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NpSe2 : a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous-Valent Metal.
Jin, Geng Bang; Malliakas, Christos D; Hu, Yung-Jin; Booth, Corwin H; Ibers, James A; Sokaras, D; Weng, T-C; Skanthakumar, S; Soderholm, L.
Affiliation
  • Jin GB; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA.
  • Malliakas CD; Current address: 3M Corporate Research Analytical Laboratory, St. Paul, MN, 55144, USA.
  • Hu YJ; Material Science Division, Argonne National Laboratory, Argonne, IL, 60439, USA.
  • Booth CH; Current address: Northwestern University, Evanston, IL, USA.
  • Ibers JA; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL, 60439, USA.
  • Sokaras D; Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, USA.
  • Weng TC; Department of Chemistry, Northwestern University, Evanston, IL, 60208-3113, USA.
  • Skanthakumar S; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California, 94025, USA.
  • Soderholm L; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, California, 94025, USA.
Angew Chem Int Ed Engl ; 58(45): 16130-16133, 2019 Nov 04.
Article in En | MEDLINE | ID: mdl-31549462
ABSTRACT
A new binary compound, NpSe2, possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valence-ambiguous Np cations.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2019 Document type: Article
Fulltext
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Angew Chem Int Ed Engl Year: 2019 Document type: Article