-area organic solar cells (OSCs) in industry because of their wide processing window and low toxicity; while, these solvents with slow evaporation kinetics will lead excessive aggregation of state-of-the-art small molecule acceptors (e.g. L8-BO), delivering serious efficiency losses. Here, a heterogeneous nucleating agent strategy is developed by grafting oligo (ethylene glycol) side-chains on L8-BO (BTO-BO). The formation energy of the obtained BTO-BO; while, changing from liquid in a solvent to a crystalline phase, is lower than that of L8-BO irrespective of the solvent type. When BTO-BO is added as the third component into the active layer (e.g. PM6:L8-BO), it easily assembles to form numerous seed crystals, which serve as nucleation sites to trigger heterogeneous nucleation and increase nucleation density of L8-BO through strong hydrogen bonding interactions even in high-boiling-point nonhalogenated solvents. Therefore, it can effectively suppress excessive aggregation during growth, achieving ideal phase-separation active layer with small domain sizes and high crystallinity. The resultant toluene-processed OSCs exhibit a record power conversion efficiency (PCE) of 19.42% (certificated 19.12%) with excellent operational stability. The strategy also has superior advantages in large-scale devices, showing a 15.03-cm2 module with a record PCE of 16.35% (certificated 15.97%).

Promotion of Activated Carbon on the Nucleation and Growth Kinetics of Methane Hydrates.

Due to the hybrid effect of physical adsorption and hydration, methane storage capacity in pre-adsorbed water-activated carbon (PW-AC) under hydrate favorable conditions is impressive, and fast nucleation and growth kinetics are also anticipated. Those fantastic natures suggest the PW-AC-based hydrates to be a promising alternative for methane storage and transportation. However, hydrate formation refers to multiscale processes, the nucleation kinetics at molecule scale give rise to macrohydrate formation, and the presence of activated carbon (AC) causes this to be more complicated. Although adequate nucleation sites induced by abundant specific surface area and pore texture were reported to correspond to fast formation kinetics at macroperspective, the micronature behind that is still ambiguous. Here, we evaluated how methane would be adsorbed on PW-AC under hydrate favorable conditions to improve the understanding of hydrate fast nucleation and growth kinetics. Microbulges on AC surface were confirmed to provide numerous nucleation sites, suggesting the contribution of abundant specific surface area of AC to fast hydrate nucleation and growth kinetics. In addition, two-way convection of water and methane molecules in micropores induced by methane physical adsorption further increases gas-liquid contact at molecular scale, which may constitute the nature of confinement effect of nanopore space.