Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethyl-idene]acetohydrazidato-κ(2)N',O(1)}nickel(II).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 5): m553, 2012 May 01.
Article
em En
| MEDLINE
| ID: mdl-22590074
In the title compound, [Ni(C(9)H(9)N(4)O(2))(2)], the Ni(II) ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethyl-idene]acetohydrazidate ligands in a distorted octa-hedral geometry. In the crystal, N-Hâ¯O and N-Hâ¯N hydrogen bonds link the mol-ecules into columns in [001]. The porous crystal packing is further stabilized via π-π inter-actions between the pyridine rings of neighbouring mol-ecules [centroid-centroid distance = 3.746â
(3)â
Å] with voids of 270â
Å(3).
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
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Article