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A porous and photoactive Ti-MOF based on a novel tetranuclear [Ti2Tb2] cluster.
Yao, Qingxia; Pan, Xuze; Si, Xuezhen; Wang, Xin; Zhang, Xiaoying; Hou, Jinle; Su, Jie; Qiu, Yi; Li, Jun.
Affiliation
  • Yao Q; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Pan X; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Si X; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Wang X; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Zhang X; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Hou J; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
  • Su J; College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, PR China. jie.su@pku.edu.cn.
  • Qiu Y; College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, PR China. jie.su@pku.edu.cn.
  • Li J; School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, PR China. yaoqingxia@lcu.edu.cn.
Chem Commun (Camb) ; 60(16): 2188-2191, 2024 Feb 20.
Article in En | MEDLINE | ID: mdl-38295378
ABSTRACT
A robust and porous titanium metal-organic framework (Ti-MOF; LCU-505) has been solvothermally synthesized based on an unprecedented tetranuclear Ti2(µ3-O)2Tb2(µ2-CH3COO)2(H2O)4(OOC-)8 cluster (abbreviated as [Ti2Tb2]) and tritopic 4,4',4''-s-triazine-2,4,6-triyl-tribenzoic acid ligand (H3TATB). LCU-505 shows remarkable water stability and permanent porosity for N2 and CO2 gas adsorption. Moreover, LCU-505 demonstrates n-type semiconductor behavior and good photocatalytic activity in the degradation of organic dyes.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Year: 2024 Document type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Chem Commun (Camb) Year: 2024 Document type: Article