Dibromidobis[1-(2-bromo-benz-yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 6): m785, 2012 Jun 01.
Article
em En
| MEDLINE
| ID: mdl-22719336
ABSTRACT
In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256â
(5)â
Å, in agreement with a classical carbonyl bond. The Cu-O bond length is 2.011â
(3)â
Å. The two bromo-benzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1â
(4)° with the coordination plane.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
Tipo de documento:
Article