Crystal structure of 2-{[2-(3-phenyl-allyl-idene)hydrazin-1-yl]thio-carbonyl-sulfanylmeth-yl}pyridinium chloride.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 11): o1207-8, 2014 Nov 01.
Article
em En
| MEDLINE
| ID: mdl-25484832
ABSTRACT
In the title salt of an S-substituted di-thio-carbazate, C16H16N3S2 (+)·Cl(-), the dihedral angles between the almost planar (r.m.s deviation = 0.005â
Å) central CN2S2 residue and the terminal pyridinium and phenyl rings are 80.09â
(11) and 3.82â
(11)°, respectively, indicating the cation has an L-shape; the amine H and thione S atoms are syn. The conformation about each of the imine [1.376â
(3)â
Å] and ethene [1.333â
(4)â
Å] bonds is E. The shortened C-C bond [1.444â
(4)â
Å] linking the double bonds is consistent with conjugation in this part of the mol-ecule. In the crystal, supra-molecular layers with a jagged topology are formed by charged-assisted amine-Hâ¯Cl(-) and pyridinium-N(+)-Hâ¯Cl(-) hydrogen bonds. The layers stack along the a axis with no specific directional inter-actions between them.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2014
Tipo de documento:
Article