Bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): a silicon(II) compound with both a bidentate and a monodentate amidinato ligand.
Angew Chem Int Ed Engl
; 51(28): 7020-3, 2012 Jul 09.
Article
em En
| MEDLINE
| ID: mdl-22653909
ABSTRACT
Well looked-after reductive HCl elimination of the λ(6)-silicon(IV) complex 1 leads to the λ(3)-silicon(II) species 2, a novel type of donor-stabilized silylene. Reaction of 2 with [W(CO)(6)] and with I(2) yields the λ(5)-silicon(II) complex 3 and the λ(6)-silicon(IV) complex 4, respectively.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2012
Tipo de documento:
Article