Solvent effect on the isomeric equilibrium of carbohydrates: the superior ability of 2,2,2-trifluoroethanol for intramolecular hydrogen bond stabilization.
J Am Chem Soc
; 123(50): 12605-10, 2001 Dec 19.
Article
em En
| MEDLINE
| ID: mdl-11741425
ABSTRACT
The higher aptitude of 2,2,2-trifluoroethanol for intramolecular hydrogen bond stabilization in carbohydrates is suggested. This belief, arising from the analysis by 1H NMR spectroscopy of the solvent effect of D2O, DMSO-d6, and 2,2,2-trifluoroethanol-d3 on the isomeric equilibrium of caryophyllose, was also confirmed by shifting of the conformational equilibria of beta-ribopyranose and of its methyl glycoside.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Ribose
/
Trifluoretanol
/
Monossacarídeos
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2001
Tipo de documento:
Article