IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand.
Chem Commun (Camb)
; 51(25): 5271-4, 2015 Mar 28.
Article
em En
| MEDLINE
| ID: mdl-25467188
ABSTRACT
The mesoionic 5-acetylimidazolium-4-olate serves as precursor for an anionic, hybrid NHC, "IMes-acac", consisting of fused diaminocarbene and acetylacetonato units, whose respective coordination abilities are evaluated by the formation of a series of representative copper(I) complexes illustrating the ambidentate character of the ligand.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2015
Tipo de documento:
Article