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Photogenerated chlorine radicals activate C(sp3)-H bonds of alkylbenzenes to access quinazolinones.
Pan, Xin-Yao; Sun, Gui-Xia; Huang, Fang-Ping; Qin, Wen-Jian; Teng, Qing-Hu; Wang, Kai.
Affiliation
  • Pan XY; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
  • Sun GX; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
  • Huang FP; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
  • Qin WJ; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
  • Teng QH; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
  • Wang K; Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China. 2020130@glut.edu.cn.
Org Biomol Chem ; 22(15): 2968-2973, 2024 Apr 17.
Article in En | MEDLINE | ID: mdl-38529682
ABSTRACT
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed. Upon irradiation, the trivalent iron complex could generate chlorine radicals, which successfully abstracted the hydrogen of benzylic C-H bonds to form benzyl radicals. And these benzyl radicals were converted into oxygenated products under air conditions, which subsequently reacted with anthranilamides for the synthesis of quinazolinones.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Year: 2024 Document type: Article
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PubMed Links
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: Org Biomol Chem Year: 2024 Document type: Article