Ternary-metal Prussian blue analogues as high-quality sodium ion capturing electrodes for rocking-chair capacitive deionization.

ABSTRACT

Prussian blue analogs (PBAs) have gained much attention in the capacitive deionization (CDI) field because of their rigid open structure and good energy storage capacity. However, their desalination performance is still to be improved for practical application. Herein, we reported the NiCoFe ternary-metal PBAs materials and explored their application as Na+ capturing electrode in rocking-chair capacitive deionization (RCDI) system. On the one hand, the introduction of Ni2+ into CoFe PBA can effectively reduce the lattice changes in the (dis)charging process.On the other hand, the RCDI system with symmetrical structure could avoid the performance deficiency caused by the unbalanced capacity of common HCDI system. Due to the rationalized RCDI cell configuration and ternary-metal PBAs with improved stability, the NiCoFe-PBAs-based RCDI exhibits amazing desalination performance with maximum capacity of 131.4 mg·g-1 and rate of 0.46 mg·g-1·s-1 as well as optimum stability with 90.7 % capacity retention over 300 cycles, surpassing those of PBAs based CDI system reported previously. The special strategy in this work offers inspiration via optimizing the cell structure and electrode materials for the promising development of CDI systems.