Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes.
Chem Commun (Camb)
; 47(37): 10431-3, 2011 Oct 07.
Article
em En
| MEDLINE
| ID: mdl-21842090
ABSTRACT
Exposure of 3-hydroxyflavonolate complexes of the group 12 metals to UV light under aerobic conditions results in oxidative carbon-carbon bond cleavage and CO release. This reactivity is novel in that it occurs under mild reaction conditions and suggests that light-induced CO-release reactivity involving metal flavonolate species may be possible in biological systems.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Monóxido de Carbono
/
Dioxigenases
/
Processos Fotoquímicos
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2011
Tipo de documento:
Article