The effect of incorporating Fréchet dendrons into rotaxanes and molecular shuttles containing the 1,2-bis(pyridinium)ethaneâ[24]crown-8 templating motif.
Chemistry
; 16(15): 4466-76, 2010 Apr 19.
Article
em En
| MEDLINE
| ID: mdl-20352637
ABSTRACT
Fréchet-type dendrons (G0-G3) were added as both axle stoppering units and cyclic wheel appendages in a series of [2]rotaxanes, [3]rotaxanes, and molecular shuttles that employ 1,2-bis(pyridinium)ethane axles and 24-membered crown ethers wheels. The addition of dendrimer wedges as stoppering units dramatically increased the solubility of simple [2]rotaxanes in nonpolar solvents. The X-ray structure of a G1-stoppered [2]rotaxane shows how the dendritic units affect the structure of the interlocked components. Increased solubility allows observation of how the interaction of dendritic units on separate components in interlocked molecules influences switching properties and molecular size. In a series of [2]rotaxane molecular shuttles incorporating two recognition sites, it was demonstrated that an increase in generation on either the stoppering unit or cyclic wheel could influence both the rate of shuttling and the site preference of the wheel on the axle.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chemistry
Ano de publicação:
2010
Tipo de documento:
Article