Asymmetric synthesis of indole homo-Michael adducts via dynamic kinetic Friedel-Crafts alkylation with cyclopropanes.
Org Lett
; 15(10): 2558-61, 2013 May 17.
Article
em En
| MEDLINE
| ID: mdl-23654283
ABSTRACT
An enantioconvergent Friedel-Crafts alkylation of indoles with donor-acceptor cyclopropanes is described. The reaction is catalyzed by pyboxâ¢MgI2 and proceeds via a type I dynamic kinetic asymmetric transformation (DyKAT).
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Lett
Ano de publicação:
2013
Tipo de documento:
Article