Bis[2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis-(per-chlorate) acetonitrile solvate.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 9): m1023-4, 2009 Aug 08.
Article
em En
| MEDLINE
| ID: mdl-21577391
ABSTRACT
In the cation of the title compound, [Mn(C(11)H(13)N(5))(2)](ClO(4))(2)·CH(3)CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis-(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593â
(10)0.407â
(10). In the crystal, mol-ecules are stabilized by two N-Hâ¯O hydrogen bonds, forming zigzag chains along the a axis, which are further inter-connected by N-Hâ¯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.50â
(1)â
Å] into a three-dimensional network.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2009
Tipo de documento:
Article