Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate, Ta(6)(mu-Cl)(12)Cl(2)(OH(2))(4).4H(2)O, and synthesis and solid-state structure of a tetraalkylammonium derivative, [N(CH(2)Ph)Bu(3)](4)[Ta(6)(mu-Cl)(12)Cl(6)], of the reduced [Ta(6)(mu-Cl)(12)](2+) cluster core(1).
Inorg Chem
; 41(18): 4700-7, 2002 Sep 09.
Article
em En
| MEDLINE
| ID: mdl-12206693
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Tantálio
/
Cloretos
/
Gálio
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2002
Tipo de documento:
Article