Thiosugar nucleotide analogs: synthesis of 5'-(2,3,4-tri-O-acetyl-6-S-acetyl-6-thio-alpha-D-galactopyranosyl diphosphate).
Carbohydr Res
; 337(21-23): 1935-40, 2002 Nov 19.
Article
em En
| MEDLINE
| ID: mdl-12433459
ABSTRACT
The synthesis of a novel analog of uridine diphosphate galactose (UDP-Gal) is described. A sulfur atom was inserted into the 6-position of galactose to give uridine 5'-(2,3,4-tri-O-acetyl-6-S-acetyl-6-thio-alpha-D-galactopyranosyl diphosphate). This peracetylated thiol analogue of UDP-Gal has been synthesized in nine steps starting from methyl alpha-D-galactopyranoside in an overall yield of 3%.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Tiogalactosídeos
/
Uridina Difosfato Galactose
Idioma:
En
Revista:
Carbohydr Res
Ano de publicação:
2002
Tipo de documento:
Article