Investigations of scope and mechanism of nickel-catalyzed transformations of glycosyl trichloroacetimidates to glycosyl trichloroacetamides and subsequent, atom-economical, one-step conversion to &#945;-urea-glycosides.

McKay, Matthew J; Park, Nathaniel H; Nguyen, Hien M

Investigations of scope and mechanism of nickel-catalyzed transformations of glycosyl trichloroacetimidates to glycosyl trichloroacetamides and subsequent, atom-economical, one-step conversion to α-urea-glycosides.

McKay, Matthew J; Park, Nathaniel H; Nguyen, Hien M.

Afiliação

McKay MJ; Department of Chemistry, University of Iowa, Iowa City, Iowa, 52242 (USA), Fax: (+1) 319-335-1270.

Chemistry ; 20(28): 8691-701, 2014 Jul 07.

Article em En | MEDLINE | ID: mdl-24905328

Assuntos

Glicosídeos/química; Níquel/química; Ureia/química; Acetamidas; Catálise; Cloroacetatos; Estereoisomerismo

Palavras-chave

carbohydrates; glycosyl trichloroacetimidates; stereoselectivity; trichloroacetamides; urea glycosides

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ureia / Glicosídeos / Níquel Tipo de estudo: Clinical_trials / Health_economic_evaluation Idioma: En Revista: Chemistry Ano de publicação: 2014 Tipo de documento: Article

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