Direct observation of areneâ¯sulphur dioxide interaction: role of metal ions in electronic modulation for binding and activation.
Chem Commun (Camb)
; 60(79): 11104-11107, 2024 Oct 01.
Article
in En
| MEDLINE
| ID: mdl-39283229
ABSTRACT
In the quest to understand biologically relevant interactions of environmentally detrimental SO2 with host molecules to modulate the electronic properties of the binding sites, we have directly observed the lone pairâ¯π interaction between the aromatic ring and nucleophilic O of SO2 (3.11 Å), for the first time to the best of our knowledge, in addition to the interaction between electrophilic S of SO2 and metal-bound thiolate (2.63 Å).
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Chem Commun (Camb)
Year:
2024
Document type:
Article