catena-Poly[[[diaqua-copper(II)]-bis-(µ(2)-di-4-pyridyl disulfide-κN:N')] bis-(hydrogen phthalate) monohydrate].
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 2): m185, 2010 Jan 20.
Article
em En
| MEDLINE
| ID: mdl-21579653
ABSTRACT
The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol-ecules, two hydrogen phthalate anions and one uncoordinated water mol-ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa-hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol-ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol-ecules.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2010
Tipo de documento:
Article