Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species.
Dalton Trans
; 39(43): 10458-63, 2010 Nov 21.
Article
em En
| MEDLINE
| ID: mdl-20886163
ABSTRACT
Well-defined aryl-Cu(III)-halide species undergo reductive elimination upon acid addition resulting in the formation of strong aryl-halide bonds. The computationally studied mechanism points towards ligand protonation as the rate-determining step, in agreement with previous experimental data.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Halogênios
/
Hidrocarbonetos Aromáticos
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2010
Tipo de documento:
Article