Oxygen-driven competition between low-dimensional structures of Sr3CoMO6 and Sr3CoMO7-δ with M = Ru, Ir.
Dalton Trans
; 43(37): 13883-91, 2014 Oct 07.
Article
em En
| MEDLINE
| ID: mdl-25111502
ABSTRACT
We have realized a reversible structure transformation of one-dimensional 1D K4CdCl6-type Sr3CoMO6 with the Co(2+)/M(4+) cation ordering into the two-dimensional 2D double layered Ruddlesden-Popper structure Sr3CoMO7-δ with a random distribution of Co and M (with M = Ru, Ir) upon increasing the partial oxygen pressure. The combined soft and hard X-ray absorption spectroscopy studies show that under transformation, Co and M cations were oxidized to Co(3+) and M(5+). During oxidation, high-spin Co(2+) in Sr3CoMO6 first transforms into high-spin Co(3+) in oxygen-deficient Sr3CoMO7-δ, and then further transforms into low-spin Co(3+) in fully oxidized Sr3CoMO7 upon further increasing the partial pressure of oxygen. The 1D Sr3CoMO6 compound is magnetically ordered at low temperatures with the magnetic moments lying along the c-axis. Their alignment is parallel for Sr3CoRuO6 and antiparallel for Sr3CoIrO6. The 2D compounds reveal a spin-glass-like behavior related to the random distribution of magnetic cations in the structure.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Dalton Trans
Ano de publicação:
2014
Tipo de documento:
Article