CO2 fixation employing an iridium(I)-hydroxide complex.
Chem Commun (Camb)
; 50(3): 286-8, 2014 Jan 11.
Article
em En
| MEDLINE
| ID: mdl-24132036
ABSTRACT
The reactivity of a number of Ir(I) complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir-O and Ir-N bonds proved facile, yielding a number of Ir(I)-carbonates and -carbamates. Most importantly, reaction between CO2 and Ir(I)-OH led to isolation of the novel [{Ir(I)}2-(µ-κ(1)κ(2)-CO3)] complex.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2014
Tipo de documento:
Article