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A C,S bonded quasi-two-coordinate chromium(II) complex showing field-induced slow magnetic relaxation behaviour.
Luo, Qian-Cheng; Ge, Ning; Zhai, Yuan-Qi; Wang, Teng-Bo; Sun, Lin; Sun, Qi; Li, Fanni; Ouyang, Zhongwen; Wang, Zhen-Xing; Zheng, Yan-Zhen.
Affiliation
  • Luo QC; Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry, School of Chemistry and School of Physics,
  • Ge N; Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry, School of Chemistry and School of Physics,
  • Zhai YQ; Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry, School of Chemistry and School of Physics,
  • Wang TB; The School of Automation Science and Technology, No. 4 Building, Xi'an Jiaotong University, Siyuanhuan North Road, Xi'an, Shaanxi, P. R. China.
  • Sun L; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China. sunlin@vip.henu.edu.cn.
  • Sun Q; Department of General Surgery, The First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, Shaanxi 710061, P. R. China.
  • Li F; Department of Talent Highland, The First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, Shaanxi 710061, P. R. China.
  • Ouyang Z; Wuhan National High Magnetic Field Centre & School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R. China. zxwang@hust.edu.cn.
  • Wang ZX; Wuhan National High Magnetic Field Centre & School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074, P. R. China. zxwang@hust.edu.cn.
  • Zheng YZ; Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry, School of Chemistry and School of Physics,
Dalton Trans ; 51(24): 9218-9222, 2022 Jun 21.
Article in En | MEDLINE | ID: mdl-35670316
ABSTRACT
A C,S bonded quasi-two-coordinate Cr(II) complex, Cr(SAr*)2 (HSAr* = HSC6H3-2,6(C6H2-2,4,6-Pri3)2), has been synthesized according to literature precedent. Magnetic measurements, high-frequency/field electron paramagnetic resonance (HF-EPR) experiments and ab initio calculation studies show that the field-induced slow magnetic relaxation behaviour is caused by relatively weak axial magnetic anisotropy.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Year: 2022 Document type: Article
Fulltext
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Dalton Trans Year: 2022 Document type: Article