Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight.
Chem Commun (Camb)
; 51(54): 10907-9, 2015 Jul 11.
Article
em En
| MEDLINE
| ID: mdl-26060842
ABSTRACT
We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Ano de publicação:
2015
Tipo de documento:
Article