[2,2'-(1,1'-Binaphthyl-2,2'-diyldiimino)-diethanol-κN,N',O]dichloridocopper(II).
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 12): m1844, 2011 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-22199617
In the title complex, [CuCl(2)(C(24)H(24)N(2)O(2))], the Cu(II) cation is N,N',O-chelated by a 2,2'-(1,1'-binaphthyl-2,2'-diyldiimino)-diethanol ligand and coordinated by two chloride anions in a distorted square-pyramidal geometry. In the diethanol ligand, the two naphthalene ring systems are twisted with respect to each other at a dihedral angle of 68.30â
(9)°. The uncoord-inated hy-droxy group links with a coordinated chloride anion via an intra-molecular O-Hâ¯Cl hydrogen bond. Inter-molecular N-Hâ¯O and N-Hâ¯Cl hydrogen bonds occur in the crystal structure.
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01-internacional
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2011
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Article