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Ultrafast voltammetry of adsorbed redox active dendrimers with nanometric resolution: an electrochemical microtome.
Amatore, C; Bouret, Y; Maisonhaute, E; Goldsmith, J I; Abruña, H D.
Afiliação
  • Amatore C; Ecole Normale Supérieure, Département de Chimie, UMR CNRS 8640 Pasteur, 24, rue Lhomond, 75231 Paris Cedex 05, France. amatore@ens.fr
Chemphyschem ; 2(2): 130-4, 2001 Feb 16.
Article em En | MEDLINE | ID: mdl-23696441
Megavolt-per-second cyclic voltammetry is used to control the expansion with time of a diffusion layer created within the redox outer shell of a fourth generation dendrimer molecule adsorbed onto an electrode; one quarter of the dendrimer is shown in the picture. This allows the measurement of the degree of communication between the ruthenium(II/III) bis(terpyridyl) ("LRuL") redox centers borne at the extremity of the dendrimer tethers, as well as the characterization of the shape of the adsorbed dendrimer molecule.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemphyschem Ano de publicação: 2001 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemphyschem Ano de publicação: 2001 Tipo de documento: Article